AQA · GCSE · Combined Science

    Course version: 8464 · Version from Sept 2018

    Calculating rates of reactions: draw tangents to the curves on these graphs and use the slope of the tangent as a measure of the rate of reaction

    The rate of reaction at a particular moment relates to the slope of the quantity-time curve.

    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    The rate of reaction at a particular moment relates to the slope of the quantity-time curve. Students draw a tangent: a straight line that touches the curve at the chosen time and follows its direction. The slope of this tangent is used as a measure of the rate of reaction; a steeper tangent indicates a faster rate. For example, a tangent drawn at 20 s that is steeper than one at 40 s shows the reaction is faster at 20 s. Tangents are most reliable where the curve is smooth.

    What earns the marks

    • A tangent is drawn as a straight line touching the curve at the required time and matching the curve's direction at that point.
    • The slope of the tangent is used as a measure of the rate of reaction at that specific time.
    • A steeper tangent is interpreted as a faster rate at that time, and a near-zero slope near the plateau as a very slow or stopped reaction.
    • The tangent must only touch the curve at one point, rather than crossing it as a secant line.

    Common mistakes and how to put them right

    • Drawing the tangent through two points on the curve instead of touching it at one point.

      Put it right by placing the line so it just touches the curve at the chosen time and follows its slope.

    • Using the whole curve's average slope when asked for the rate at a specific time.

      Put it right by drawing the tangent at that time only.

    Exam tips

    • Use a ruler and a sharp pencil, and carefully align the ruler to match the curve's direction at the specific time.
    • Remember that comparing the steepness of tangents allows you to compare rates at different times without calculating the exact gradient.

    Try the lesson

    The start of the Calculating rates of reactions: draw tangents to the curves on these graphs and use the slope of the tangent as a measure of the rate of reaction lesson, made from checked teaching notes for this specification point.

    Have a go first

    A graph shows the volume of gas produced against time for a reaction. To find the rate of reaction at a particular time, what should you draw on the curve at that time?

    Listen

    The rate of reaction at a particular moment relates to the slope of the quantity-time curve. Students draw a tangent: a straight line that touches the curve at the chosen time and follows its direction. The slope of this tangent is used as a measure of the rate of reaction; a steeper tangent indicates a faster rate. For example, a tangent drawn at 20 s that is steeper than one at 40 s shows the reaction is faster at 20 s. Tangents are most reliable where the curve is smooth. A strong answer earns marks for these points. A tangent is drawn as a straight line touching the curve at the required time and matching the curve's direction at that point. The slope of the tangent is used as a measure of the rate of reaction at that specific time. A steeper tangent is interpreted as a faster rate at that time, and a near-zero slope near the plateau as a very slow or stopped reaction. The tangent must only touch the curve at one point, rather than crossing it as a secant line. A common slip: Drawing the tangent through two points on the curve instead of touching it at one point. Instead, placing the line so it just touches the curve at the chosen time and follows its slope. Exam tip: Use a ruler and a sharp pencil, and carefully align the ruler to match the curve's direction at the specific time.

    See it

    A top-down flowchart with eight boxes. The first box says choose the time on the curve and leads to a box saying draw a straight line touching the curve at that time. That leads to a box saying match the line to the curve's direction at that point, which leads to a box saying the tangent touches the curve at one point only. This leads to a box saying use the slope of the tangent as the rate of reaction. From this box three arrows lead to three separate boxes: steeper tangent means faster rate; near-zero slope near the plateau means very slow or stopped reaction; and compare steepness of tangents to compare rates at different times.
    The steps for drawing a tangent to a curve and using its slope to measure and compare rates of reaction.

    Key words

    Say what each word means before you turn the card.

    Tangent

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    Slope of the tangent

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    Steeper tangent

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    Rate of reaction

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    See every definition
    Tangent
    A straight line that touches the curve at the chosen time and follows its direction.
    Slope of the tangent
    Used as a measure of the rate of reaction at that specific time.
    Steeper tangent
    Interpreted as a faster rate at that time.
    Rate of reaction
    At a particular moment, relates to the slope of the quantity-time curve.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart with eight boxes. The first box says choose the time on the curve and leads to a box saying draw a straight line touching the curve at that time. That leads to a box saying match the line to the curve's direction at that point, which leads to a box saying the tangent touches the curve at one point only. This leads to a box saying use the slope of the tangent as the rate of reaction. From this box three arrows lead to three separate boxes: steeper tangent means faster rate; near-zero slope near the plateau means very slow or stopped reaction; and compare steepness of tangents to compare rates at different times.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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