AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Ionic bonding: Metal atoms lose electrons to become positively charged ions.

    Metal atoms have relatively few electrons in their outer shell, so losing those electrons is energetically favourable and produces a positive ion.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 2 of 7
    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Metal atoms have relatively few electrons in their outer shell, so losing those electrons is energetically favourable and produces a positive ion. For example, a sodium atom has the electronic structure 2,8,1; losing its single outer electron gives Na⁺ with the structure 2,8, which is the same as neon. The number of electrons lost equals the group number for Groups 1, 2 and 3, so magnesium (2,8,2) loses two electrons to form Mg²⁺. The charge is written as a superscript after the symbol, and the size of the charge matches the number of electrons lost. This electron loss is the first half of ionic bonding and explains why metals form cations in compounds such as NaCl and MgO.

    What earns the marks

    • Metal atoms lose the electrons in their outermost shell first, because these are the least strongly attracted to the nucleus.
    • The number of electrons lost by a metal atom is equal to its group number for Groups 1, 2 and 3.
    • Loss of electrons produces a positive ion because the number of protons now exceeds the number of electrons.
    • The charge on the ion is written as a superscript, for example Na⁺, Mg²⁺ and Al³⁺.
    • The electronic structure of the ion formed is that of the nearest noble gas, for example Na⁺ is 2,8 like neon.

    Common mistakes and how to put them right

    • Writing the charge after the symbol on the baseline, such as Na1⁺, instead of using a superscript.

      Put it right: The correct form is Na⁺.

    • Saying that metal atoms gain electrons to become positive ions.

      Put it right: Metals lose electrons, and gaining electrons would make the ion negative.

    • Forgetting to balance the charge with the number of electrons lost, for example writing Mg⁺ when magnesium loses two electrons and forms Mg²⁺.

    Exam tips

    • State clearly that electrons are lost from the outer shell, not from the nucleus.
    • Link the group number to the number of electrons lost before writing the ion symbol.
    • Check that the superscript charge matches the number of electrons removed, and that the sign is positive.

    Try the lesson

    The start of the Ionic bonding: Metal atoms lose electrons to become positively charged ions. lesson, made from checked teaching notes for this specification point.

    Have a go first

    A magnesium atom loses two electrons when it forms an ion. What is the charge on the magnesium ion formed?

    Listen

    Metal atoms have relatively few electrons in their outer shell, so losing those electrons is energetically favourable and produces a positive ion. For example, a sodium atom has the electronic structure 2,8,1; losing its single outer electron gives Na⁺ with the structure 2,8, which is the same as neon. The number of electrons lost equals the group number for Groups 1, 2 and 3, so magnesium (2,8,2) loses two electrons to form Mg²⁺. The charge is written as a superscript after the symbol, and the size of the charge matches the number of electrons lost. This electron loss is the first half of ionic bonding and explains why metals form cations in compounds such as NaCl and MgO. A strong answer earns marks for these points. Metal atoms lose the electrons in their outermost shell first, because these are the least strongly attracted to the nucleus. The number of electrons lost by a metal atom is equal to its group number for Groups 1, 2 and 3. Loss of electrons produces a positive ion because the number of protons now exceeds the number of electrons. The charge on the ion is written as a superscript, for example Na⁺, Mg²⁺ and Al³⁺. Exam tip: State clearly that electrons are lost from the outer shell, not from the nucleus.

    See it

    A top-down flowchart. It starts with a node labelled 'Metal atom', which leads to 'Loses outer-shell electrons'. From there one arrow leads to 'Protons now exceed electrons', which leads to 'Positively charged ion', and another arrow leads to 'Number of electrons lost equals group number (Groups 1, 2, 3)', which leads to 'Charge written as superscript: Na⁺, Mg²⁺, Al³⁺'. The 'Positively charged ion' node then leads to 'Ion has electronic structure of nearest noble gas'.
    Shows how a metal atom losing outer-shell electrons produces a positive ion, with the number of electrons lost matching the group number and the charge written as a superscript.

    Key words

    Say what each word means before you turn the card.

    Ion formation by electron loss

    Try answering aloud or in your head before turning the card.

    Charge and relative numbers of protons and electrons

    Try answering aloud or in your head before turning the card.

    Representation of ions using symbols and superscripts

    Try answering aloud or in your head before turning the card.

    See every definition
    Ion formation by electron loss
    Metal atoms lose electrons to become positively charged ions, losing the electrons in their outermost shell first because these are the least strongly attracted to the nucleus.
    Charge and relative numbers of protons and electrons
    Loss of electrons produces a positive ion because the number of protons now exceeds the number of electrons, and the size of the charge matches the number of electrons lost.
    Representation of ions using symbols and superscripts
    The charge on the ion is written as a superscript after the symbol, and the superscript charge must match the number of electrons removed, with a positive sign.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. It starts with a node labelled 'Metal atom', which leads to 'Loses outer-shell electrons'. From there one arrow leads to 'Protons now exceed electrons', which leads to 'Positively charged ion', and another arrow leads to 'Number of electrons lost equals group number (Groups 1, 2, 3)', which leads to 'Charge written as superscript: Na⁺, Mg²⁺, Al³⁺'. The 'Positively charged ion' node then leads to 'Ion has electronic structure of nearest noble gas'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

    There is more to this lesson

    The full lesson goes on to check your understanding and help you earn the marks. Create a free account to carry on, with your progress saved.

    Carry on with the full lesson

    A week of Premium from your first lesson · Then the free plan continues · No card, no charge

    Test your understanding of Ionic bonding: Metal atoms lose electrons to become positively charged ions.

    Active recall beats re-reading. Take an instant quiz now to test what you’ve learned and lock it into long-term memory.

    Take topic quiz

    A week of Premium from your first lesson · Then the free plan continues · No card, no charge