AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Endothermic reactions include thermal decompositions and the reaction of…

    Full specification wording

    Energy transfer during exothermic and endothermic reactions: Endothermic reactions include thermal decompositions and the reaction of citric acid and sodium hydrogencarbonate.

    Thermal decomposition means breaking a compound down by heating, for example heating calcium carbonate to form calcium oxide and carbon dioxide; energy must be taken in continuously, so it is…

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 8 of 12
    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Thermal decomposition means breaking a compound down by heating, for example heating calcium carbonate to form calcium oxide and carbon dioxide; energy must be taken in continuously, so it is endothermic. The reaction of citric acid with sodium hydrogencarbonate is also endothermic: when the two solids or solutions mix, they fizz to produce carbon dioxide and the mixture cools. In both cases energy is taken in from the surroundings, so the temperature of the surroundings falls. These examples show that endothermic reactions are not limited to one type of chemistry; they include decomposition driven by heating and a reaction between an acid and a hydrogencarbonate.

    What earns the marks

    • Thermal decomposition is an endothermic process in which a compound is broken down by heating.
    • A named thermal decomposition, such as calcium carbonate forming calcium oxide and carbon dioxide, releases carbon dioxide and requires energy input.
    • The reaction of citric acid with sodium hydrogencarbonate is endothermic and produces carbon dioxide gas.
    • In both examples, energy is taken in from the surroundings, so the temperature of the surroundings decreases.
    • The citric acid and sodium hydrogencarbonate reaction can be observed as fizzing and a temperature fall.

    Common mistakes and how to put them right

    • Calling thermal decomposition exothermic because heat is applied.

      Put it right: Energy is taken in overall, so it is endothermic.

    • Writing that the citric acid and sodium hydrogencarbonate reaction warms the mixture.

      Put it right: The mixture cools as energy is taken in.

    • Confusing the gas produced with the energy change.

      Put it right: Carbon dioxide production is a chemical observation, while the temperature fall shows the endothermic energy change.

    Exam tips

    • Name the products in a thermal decomposition, for example calcium oxide and carbon dioxide, to show the reaction clearly.
    • For citric acid and sodium hydrogencarbonate, state both observations: fizzing and a decrease in temperature.
    • Use the phrase energy taken in from the surroundings to explain why these reactions are endothermic.

    Try the lesson

    The start of the Energy transfer during exothermic and endothermic reactions: Endothermic reactions include thermal decompositions and the reaction of citric acid and sodium hydrogencarbonate. lesson, made from checked teaching notes for this specification point.

    Have a go first

    Which of these is an example of an endothermic reaction?

    Listen

    Thermal decomposition means breaking a compound down by heating, for example heating calcium carbonate to form calcium oxide and carbon dioxide; energy must be taken in continuously, so it is endothermic. The reaction of citric acid with sodium hydrogencarbonate is also endothermic: when the two solids or solutions mix, they fizz to produce carbon dioxide and the mixture cools. In both cases energy is taken in from the surroundings, so the temperature of the surroundings falls. These examples show that endothermic reactions are not limited to one type of chemistry; they include decomposition driven by heating and a reaction between an acid and a hydrogencarbonate. A strong answer earns marks for these points. Thermal decomposition is an endothermic process in which a compound is broken down by heating. A named thermal decomposition, such as calcium carbonate forming calcium oxide and carbon dioxide, releases carbon dioxide and requires energy input. The reaction of citric acid with sodium hydrogencarbonate is endothermic and produces carbon dioxide gas. In both examples, energy is taken in from the surroundings, so the temperature of the surroundings decreases. A common slip: Calling thermal decomposition exothermic because heat is applied. Instead, energy is taken in overall, so it is endothermic. Exam tip: Name the products in a thermal decomposition, for example calcium oxide and carbon dioxide, to show the reaction clearly.

    See it

    A top-down flowchart. The top node reads 'Endothermic reactions' and branches into two nodes: 'Thermal decomposition' and 'Citric acid and sodium hydrogencarbonate'. From 'Thermal decomposition' a node reads 'Compound broken down by heating', leading to 'Calcium carbonate heated', which leads to 'Calcium oxide and carbon dioxide'. From 'Citric acid and sodium hydrogencarbonate' two nodes branch out: 'Fizzing produces carbon dioxide' and 'Mixture cools'. Both 'Thermal decomposition' and 'Citric acid and sodium hydrogencarbonate' also connect to a node reading 'Energy taken in from surroundings', which leads to a final node reading 'Temperature of surroundings falls'.
    It shows two examples of endothermic reactions and how both take in energy from the surroundings so the temperature falls.

    Key words

    Say what each word means before you turn the card.

    Thermal decomposition

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    Temperature decrease as evidence

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    Energy input required for decomposition

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    See every definition
    Thermal decomposition
    Breaking a compound down by heating, for example heating calcium carbonate to form calcium oxide and carbon dioxide.
    Temperature decrease as evidence
    Energy is taken in from the surroundings, so the temperature of the surroundings falls.
    Energy input required for decomposition
    Energy must be taken in continuously, so thermal decomposition is endothermic.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node reads 'Endothermic reactions' and branches into two nodes: 'Thermal decomposition' and 'Citric acid and sodium hydrogencarbonate'. From 'Thermal decomposition' a node reads 'Compound broken down by heating', leading to 'Calcium carbonate heated', which leads to 'Calcium oxide and carbon dioxide'. From 'Citric acid and sodium hydrogencarbonate' two nodes branch out: 'Fizzing produces carbon dioxide' and 'Mixture cools'. Both 'Thermal decomposition' and 'Citric acid and sodium hydrogencarbonate' also connect to a node reading 'Energy taken in from surroundings', which leads to a final node reading 'Temperature of surroundings falls'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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