AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    If a reaction transfers energy to the surroundings the product molecules…

    Full specification wording

    Energy transfer during exothermic and endothermic reactions: If a reaction transfers energy to the surroundings the product molecules must have less energy than the reactants, by the amount transferred.

    In an exothermic reaction, the products have lower energy than the reactants because energy is transferred to the surroundings.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 3 of 12

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    In an exothermic reaction, the products have lower energy than the reactants because energy is transferred to the surroundings. The difference in energy between reactants and products equals the energy transferred. For example, in the combustion of methane, the chemical energy stored in the reactants is greater than that in the products; the excess is released as heat, raising the temperature of the surroundings. This concept explains why exothermic reactions cause temperature increases.

    What earns the marks

    • States that in an exothermic reaction, products have less energy than reactants.
    • Explains that the energy difference equals the energy transferred to the surroundings.
    • Relates the energy difference to bond breaking and bond making.
    • Uses a reaction profile diagram to show products at a lower energy level than reactants.
    • Applies the idea to a named exothermic reaction, such as combustion.

    Common mistakes and how to put them right

    • Thinking products have more energy in an exothermic reaction.

      Put it right by stating products have less energy because energy is released.

    • Assuming the energy transferred is lost.

      Put it right by explaining it is transferred to the surroundings, often as thermal energy.

    • Confusing the energy change with activation energy.

      Put it right by distinguishing the overall energy difference from the energy needed to start the reaction.

    Exam tips

    • Use reaction profile diagrams to show the energy levels of reactants and products.
    • State that the energy difference is transferred to the surroundings, not destroyed.
    • When explaining, refer to the energy stored in chemical bonds.

    Try the lesson

    The start of the Energy transfer during exothermic and endothermic reactions: If a reaction transfers energy to the surroundings the product molecules must have less energy than the reactants, by the amount transferred. lesson, made from checked teaching notes for this specification point.

    Have a go first

    A reaction transfers 30 kJ of energy to the surroundings. How does the energy of the product molecules compare with the reactants?

    Listen

    In an exothermic reaction, the products have lower energy than the reactants because energy is transferred to the surroundings. The difference in energy between reactants and products equals the energy transferred. For example, in the combustion of methane, the chemical energy stored in the reactants is greater than that in the products; the excess is released as heat, raising the temperature of the surroundings. This concept explains why exothermic reactions cause temperature increases. A strong answer earns marks for these points. States that in an exothermic reaction, products have less energy than reactants. Explains that the energy difference equals the energy transferred to the surroundings. Relates the energy difference to bond breaking and bond making. Uses a reaction profile diagram to show products at a lower energy level than reactants. A common slip: Thinking products have more energy in an exothermic reaction. Instead, stating products have less energy because energy is released. Exam tip: Use reaction profile diagrams to show the energy levels of reactants and products.

    See it

    A top-down flowchart with five boxes connected by arrows. The first box reads 'Reactants have higher energy' and points to the second box, 'Reaction transfers energy to the surroundings'. This points to the third box, 'Products have less energy than reactants', which points to the fourth box, 'Energy difference equals the energy transferred'. The fourth box points to the final box, 'Surroundings temperature increases'.
    It shows that in an exothermic reaction the reactants have higher energy, energy is transferred to the surroundings, and the products have less energy, with the difference equal to the energy transferred.

    Put it in order

    Put these steps in the order they happen.

    1. 1. Reaction transfers energy to the surroundings
    2. 2. Products have less energy than reactants
    3. 3. Reactants have higher energy
    4. 4. Surroundings temperature increases
    5. 5. Energy difference equals the energy transferred

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 2 boxes numbered instead of named. A top-down flowchart with five boxes connected by arrows. The first box reads 'Reactants have higher energy' and points to the second box, 'Reaction transfers energy to the surroundings'. This points to the third box, 'Products have less energy than reactants', which points to the fourth box, 'Energy difference equals the energy transferred'. The fourth box points to the final box, 'Surroundings temperature increases'.
    • 1Box 1

    • 2Box 2

    0 of 2 labelled

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