AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    The relative atomic mass of an element is an average value that takes…

    Full specification wording

    Relative atomic mass: The relative atomic mass of an element is an average value that takes account of the abundance of the isotopes of the element.

    Most elements exist as a mixture of isotopes: atoms with the same number of protons but different numbers of neutrons.

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    Study notes

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    The idea

    Most elements exist as a mixture of isotopes: atoms with the same number of protons but different numbers of neutrons. Because the isotopes of an element have different masses and occur in different abundances, the relative atomic mass (Aᵣ) is a weighted average, not simply the mass of one atom. For example, chlorine consists of about 75% chlorine-35 and 25% chlorine-37, giving a relative atomic mass of about 35.5. The value is relative to 1/12 of the mass of a carbon-12 atom, and it is not a whole number when isotopes are present in significant amounts. Aᵣ is the value shown for each element on the periodic table.

    What earns the marks

    • Isotopes are atoms of the same element with different numbers of neutrons and therefore different mass numbers.
    • Relative atomic mass is a weighted average that reflects the abundance of each isotope.
    • The average is relative to 1/12 of the mass of a carbon-12 atom.
    • Aᵣ is often not a whole number because it is an average of isotope masses.
    • The periodic table value for an element is its relative atomic mass.

    Common mistakes and how to put them right

    • Treating relative atomic mass as the mass of the most common isotope.

      Put it right: Treat it as a weighted average of all isotopes.

    • Averaging isotope masses without including their abundances.

      Put it right: Weight each mass by its percentage abundance.

    • Confusing relative atomic mass with mass number.

      Put it right: Note that mass number is a whole number for one isotope, while Aᵣ is an average for the element.

    Exam tips

    • Quote the definition of relative atomic mass precisely, including the word average.
    • Link the idea of abundance to the reason Aᵣ is not a whole number.
    • Use a named element such as chlorine or copper to illustrate the idea in an explanation.

    Try the lesson

    The start of the Relative atomic mass: The relative atomic mass of an element is an average value that takes account of the abundance of the isotopes of the element. lesson, made from checked teaching notes for this specification point.

    Have a go first

    Why is the relative atomic mass of an element often not a whole number?

    Listen

    Most elements exist as a mixture of isotopes: atoms with the same number of protons but different numbers of neutrons. Because the isotopes of an element have different masses and occur in different abundances, the relative atomic mass (Aᵣ) is a weighted average, not simply the mass of one atom. For example, chlorine consists of about 75% chlorine-35 and 25% chlorine-37, giving a relative atomic mass of about 35.5. The value is relative to 1/12 of the mass of a carbon-12 atom, and it is not a whole number when isotopes are present in significant amounts. Aᵣ is the value shown for each element on the periodic table. A strong answer earns marks for these points. Isotopes are atoms of the same element with different numbers of neutrons and therefore different mass numbers. Relative atomic mass is a weighted average that reflects the abundance of each isotope. The average is relative to 1/12 of the mass of a carbon-12 atom. Aᵣ is often not a whole number because it is an average of isotope masses. A common slip: Treating relative atomic mass as the mass of the most common isotope. Instead, treat it as a weighted average of all isotopes. Exam tip: Quote the definition of relative atomic mass precisely, including the word average.

    See it

    A top-down flowchart. A single node reads 'Element exists as a mixture of isotopes' and branches into two nodes: 'Isotopes have different masses' and 'Isotopes occur in different abundances'. Both of these lead into one node reading 'Relative atomic mass is a weighted average'. From that node three arrows lead to three separate end nodes: 'Average is relative to 1/12 of the mass of a carbon-12 atom', 'Aᵣ is often not a whole number', and 'Aᵣ is the value shown on the periodic table'.
    Shows how isotope masses and abundances combine into a weighted average relative atomic mass, which is often not a whole number and is the value shown on the periodic table.

    Key words

    Say what each word means before you turn the card.

    Isotopes

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    Relative atomic mass

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    Abundance

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    See every definition
    Isotopes
    Atoms of the same element with different numbers of neutrons and therefore different mass numbers.
    Relative atomic mass
    A weighted average that reflects the abundance of each isotope, relative to 1/12 of the mass of a carbon-12 atom.
    Abundance
    How much of each isotope of an element is present, which the weighted average reflects.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. A single node reads 'Element exists as a mixture of isotopes' and branches into two nodes: 'Isotopes have different masses' and 'Isotopes occur in different abundances'. Both of these lead into one node reading 'Relative atomic mass is a weighted average'. From that node three arrows lead to three separate end nodes: 'Average is relative to 1/12 of the mass of a carbon-12 atom', 'Aᵣ is often not a whole number', and 'Aᵣ is the value shown on the periodic table'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

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