AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Passing an electric current through electrolytes causes the ions to move…

    Full specification wording

    The process of electrolysis: Passing an electric current through electrolytes causes the ions to move to the electrodes.

    When a direct current is passed through an electrolyte, the mobile ions move towards the electrodes.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 3 of 7
    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    When a direct current is passed through an electrolyte, the mobile ions move towards the electrodes. Positively charged ions are attracted to the negative electrode, and negatively charged ions are attracted to the positive electrode. This movement of ions through the electrolyte completes the circuit and allows charge to flow. For example, in molten sodium chloride, Na⁺ ions move towards the negative electrode and Cl⁻ ions move towards the positive electrode. The ions then gain or lose electrons at the electrodes, producing new substances. This process is electrolysis, and it requires a direct current supply and mobile ions.

    What earns the marks

    • Passing a direct current through an electrolyte causes ions to move towards the electrodes.
    • The movement of ions through the electrolyte allows charge to flow and completes the circuit.
    • Ions are discharged at the electrodes, where they gain or lose electrons.
    • Electrolysis requires mobile ions and a direct current supply.
    • A named example such as molten sodium chloride can be used to show Na⁺ and Cl⁻ ions moving to opposite electrodes.

    Common mistakes and how to put them right

    • Thinking that ions move only when the current is switched on but not before.

      Put it right: Ions are already mobile in the electrolyte and the current causes their directed movement.

    • Believing that electrons flow through the electrolyte.

      Put it right: Ions carry charge through the electrolyte while electrons flow in the external circuit.

    • Assuming that alternating current is used.

      Put it right: Electrolysis uses a direct current so that the electrodes keep fixed polarities.

    Exam tips

    • State that a direct current is needed and explain that it causes directed ion movement.
    • Describe the movement of both positive and negative ions to show a complete picture.
    • Link ion movement to discharge at the electrodes and the formation of new substances.

    Try the lesson

    The start of the The process of electrolysis: Passing an electric current through electrolytes causes the ions to move to the electrodes. lesson, made from checked teaching notes for this specification point.

    Have a go first

    What happens to the ions in an electrolyte when an electric current is passed through it?

    Listen

    When a direct current is passed through an electrolyte, the mobile ions move towards the electrodes. Positively charged ions are attracted to the negative electrode, and negatively charged ions are attracted to the positive electrode. This movement of ions through the electrolyte completes the circuit and allows charge to flow. For example, in molten sodium chloride, Na⁺ ions move towards the negative electrode and Cl⁻ ions move towards the positive electrode. The ions then gain or lose electrons at the electrodes, producing new substances. This process is electrolysis, and it requires a direct current supply and mobile ions. A strong answer earns marks for these points. Passing a direct current through an electrolyte causes ions to move towards the electrodes. The movement of ions through the electrolyte allows charge to flow and completes the circuit. Ions are discharged at the electrodes, where they gain or lose electrons. Electrolysis requires mobile ions and a direct current supply. A common slip: Thinking that ions move only when the current is switched on but not before. Instead, ions are already mobile in the electrolyte and the current causes their directed movement. Exam tip: State that a direct current is needed and explain that it causes directed ion movement.

    See it

    A top-down flowchart. The first box reads 'Direct current passed through electrolyte' and an arrow leads down to 'Mobile ions move towards electrodes'. From this box two arrows branch out: one to 'Positive ions attracted to negative electrode' and one to 'Negative ions attracted to positive electrode'. Both of these boxes have arrows leading to 'Ions gain or lose electrons at electrodes', which then leads to 'New substances produced'. A separate arrow from 'Mobile ions move towards electrodes' leads to 'Ion movement allows charge to flow and completes the circuit'.
    It shows how passing a direct current through an electrolyte makes positive and negative ions move to opposite electrodes, where they gain or lose electrons to produce new substances.

    Key words

    Say what each word means before you turn the card.

    Electrolysis and direct current

    Try answering aloud or in your head before turning the card.

    Ion migration in electrolytes

    Try answering aloud or in your head before turning the card.

    Charge flow in circuits

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    Discharge at electrodes

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    See every definition
    Electrolysis and direct current
    Passing a direct current through an electrolyte causes the mobile ions to move towards the electrodes, and this process is electrolysis.
    Ion migration in electrolytes
    Positively charged ions are attracted to the negative electrode and negatively charged ions are attracted to the positive electrode.
    Charge flow in circuits
    The movement of ions through the electrolyte allows charge to flow and completes the circuit.
    Discharge at electrodes
    The ions gain or lose electrons at the electrodes, producing new substances.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The first box reads 'Direct current passed through electrolyte' and an arrow leads down to 'Mobile ions move towards electrodes'. From this box two arrows branch out: one to 'Positive ions attracted to negative electrode' and one to 'Negative ions attracted to positive electrode'. Both of these boxes have arrows leading to 'Ions gain or lose electrons at electrodes', which then leads to 'New substances produced'. A separate arrow from 'Mobile ions move towards electrodes' leads to 'Ion movement allows charge to flow and completes the circuit'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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