AQA · GCSE · Combined Science

    Course version: 8464 · Version from Sept 2018

    Catalysts: Students should be able to identify catalysts in reactions from their effect on the rate of reaction and because they are not included in the chemical equation for the reaction.

    A catalyst speeds up a reaction without being used up, so it is not consumed and does not appear in the overall chemical equation.

      Study notes

      From the checked teaching notes for this specification point.

      The idea

      A catalyst speeds up a reaction without being used up, so it is not consumed and does not appear in the overall chemical equation. To identify one, compare rates: adding the suspected catalyst increases the rate, while the same amount of an inert substance does not. Then check the equation: a species that appears on both sides, or is written above the arrow, is a catalyst rather than a reactant or product. For example, in the decomposition of hydrogen peroxide, 2H₂O₂ → 2H₂O + O₂, manganese(IV) oxide, MnO₂, speeds up the reaction but is not in the equation; it can be filtered off and reused. Enzymes are biological catalysts that behave in the same way.

      What earns the marks

      • A catalyst increases the rate of a reaction while remaining chemically unchanged at the end.
      • A catalyst is not used up, so it can often be recovered and reused.
      • A catalyst does not appear in the overall chemical equation because it is not a reactant or a product.
      • A species written above the reaction arrow, or shown on both sides of an equation, indicates a catalyst.
      • Comparing the rate with and without the suspected substance provides evidence that it is a catalyst.
      • Enzymes are biological catalysts and can be identified by the same rate and equation evidence.

      Common mistakes and how to put them right

      • Assuming any substance that speeds up a reaction is a catalyst.

        Put it right: Check that it is unchanged and absent from the overall equation.

      • Treating a catalyst as a reactant because it is added at the start.

        Put it right: A catalyst is not used up and is not written as a reactant.

      • Claiming a catalyst increases the yield of a reaction.

        Put it right: A catalyst speeds up the forward and reverse reactions equally and does not change the yield.

      Exam tips

      • Quote the rate evidence and the equation evidence together; one alone is usually insufficient for full credit.
      • When a species appears above the arrow, name it as the catalyst and explain that it is not included in the equation.
      • Use the phrase 'not used up' or 'chemically unchanged' rather than 'not involved', which is inaccurate.

      Try the lesson

      The start of the Catalysts: Students should be able to identify catalysts in reactions from their effect on the rate of reaction and because they are not included in the chemical equation for the reaction. lesson, made from checked teaching notes for this specification point.

      Have a go first

      A student investigates a chemical reaction. In the first experiment, a small amount of solid X is added to the reactants, and the reaction happens much faster. At the end of the experiment, solid X is filtered out, dried, and weighed. Its mass is unchanged. Solid X does not appear in the balanced chemical equation for the reaction. What is solid X?

      Listen

      A catalyst speeds up a reaction without being used up, so it is not consumed and does not appear in the overall chemical equation. To identify one, compare rates: adding the suspected catalyst increases the rate, while the same amount of an inert substance does not. Then check the equation: a species that appears on both sides, or is written above the arrow, is a catalyst rather than a reactant or product. For example, in the decomposition of hydrogen peroxide, 2H₂O₂ → 2H₂O + O₂, manganese(IV) oxide, MnO₂, speeds up the reaction but is not in the equation; it can be filtered off and reused. Enzymes are biological catalysts that behave in the same way. A strong answer earns marks for these points. A catalyst increases the rate of a reaction while remaining chemically unchanged at the end. A catalyst is not used up, so it can often be recovered and reused. A catalyst does not appear in the overall chemical equation because it is not a reactant or a product. A species written above the reaction arrow, or shown on both sides of an equation, indicates a catalyst. A common slip: Assuming any substance that speeds up a reaction is a catalyst: the error is ignoring whether it is consumed. Instead, check that it is unchanged and absent from the overall equation. Exam tip: Quote the rate evidence and the equation evidence together; one alone is usually insufficient for full credit.

      See it

      A flowchart running from top to bottom. The first box says a suspected substance is added, leading to a box comparing the rate with and without it. This branches into two boxes: rate increases, and rate unchanged. The rate increases branch leads to a box saying check the chemical equation, which branches into two boxes: not included as reactant or product, and written above the arrow or on both sides. Both of these lead to a box saying identified as a catalyst. That leads to a box saying chemically unchanged and not used up, which leads to a final box saying can be recovered and reused.
      It shows the two pieces of evidence, rate data and the chemical equation, used to identify a catalyst and why it can be recovered and reused.

      Label the diagram

      Some boxes have lost their names. Pick the right name for each number.

      The diagram again, with 3 boxes numbered instead of named. A flowchart running from top to bottom. The first box says a suspected substance is added, leading to a box comparing the rate with and without it. This branches into two boxes: rate increases, and rate unchanged. The rate increases branch leads to a box saying check the chemical equation, which branches into two boxes: not included as reactant or product, and written above the arrow or on both sides. Both of these lead to a box saying identified as a catalyst. That leads to a box saying chemically unchanged and not used up, which leads to a final box saying can be recovered and reused.
      • 1Box 1

      • 2Box 2

      • 3Box 3

      0 of 3 labelled

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