AQA · A-Level · Chemistry

    Course version: 7405 · Version from Sept 2016

    Students should be able to represent: a covalent bond using a line a…

    Full specification wording

    Nature of covalent and dative covalent bonds: Students should be able to represent: a covalent bond using a line a co-ordinate bond using an arrow.

    Representation carries its own marks.

    Checked against the AQA 7405 specification (opens in a new tab) on .

    • Point 4 of 4
    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Representation carries its own marks. An ordinary covalent bond is drawn as a straight line between the two atoms, one line for each shared pair. A co-ordinate bond is drawn as an arrow whose head points from the atom supplying the lone pair towards the atom receiving it, so in the ammonium ion the arrow runs from nitrogen to the added hydrogen. Do not confuse this with a curly arrow, which is reserved for showing the movement of an electron pair in a mechanism and must start at a lone pair or a bond. A displayed formula must show every atom and every bond, and an ion needs its charge written outside a square bracket enclosing the whole species.

    What earns the marks

    • A straight line drawn for each shared pair in an ordinary covalent bond.
    • An arrow drawn for the co-ordinate bond.
    • The arrowhead pointing from the donor atom towards the acceptor atom.
    • The overall charge shown outside a bracket enclosing the whole ion.

    Common mistakes and how to put them right

    • Drawing a curly arrow, which means the movement of an electron pair, in place of the straight dative arrow.

    • Pointing the arrow from the acceptor back to the donor.

    • Drawing four plain lines in the ammonium ion so the dative bond cannot be identified.

    • Leaving the charge off the ion or placing it on a single atom rather than outside the bracket.

    Exam tips

    • Read the question: if it says show the co-ordinate bond, a plain line will not score.
    • In a displayed formula show all bonds and all atoms, including every hydrogen.
    • Keep diagrams unambiguous; a structure open to two readings earns nothing.

    Try the lesson

    The start of the Nature of covalent and dative covalent bonds: Students should be able to represent: a covalent bond using a line a co-ordinate bond using an arrow. lesson, made from checked teaching notes for this specification point.

    Have a go first

    In a displayed structure, which symbol is used to show a co-ordinate bond?

    Listen

    Representation carries its own marks. An ordinary covalent bond is drawn as a straight line between the two atoms, one line for each shared pair. A co-ordinate bond is drawn as an arrow whose head points from the atom supplying the lone pair towards the atom receiving it, so in the ammonium ion the arrow runs from nitrogen to the added hydrogen. Do not confuse this with a curly arrow, which is reserved for showing the movement of an electron pair in a mechanism and must start at a lone pair or a bond. A displayed formula must show every atom and every bond, and an ion needs its charge written outside a square bracket enclosing the whole species. A strong answer earns marks for these points. a straight line drawn for each shared pair in an ordinary covalent bond. an arrow drawn for the co-ordinate bond. the arrowhead pointing from the donor atom towards the acceptor atom. the overall charge shown outside a bracket enclosing the whole ion. Exam tip: Read the question: if it says show the co-ordinate bond, a plain line will not score.

    See it

    A top-down flowchart. The node 'Ordinary covalent bond' leads to 'Straight line between the two atoms', which leads to 'One line for each shared pair'. The node 'Co-ordinate bond' leads to 'Arrow', which leads to 'Arrowhead points from donor atom towards acceptor atom'. The node 'Ammonium ion' branches to two nodes: 'Three ordinary bonds as lines' and 'Fourth bond as an arrow from nitrogen to the added hydrogen'. The node 'Ion' leads to 'Charge written outside a square bracket enclosing the whole species'. The node 'Curly arrow' leads to 'Reserved for movement of an electron pair in a mechanism'.
    It shows how ordinary covalent bonds and co-ordinate bonds are represented, the correct direction of the dative arrow, and how an ion's charge is shown.

    Key words

    Say what each word means before you turn the card.

    lines for covalent bonds

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    arrows for dative bonds

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    arrow direction

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    charges on ions

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    See every definition
    lines for covalent bonds
    A straight line is drawn between the two atoms, one line for each shared pair in an ordinary covalent bond.
    arrows for dative bonds
    An arrow is drawn for a co-ordinate bond, whose head points from the atom supplying the lone pair towards the atom receiving it.
    arrow direction
    The arrowhead points from the donor atom towards the acceptor atom, so in the ammonium ion the arrow runs from nitrogen to the added hydrogen.
    charges on ions
    An ion needs its charge written outside a square bracket enclosing the whole species.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The node 'Ordinary covalent bond' leads to 'Straight line between the two atoms', which leads to 'One line for each shared pair'. The node 'Co-ordinate bond' leads to 'Arrow', which leads to 'Arrowhead points from donor atom towards acceptor atom'. The node 'Ammonium ion' branches to two nodes: 'Three ordinary bonds as lines' and 'Fourth bond as an arrow from nitrogen to the added hydrogen'. The node 'Ion' leads to 'Charge written outside a square bracket enclosing the whole species'. The node 'Curly arrow' leads to 'Reserved for movement of an electron pair in a mechanism'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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