AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Covalent bonding: These bonds between atoms are strong.

    The covalent bonds within a molecule are strong because the shared electron pair is attracted to both nuclei.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 2 of 8
    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    The covalent bonds within a molecule are strong because the shared electron pair is attracted to both nuclei. Breaking one mole of these bonds needs a large amount of energy, so the bonds do not break during melting or boiling. For example, when water boils, the strong O–H covalent bonds stay intact; the weak forces between separate water molecules are overcome instead. This explains why simple molecular substances have low melting and boiling points even though their covalent bonds are strong. Always distinguish between the strong bonds inside a molecule and the weak intermolecular forces between molecules.

    What earns the marks

    • Covalent bonds are strong because the shared pair is attracted to both nuclei.
    • A large amount of energy is needed to break covalent bonds, so they remain intact during physical changes such as melting and boiling.
    • When a simple molecular substance boils, weak forces between molecules are overcome, not the strong covalent bonds within each molecule.
    • Strong covalent bonds explain why molecules stay together, while weak intermolecular forces explain low melting and boiling points.

    Common mistakes and how to put them right

    • Saying that covalent bonds break when a simple molecular substance boils.

      Put it right by stating that intermolecular forces break instead.

    • Confusing strong covalent bonds with weak intermolecular forces.

      Put it right by naming each type of attraction separately.

    • Claiming that all attractions in a simple molecular substance are weak.

      Put it right by stating that the bonds within each molecule are strong.

    Exam tips

    • Use the phrase 'strong covalent bonds between atoms' and 'weak forces between molecules' to make the distinction clear.
    • When explaining a low boiling point, refer to energy needed to overcome intermolecular forces, not to break covalent bonds.
    • Link the strength of a covalent bond to the attraction between the shared pair and both nuclei.

    Try the lesson

    The start of the Covalent bonding: These bonds between atoms are strong. lesson, made from checked teaching notes for this specification point.

    Have a go first

    Which statement about the covalent bonds between atoms in a molecule is correct?

    Listen

    The covalent bonds within a molecule are strong because the shared electron pair is attracted to both nuclei. Breaking one mole of these bonds needs a large amount of energy, so the bonds do not break during melting or boiling. For example, when water boils, the strong O–H covalent bonds stay intact; the weak forces between separate water molecules are overcome instead. This explains why simple molecular substances have low melting and boiling points even though their covalent bonds are strong. Always distinguish between the strong bonds inside a molecule and the weak intermolecular forces between molecules. A strong answer earns marks for these points. Covalent bonds are strong because the shared pair is attracted to both nuclei. A large amount of energy is needed to break covalent bonds, so they remain intact during physical changes such as melting and boiling. When a simple molecular substance boils, weak forces between molecules are overcome, not the strong covalent bonds within each molecule. Strong covalent bonds explain why molecules stay together, while weak intermolecular forces explain low melting and boiling points. A common slip: Saying that covalent bonds break when a simple molecular substance boils. Instead, stating that intermolecular forces break instead. Exam tip: Use the phrase 'strong covalent bonds between atoms' and 'weak forces between molecules' to make the distinction clear.

    See it

    A top-down flowchart. At the top is a node labelled "Simple molecular substance", which branches into two nodes: "Strong covalent bonds between atoms within each molecule" and "Weak forces between separate molecules". From the strong covalent bonds node, an arrow leads to "Shared electron pair attracted to both nuclei", then to "Large amount of energy needed to break the bonds", then to "Covalent bonds stay intact during melting and boiling". From the weak forces node, an arrow leads to "Overcome when the substance boils", then to "Low melting and boiling points".
    It shows how strong covalent bonds within molecules and weak forces between molecules together explain the low melting and boiling points of simple molecular substances.

    Key words

    Say what each word means before you turn the card.

    Bond strength and energy transfer

    Try answering aloud or in your head before turning the card.

    Explaining physical properties of simple molecules

    Try answering aloud or in your head before turning the card.

    Attraction between shared electrons and nuclei

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    See every definition
    Bond strength and energy transfer
    A large amount of energy is needed to break covalent bonds, so they remain intact during physical changes such as melting and boiling.
    Explaining physical properties of simple molecules
    Strong covalent bonds explain why molecules stay together, while weak intermolecular forces explain low melting and boiling points.
    Attraction between shared electrons and nuclei
    Covalent bonds are strong because the shared pair is attracted to both nuclei.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. At the top is a node labelled "Simple molecular substance", which branches into two nodes: "Strong covalent bonds between atoms within each molecule" and "Weak forces between separate molecules". From the strong covalent bonds node, an arrow leads to "Shared electron pair attracted to both nuclei", then to "Large amount of energy needed to break the bonds", then to "Covalent bonds stay intact during melting and boiling". From the weak forces node, an arrow leads to "Overcome when the substance boils", then to "Low melting and boiling points".
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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