AQA · GCSE · Combined Science

    Course version: 8464 · Version from Sept 2018

    Cracking and alkenes: There is a high demand for fuels with small molecules and so some of the products of cracking are useful as fuels.

    Cracking breaks large hydrocarbon molecules into smaller, more useful ones.

    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Cracking breaks large hydrocarbon molecules into smaller, more useful ones. Small molecules such as methane, ethane, propane and butane have weak intermolecular forces, so they have low boiling points and are gases or volatile liquids that ignite and burn easily. This makes them valuable as fuels for cooking, heating and transport. Demand for these small-molecule fuels is high because they release energy readily when burned. Cracking therefore supplies fuels such as petrol and diesel components as well as alkenes for making polymers.

    For example: Decane can be cracked to produce octane and ethene; the octane is a useful fuel while the ethene is a feedstock for plastics.

    What earns the marks

    • Cracking converts large hydrocarbon molecules into smaller molecules.
    • Small molecules have weaker intermolecular forces and lower boiling points than large molecules.
    • Small-molecule fuels are gases or volatile liquids that burn readily, so they are in high demand.
    • Some cracking products, such as petrol components, are used as fuels.
    • Cracking also produces alkenes, which are useful for making polymers.
    • The demand for small-molecule fuels is a reason why cracking is carried out industrially.

    Common mistakes and how to put them right

    • Saying cracking only makes alkenes.

      Put it right: Cracking also produces smaller alkanes that are used as fuels.

    • Confusing small molecules with low demand.

      Put it right: Small molecules are in high demand because they are useful fuels, not because they are scarce.

    • Stating that large molecules burn better.

      Put it right: Large molecules have stronger intermolecular forces and are less volatile, so they are less useful as fuels.

    Exam tips

    • Link the small size of the molecule to weak intermolecular forces and a low boiling point.
    • Give a named example of a small-molecule fuel, such as methane or petrol.
    • Mention both products of cracking: fuels and alkenes for polymers.
    • Use the phrase high demand for fuels with small molecules when explaining why cracking is useful.

    Try the lesson

    The start of the Cracking and alkenes: There is a high demand for fuels with small molecules and so some of the products of cracking are useful as fuels. lesson, made from checked teaching notes for this specification point.

    Have a go first

    Why is there a high demand for fuels made of small molecules?

    Listen

    Cracking breaks large hydrocarbon molecules into smaller, more useful ones. Small molecules such as methane, ethane, propane and butane have weak intermolecular forces, so they have low boiling points and are gases or volatile liquids that ignite and burn easily. This makes them valuable as fuels for cooking, heating and transport. Demand for these small-molecule fuels is high because they release energy readily when burned. Cracking therefore supplies fuels such as petrol and diesel components as well as alkenes for making polymers. For example, decane can be cracked to produce octane and ethene; the octane is a useful fuel while the ethene is a feedstock for plastics. A strong answer earns marks for these points. Cracking converts large hydrocarbon molecules into smaller molecules. Small molecules have weaker intermolecular forces and lower boiling points than large molecules. Small-molecule fuels are gases or volatile liquids that burn readily, so they are in high demand. Some cracking products, such as petrol components, are used as fuels. Exam tip: Link the small size of the molecule to weak intermolecular forces and a low boiling point.

    See it

    A flowchart running from top to bottom. The first box reads 'Large hydrocarbon molecules' and an arrow leads to 'Cracking'. From 'Cracking' an arrow leads to 'Smaller molecules'. From 'Smaller molecules' an arrow leads to 'Weak intermolecular forces', then to 'Low boiling points', then to 'Gases or volatile liquids that burn readily', and finally to 'High demand for fuels with small molecules'. A second arrow from 'Smaller molecules' leads separately to 'Alkenes for making polymers'.
    It shows how cracking turns large hydrocarbon molecules into smaller molecules, why small molecules make useful fuels, and that alkenes are also produced for making polymers.

    Key words

    Say what each word means before you turn the card.

    Cracking of hydrocarbons

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    Intermolecular forces and boiling point

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    Fuels and energy resources

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    Industrial uses of alkenes

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    See every definition
    Cracking of hydrocarbons
    Breaks large hydrocarbon molecules into smaller, more useful ones, supplying fuels such as petrol and diesel components as well as alkenes for making polymers.
    Intermolecular forces and boiling point
    Small molecules have weak intermolecular forces, so they have low boiling points and are gases or volatile liquids that ignite and burn easily.
    Fuels and energy resources
    Small-molecule fuels are in high demand because they release energy readily when burned, making them valuable for cooking, heating and transport.
    Industrial uses of alkenes
    Cracking produces alkenes, which are useful for making polymers.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A flowchart running from top to bottom. The first box reads 'Large hydrocarbon molecules' and an arrow leads to 'Cracking'. From 'Cracking' an arrow leads to 'Smaller molecules'. From 'Smaller molecules' an arrow leads to 'Weak intermolecular forces', then to 'Low boiling points', then to 'Gases or volatile liquids that burn readily', and finally to 'High demand for fuels with small molecules'. A second arrow from 'Smaller molecules' leads separately to 'Alkenes for making polymers'.
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    • 2Box 2

    • 3Box 3

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