AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Ionic compounds have regular structures (giant ionic lattices) in which…

    Full specification wording

    Properties of ionic compounds: Ionic compounds have regular structures (giant ionic lattices) in which there are strong electrostatic forces of attraction in all directions between oppositely charged ions.

    Ionic compounds form when oppositely charged ions pack together in a regular three-dimensional arrangement called a giant ionic lattice.

    Checked against the AQA 8462 specification (opens in a new tab) on .

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    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Ionic compounds form when oppositely charged ions pack together in a regular three-dimensional arrangement called a giant ionic lattice. Each ion is surrounded by ions of opposite charge, and the electrostatic forces of attraction act in all directions, not just between one pair. For example, in sodium chloride, each Na⁺ is surrounded by six Cl⁻ ions and each Cl⁻ by six Na⁺ ions. The lattice is described as giant because it extends throughout the crystal. These strong forces hold the structure together, which explains the high melting and boiling points. The regularity also means ionic compounds often form crystals with flat faces.

    What earns the marks

    • Describes the structure as a giant ionic lattice with a regular arrangement of alternating positive and negative ions.
    • States that electrostatic forces of attraction act in all directions between oppositely charged ions.
    • Explains that the forces are strong because of the high charges and close packing of ions.
    • Uses a named example such as sodium chloride to illustrate the lattice arrangement.
    • Links the regular structure to the crystalline nature of ionic compounds.

    Common mistakes and how to put them right

    • Describing ionic bonding as sharing electrons.

      Put it right: Ionic bonding involves transfer of electrons to form ions and electrostatic attraction between them.

    • Saying forces act only between one pair of ions.

      Put it right: Forces act in all directions throughout the lattice.

    • Confusing a giant ionic lattice with a simple molecule.

      Put it right: It is a continuous three-dimensional structure, not discrete molecules.

    Exam tips

    • Use the phrase 'electrostatic forces of attraction in all directions' when describing ionic lattices.
    • Refer to a specific ionic compound to support your description.
    • If asked to explain properties, always link back to the strength and direction of the forces.

    Try the lesson

    The start of the Properties of ionic compounds: Ionic compounds have regular structures (giant ionic lattices) in which there are strong electrostatic forces of attraction in all directions between oppositely charged ions. lesson, made from checked teaching notes for this specification point.

    Have a go first

    What name is given to the regular structure of an ionic compound such as sodium chloride?

    Listen

    Ionic compounds form when oppositely charged ions pack together in a regular three-dimensional arrangement called a giant ionic lattice. Each ion is surrounded by ions of opposite charge, and the electrostatic forces of attraction act in all directions, not just between one pair. For example, in sodium chloride, each Na⁺ is surrounded by six Cl⁻ ions and each Cl⁻ by six Na⁺ ions. The lattice is described as giant because it extends throughout the crystal. These strong forces hold the structure together, which explains the high melting and boiling points. The regularity also means ionic compounds often form crystals with flat faces. A strong answer earns marks for these points. Describes the structure as a giant ionic lattice with a regular arrangement of alternating positive and negative ions. States that electrostatic forces of attraction act in all directions between oppositely charged ions. Explains that the forces are strong because of the high charges and close packing of ions. Uses a named example such as sodium chloride to illustrate the lattice arrangement. A common slip: Describing ionic bonding as sharing electrons. Instead, ionic bonding involves transfer of electrons to form ions and electrostatic attraction between them. Exam tip: Use the phrase 'electrostatic forces of attraction in all directions' when describing ionic lattices.

    See it

    A top-down flowchart. It starts with a node labelled 'Oppositely charged ions', which leads to 'Pack together in a regular three-dimensional arrangement', then to 'Giant ionic lattice'. From the lattice, one path goes to 'Each ion surrounded by ions of opposite charge', then to 'Strong electrostatic forces of attraction in all directions', then to 'Strong forces hold the structure together', and finally to 'High melting and boiling points'. A second path branches from 'Giant ionic lattice' to 'Regular structure', which leads to 'Ionic compounds often form crystals with flat faces'.
    This shows how oppositely charged ions packing into a regular giant ionic lattice gives strong electrostatic forces of attraction in all directions, which holds the structure together and explains high melting and boiling points and the crystalline appearance.

    Key words

    Say what each word means before you turn the card.

    Giant ionic lattice

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    Electrostatic forces of attraction

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    Structure-property relationships

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    See every definition
    Giant ionic lattice
    A regular structure in which oppositely charged ions pack together in a three-dimensional arrangement that extends throughout the crystal.
    Electrostatic forces of attraction
    Strong forces that act in all directions between oppositely charged ions in a giant ionic lattice.
    Structure-property relationships
    The link between the strong forces holding the regular structure together and the high melting and boiling points of ionic compounds.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. It starts with a node labelled 'Oppositely charged ions', which leads to 'Pack together in a regular three-dimensional arrangement', then to 'Giant ionic lattice'. From the lattice, one path goes to 'Each ion surrounded by ions of opposite charge', then to 'Strong electrostatic forces of attraction in all directions', then to 'Strong forces hold the structure together', and finally to 'High melting and boiling points'. A second path branches from 'Giant ionic lattice' to 'Regular structure', which leads to 'Ionic compounds often form crystals with flat faces'.
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    • 3Box 3

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