AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Ionic compounds are held together by strong electrostatic forces of…

    Full specification wording

    Ionic compounds: Ionic compounds are held together by strong electrostatic forces of attraction between oppositely charged ions.

    In an ionic compound, positive and negative ions attract each other because opposite charges attract.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 2 of 6
    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    In an ionic compound, positive and negative ions attract each other because opposite charges attract. These attractions act in all directions throughout the giant lattice and are called electrostatic forces of attraction. They are strong, so a large amount of energy is needed to overcome them. This is why ionic compounds have high melting points and high boiling points. For example, sodium chloride melts at about 801 °C because the Na⁺ and Cl⁻ ions are held in a strong three-dimensional network. When an ionic compound melts or dissolves, the lattice breaks down and the ions become free to move, which allows the molten or dissolved compound to conduct electricity.

    What earns the marks

    • Ionic compounds are held together by electrostatic forces of attraction between oppositely charged ions.
    • The forces act between positive and negative ions throughout the giant lattice.
    • The attractions are strong, so a large amount of energy is needed to break them.
    • Strong electrostatic forces explain the high melting points and boiling points of ionic compounds.
    • When melted or dissolved, the lattice breaks down and the ions are free to move.
    • Free-moving ions allow molten or aqueous ionic compounds to conduct electricity.

    Common mistakes and how to put them right

    • Saying ionic compounds are held together by covalent bonds.

      Put it right: The bonding is electrostatic attraction between oppositely charged ions.

    • Describing the forces as weak.

      Put it right: They are strong, which is why ionic compounds have high melting points.

    • Stating that solid ionic compounds conduct electricity.

      Put it right: The ions are fixed in the lattice, so conduction occurs only when molten or dissolved.

    Exam tips

    • Use the phrase strong electrostatic forces of attraction between oppositely charged ions.
    • Link the strength of the forces to a named property such as high melting point.
    • Explain conduction by referring to ions being free to move when molten or in solution.

    Try the lesson

    The start of the Ionic compounds: Ionic compounds are held together by strong electrostatic forces of attraction between oppositely charged ions. lesson, made from checked teaching notes for this specification point.

    Have a go first

    What holds the ions together in an ionic compound?

    Listen

    In an ionic compound, positive and negative ions attract each other because opposite charges attract. These attractions act in all directions throughout the giant lattice and are called electrostatic forces of attraction. They are strong, so a large amount of energy is needed to overcome them. This is why ionic compounds have high melting points and high boiling points. For example, sodium chloride melts at about 801 °C because the Na⁺ and Cl⁻ ions are held in a strong three-dimensional network. When an ionic compound melts or dissolves, the lattice breaks down and the ions become free to move, which allows the molten or dissolved compound to conduct electricity. A strong answer earns marks for these points. Ionic compounds are held together by electrostatic forces of attraction between oppositely charged ions. The forces act between positive and negative ions throughout the giant lattice. The attractions are strong, so a large amount of energy is needed to break them. Strong electrostatic forces explain the high melting points and boiling points of ionic compounds. Exam tip: Use the phrase strong electrostatic forces of attraction between oppositely charged ions.

    See it

    A top-down flowchart. The top node reads 'Oppositely charged ions in a giant lattice' and points down to 'Strong electrostatic forces of attraction'. From this node three branches lead downwards. The first branch goes to 'Large amount of energy needed to overcome them', which leads to 'High melting points and high boiling points'. The second branch goes to 'Solid: ions fixed in the lattice', which leads to 'Solid does not conduct electricity'. The third branch goes to 'Melted or dissolved: lattice breaks down', which leads to 'Ions become free to move', which leads to 'Molten or dissolved compound conducts electricity'.
    Shows how strong electrostatic forces between oppositely charged ions in a giant lattice lead to high melting and boiling points, and how the lattice breaking down on melting or dissolving frees ions to conduct electricity.

    Key words

    Say what each word means before you turn the card.

    Electrostatic attraction between oppositely charged ions

    Try answering aloud or in your head before turning the card.

    Strength of ionic bonding

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    Relationship between bonding and physical properties

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    Conduction by free-moving ions

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    See every definition
    Electrostatic attraction between oppositely charged ions
    Ionic compounds are held together by strong electrostatic forces of attraction between oppositely charged ions, which attract each other because opposite charges attract.
    Strength of ionic bonding
    The attractions are strong, so a large amount of energy is needed to overcome them.
    Relationship between bonding and physical properties
    Strong electrostatic forces explain the high melting points and high boiling points of ionic compounds.
    Conduction by free-moving ions
    When an ionic compound melts or dissolves, the lattice breaks down and the ions become free to move, which allows the molten or dissolved compound to conduct electricity.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node reads 'Oppositely charged ions in a giant lattice' and points down to 'Strong electrostatic forces of attraction'. From this node three branches lead downwards. The first branch goes to 'Large amount of energy needed to overcome them', which leads to 'High melting points and high boiling points'. The second branch goes to 'Solid: ions fixed in the lattice', which leads to 'Solid does not conduct electricity'. The third branch goes to 'Melted or dissolved: lattice breaks down', which leads to 'Ions become free to move', which leads to 'Molten or dissolved compound conducts electricity'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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