AQA · GCSE · Combined Science

    Course version: 8464 · Version from Sept 2018

    Crude oil, hydrocarbons and alkanes: Most of the hydrocarbons in crude oil are hydrocarbons called alkanes. The general formula for the homologous series of alkanes is CₙH₂ₙ₊₂

    Crude oil is a mixture of many compounds, most of which contain only carbon and hydrogen, so they are hydrocarbons.

    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Crude oil is a mixture of many compounds, most of which contain only carbon and hydrogen, so they are hydrocarbons. The majority of these belong to the alkane family. Alkanes form a homologous series: a family with the same general formula, similar reactions and a gradual change in physical properties as chain length increases. Their general formula is CₙH₂ₙ₊₂, where n is the number of carbon atoms. For example, when n = 1 the formula is CH₄ (methane); when n = 2 it is C₂H₆ (ethane); when n = 3 it is C₃H₈ (propane). Substituting n into 2n + 2 gives the hydrogen count, so each alkane has two more hydrogen atoms than twice its carbon atoms. Alkanes are saturated: every carbon forms four single covalent bonds, so no more atoms can add without substitution.

    What earns the marks

    • Crude oil is a mixture of hydrocarbons, and most of its hydrocarbons are alkanes.
    • Alkanes are a homologous series, meaning they share a general formula and show trends in properties.
    • The general formula of alkanes is CₙH₂ₙ₊₂, where n is the number of carbon atoms.
    • Substituting n into 2n + 2 gives the number of hydrogen atoms, e.g. n = 4 gives C₄H₁₀.
    • Alkanes are saturated hydrocarbons containing only single covalent bonds between carbon atoms.

    Common mistakes and how to put them right

    • Writing the general formula as CₙH₂ₙ.

      Put it right: This is the alkene general formula; alkanes are saturated and use CₙH₂ₙ₊₂.

    • Counting hydrogen atoms incorrectly for a given n, for example giving C₃H₆ instead of C₃H₈.

      Put it right: Calculate 2n + 2.

    • Describing crude oil as a single compound rather than a mixture of many hydrocarbons separated by fractional distillation.

    Exam tips

    • When asked to deduce a formula, identify n from the number of carbon atoms, then compute 2n + 2 carefully.
    • Use the word saturated to show that alkanes contain only single carbon–carbon bonds.
    • Link the homologous series idea to trends such as increasing boiling point with increasing chain length.

    Try the lesson

    The start of the Crude oil, hydrocarbons and alkanes: Most of the hydrocarbons in crude oil are hydrocarbons called alkanes. The general formula for the homologous series of alkanes is CₙH₂ₙ₊₂ lesson, made from checked teaching notes for this specification point.

    Have a go first

    Which general formula represents the homologous series of alkanes found in crude oil?

    Listen

    Crude oil is a mixture of many compounds, most of which contain only carbon and hydrogen, so they are hydrocarbons. The majority of these belong to the alkane family. Alkanes form a homologous series: a family with the same general formula, similar reactions and a gradual change in physical properties as chain length increases. Their general formula is CₙH₂ₙ₊₂, where n is the number of carbon atoms. For example, when n = 1 the formula is CH₄ (methane); when n = 2 it is C₂H₆ (ethane); when n = 3 it is C₃H₈ (propane). Substituting n into 2n + 2 gives the hydrogen count, so each alkane has two more hydrogen atoms than twice its carbon atoms. Alkanes are saturated: every carbon forms four single covalent bonds, so no more atoms can add without substitution. A strong answer earns marks for these points. Crude oil is a mixture of hydrocarbons, and most of its hydrocarbons are alkanes. Alkanes are a homologous series, meaning they share a general formula and show trends in properties. The general formula of alkanes is CₙH₂ₙ₊₂, where n is the number of carbon atoms. Substituting n into 2n + 2 gives the number of hydrogen atoms, e.g. n = 4 gives C₄H₁₀. Exam tip: When asked to deduce a formula, identify n from the number of carbon atoms, then compute 2n + 2 carefully.

    See it

    A top-down flowchart. The top box reads 'Crude oil: mixture of hydrocarbons' and has an arrow down to 'Most hydrocarbons are alkanes'. That box has an arrow down to 'Alkanes: homologous series'. From this box an arrow goes down to 'General formula CₙH₂ₙ₊₂', which leads down to 'n = number of carbon atoms', then down to 'Hydrogen count = 2n + 2'. A second arrow from 'Alkanes: homologous series' goes sideways to a box reading 'Saturated: only single covalent bonds'.
    It shows how crude oil's hydrocarbons relate to the alkane homologous series, its general formula CₙH₂ₙ₊₂ and the saturated single-bond structure.

    Key words

    Say what each word means before you turn the card.

    Crude oil

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    Homologous series

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    Saturated

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    See every definition
    Crude oil
    A mixture of many compounds, most of which contain only carbon and hydrogen, so they are hydrocarbons.
    Homologous series
    A family with the same general formula, similar reactions and a gradual change in physical properties as chain length increases.
    Saturated
    Every carbon forms four single covalent bonds, so no more atoms can add without substitution.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top box reads 'Crude oil: mixture of hydrocarbons' and has an arrow down to 'Most hydrocarbons are alkanes'. That box has an arrow down to 'Alkanes: homologous series'. From this box an arrow goes down to 'General formula CₙH₂ₙ₊₂', which leads down to 'n = number of carbon atoms', then down to 'Hydrogen count = 2n + 2'. A second arrow from 'Alkanes: homologous series' goes sideways to a box reading 'Saturated: only single covalent bonds'.
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