AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Whenever a measurement is made there is always some uncertainty about the…

    Full specification wording

    Chemical measurements: Whenever a measurement is made there is always some uncertainty about the result obtained.

    Every measurement has uncertainty because instruments have limited resolution, conditions vary and the person reading the scale may make small errors.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 1 of 2
    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Every measurement has uncertainty because instruments have limited resolution, conditions vary and the person reading the scale may make small errors. Uncertainty is the range of values within which the true value is likely to lie. For example, a balance reading to the nearest 0.01 g has an uncertainty of about ±0.01 g, while a thermometer read to the nearest 1 °C has an uncertainty of about ±0.5 °C if you estimate between marks. Uncertainty is not the same as a mistake: it is unavoidable and can be reduced but not removed. Repeating measurements and using finer-scale instruments can reduce uncertainty, and the mean of repeated readings is usually more reliable.

    What earns the marks

    • State that all measurements have some uncertainty.
    • Identify a source of uncertainty, such as instrument resolution or reading the scale.
    • Distinguish uncertainty from a mistake or a gross error.
    • Explain that repeating measurements or using a finer scale can reduce uncertainty.
    • Use the resolution of an instrument to estimate the uncertainty in a single reading.

    Common mistakes and how to put them right

    • Treating uncertainty as a mistake.

      Put it right by explaining that uncertainty is unavoidable and affects every measurement.

    • Believing that a more precise instrument removes uncertainty completely.

      Put it right by stating that it only reduces uncertainty.

    • Confusing uncertainty with accuracy.

      Put it right by explaining that uncertainty describes the spread of possible values, while accuracy describes closeness to the true value.

    Exam tips

    • Quote the instrument resolution when asked to estimate uncertainty.
    • Use the phrase true value when defining uncertainty.
    • Give a specific example, such as a balance reading to the nearest 0.01 g, rather than a vague statement.

    Try the lesson

    The start of the Chemical measurements: Whenever a measurement is made there is always some uncertainty about the result obtained. lesson, made from checked teaching notes for this specification point.

    Have a go first

    A student records the volume of gas collected in a measuring cylinder as 24 cm³. Why is this value not exact?

    Listen

    Every measurement has uncertainty because instruments have limited resolution, conditions vary and the person reading the scale may make small errors. Uncertainty is the range of values within which the true value is likely to lie. For example, a balance reading to the nearest 0.01 g has an uncertainty of about ±0.01 g, while a thermometer read to the nearest 1 °C has an uncertainty of about ±0.5 °C if you estimate between marks. Uncertainty is not the same as a mistake: it is unavoidable and can be reduced but not removed. Repeating measurements and using finer-scale instruments can reduce uncertainty, and the mean of repeated readings is usually more reliable. A strong answer earns marks for these points. State that all measurements have some uncertainty. Identify a source of uncertainty, such as instrument resolution or reading the scale. Distinguish uncertainty from a mistake or a gross error. Explain that repeating measurements or using a finer scale can reduce uncertainty. A common slip: Treating uncertainty as a mistake. Instead, explaining that uncertainty is unavoidable and affects every measurement. Exam tip: Quote the instrument resolution when asked to estimate uncertainty.

    See it

    A top-down flowchart. The top node 'Measurement made' leads to 'Uncertainty about the result'. From this, one branch goes to 'Sources of uncertainty', which splits into three nodes: 'Instrument resolution', 'Conditions vary' and 'Reading the scale'. A second branch from 'Uncertainty about the result' goes to 'Uncertainty is not a mistake'. A third branch goes to 'Can be reduced but not removed', which splits into 'Repeat measurements' and 'Use finer-scale instruments'; 'Repeat measurements' then leads to 'Mean of repeated readings usually more reliable'.
    Shows that every measurement carries uncertainty, its sources, that it is not a mistake, and how it can be reduced but not removed.

    Key words

    Say what each word means before you turn the card.

    Measurement and uncertainty

    Try answering aloud or in your head before turning the card.

    Instrument resolution

    Try answering aloud or in your head before turning the card.

    Repeat measurements

    Try answering aloud or in your head before turning the card.

    See every definition
    Measurement and uncertainty
    Whenever a measurement is made there is always some uncertainty about the result obtained, which is the range of values within which the true value is likely to lie.
    Instrument resolution
    Instruments have limited resolution, and the resolution of an instrument can be used to estimate the uncertainty in a single reading.
    Repeat measurements
    Repeating measurements can reduce uncertainty, and the mean of repeated readings is usually more reliable.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node 'Measurement made' leads to 'Uncertainty about the result'. From this, one branch goes to 'Sources of uncertainty', which splits into three nodes: 'Instrument resolution', 'Conditions vary' and 'Reading the scale'. A second branch from 'Uncertainty about the result' goes to 'Uncertainty is not a mistake'. A third branch goes to 'Can be reduced but not removed', which splits into 'Repeat measurements' and 'Use finer-scale instruments'; 'Repeat measurements' then leads to 'Mean of repeated readings usually more reliable'.
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