AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    The output is a line spectrum that can be analysed to identify the metal…

    Full specification wording

    Flame emission spectroscopy: The output is a line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations.

    The output of flame emission spectroscopy is a line spectrum.

    Checked against the AQA 8462 specification (opens in a new tab) on .

    • Point 3 of 4
    • 4 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    The output of flame emission spectroscopy is a line spectrum. Each metal ion produces a characteristic pattern of lines at particular wavelengths, so the positions of the lines can be used to identify which metal ions are present in the solution. The intensity, or brightness, of the lines relates to how much of each metal ion is present, so the spectrum can also be used to measure concentrations. This is often done by comparing the sample spectrum with spectra from solutions of known concentration, sometimes called calibration solutions. A more intense line means a higher concentration of that metal ion.

    What earns the marks

    • The output of flame emission spectroscopy is a line spectrum.
    • Each metal ion produces a characteristic pattern of lines at particular wavelengths.
    • The positions of the lines are used to identify which metal ions are present in the solution.
    • The intensity of the lines is related to the concentration of the metal ion.
    • Concentrations can be measured by comparing the sample spectrum with spectra from solutions of known concentration.
    • A more intense line indicates a higher concentration of that metal ion.

    Common mistakes and how to put them right

    • Saying the line spectrum shows a continuous rainbow.

      Put it right: A line spectrum has separate bright lines at specific wavelengths.

    • Saying the number of lines directly gives the concentration.

      Put it right: Line positions identify the metal ion and line intensity relates to concentration.

    • Saying the spectrum identifies non-metal ions.

      Put it right: Flame emission spectroscopy analyses metal ions.

    Exam tips

    • Distinguish clearly between line positions for identification and line intensity for concentration.
    • Mention comparison with known concentrations when explaining how concentration is measured.
    • Use the phrase characteristic pattern of lines to show why identification is possible.

    Try the lesson

    The start of the Flame emission spectroscopy: The output is a line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations. lesson, made from checked teaching notes for this specification point.

    Have a go first

    What is the output of flame emission spectroscopy that can be analysed to identify metal ions?

    Listen

    The output of flame emission spectroscopy is a line spectrum. Each metal ion produces a characteristic pattern of lines at particular wavelengths, so the positions of the lines can be used to identify which metal ions are present in the solution. The intensity, or brightness, of the lines relates to how much of each metal ion is present, so the spectrum can also be used to measure concentrations. This is often done by comparing the sample spectrum with spectra from solutions of known concentration, sometimes called calibration solutions. A more intense line means a higher concentration of that metal ion. A strong answer earns marks for these points. The output of flame emission spectroscopy is a line spectrum. Each metal ion produces a characteristic pattern of lines at particular wavelengths. The positions of the lines are used to identify which metal ions are present in the solution. The intensity of the lines is related to the concentration of the metal ion. A common slip: Saying the line spectrum shows a continuous rainbow: the error is confusing a line spectrum with a continuous spectrum. Instead, a line spectrum has separate bright lines at specific wavelengths. Exam tip: Distinguish clearly between line positions for identification and line intensity for concentration.

    See it

    A top-down flowchart. The top node reads 'Flame emission spectroscopy' and points down to 'Output is a line spectrum'. That points down to 'Characteristic pattern of lines at particular wavelengths', which splits into two branches. The left branch is 'Positions of the lines', leading down to 'Identify which metal ions are present'. The right branch is 'Intensity of the lines', leading down to 'Related to the concentration of the metal ion'. From there one arrow goes to 'Compare sample spectrum with spectra from solutions of known concentration', which leads to 'Measure concentrations'. A second arrow from the same node goes to 'A more intense line means a higher concentration'.
    It shows how the line spectrum from flame emission spectroscopy is used, with line positions identifying metal ions and line intensity, compared with known concentrations, measuring concentration.

    Key words

    Say what each word means before you turn the card.

    Line spectra

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    Identification of metal ions

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    Measurement of concentration

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    Calibration

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    See every definition
    Line spectra
    The output of flame emission spectroscopy, in which each metal ion produces a characteristic pattern of lines at particular wavelengths.
    Identification of metal ions
    Using the positions of the lines in the spectrum to identify which metal ions are present in the solution.
    Measurement of concentration
    Using the intensity of the lines, often by comparing the sample spectrum with spectra from solutions of known concentration.
    Calibration
    Comparing the sample spectrum with spectra from solutions of known concentration.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node reads 'Flame emission spectroscopy' and points down to 'Output is a line spectrum'. That points down to 'Characteristic pattern of lines at particular wavelengths', which splits into two branches. The left branch is 'Positions of the lines', leading down to 'Identify which metal ions are present'. The right branch is 'Intensity of the lines', leading down to 'Related to the concentration of the metal ion'. From there one arrow goes to 'Compare sample spectrum with spectra from solutions of known concentration', which leads to 'Measure concentrations'. A second arrow from the same node goes to 'A more intense line means a higher concentration'.
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