AQA · GCSE · Chemistry

    Course version: 8462 · Version from Sept 2018

    Atoms of the same element can have different numbers of neutrons; these…

    Full specification wording

    Size and mass of atoms: Atoms of the same element can have different numbers of neutrons; these atoms are called isotopes of that element.

    Isotopes are atoms of the same element that have the same number of protons (and therefore the same atomic number) but different numbers of neutrons.

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    Study notes

    From the checked teaching notes for this specification point.

    The idea

    Isotopes are atoms of the same element that have the same number of protons (and therefore the same atomic number) but different numbers of neutrons. This means they have different mass numbers. For example, chlorine has two common isotopes: chlorine-35 (17 protons, 18 neutrons) and chlorine-37 (17 protons, 19 neutrons). Because isotopes have the same electron configuration, they have identical chemical properties, but their physical properties may differ slightly due to different masses. Isotopes are represented using symbols like ³⁵Cl and ³⁷Cl. Understanding isotopes is essential for explaining relative atomic mass and radioactive decay.

    What earns the marks

    • Define isotopes as atoms of the same element with different numbers of neutrons.
    • State that isotopes have the same number of protons and electrons but different numbers of neutrons.
    • Give examples of isotopes, such as chlorine-35 and chlorine-37, or carbon-12 and carbon-14.
    • Explain that isotopes have the same chemical properties but different physical properties.
    • Calculate the relative atomic mass from isotopic abundances.

    Common mistakes and how to put them right

    • Thinking that isotopes have different numbers of protons.

      Put it right by emphasising that protons define the element and must be the same.

    • Confusing isotopes with ions.

      Put it right: Ions have different numbers of electrons, while isotopes have different numbers of neutrons.

    • Assuming isotopes have different chemical properties.

      Put it right by explaining that chemical properties depend on electron arrangement, which is the same.

    Exam tips

    • Remember that isotopes of an element have the same atomic number but different mass numbers.
    • Use the format 'element-mass number' (e.g., carbon-14) or symbol with superscript (e.g., ¹⁴C).
    • When calculating relative atomic mass, use the formula: (abundance₁ × mass₁ + abundance₂ × mass₂) / total abundance.

    Try the lesson

    The start of the Size and mass of atoms: Atoms of the same element can have different numbers of neutrons; these atoms are called isotopes of that element. lesson, made from checked teaching notes for this specification point.

    Have a go first

    What are isotopes? Select the correct answer.

    Listen

    Isotopes are atoms of the same element that have the same number of protons (and therefore the same atomic number) but different numbers of neutrons. This means they have different mass numbers. For example, chlorine has two common isotopes: chlorine-35 (17 protons, 18 neutrons) and chlorine-37 (17 protons, 19 neutrons). Because isotopes have the same electron configuration, they have identical chemical properties, but their physical properties may differ slightly due to different masses. Isotopes are represented using symbols like ³⁵Cl and ³⁷Cl. Understanding isotopes is essential for explaining relative atomic mass and radioactive decay. A strong answer earns marks for these points. Define isotopes as atoms of the same element with different numbers of neutrons. State that isotopes have the same number of protons and electrons but different numbers of neutrons. Give examples of isotopes, such as chlorine-35 and chlorine-37, or carbon-12 and carbon-14. Explain that isotopes have the same chemical properties but different physical properties. A common slip: Thinking that isotopes have different numbers of protons. Instead, emphasising that protons define the element and must be the same. Exam tip: Remember that isotopes of an element have the same atomic number but different mass numbers.

    See it

    A top-down flowchart. The top node reads 'Atoms of the same element' and branches to three nodes: 'Same number of protons', 'Different numbers of neutrons' and 'Called isotopes'. 'Same number of protons' leads to 'Same atomic number'. 'Different numbers of neutrons' leads to 'Different mass numbers'. 'Called isotopes' leads to 'Same electron configuration', which leads to 'Identical chemical properties'. 'Different mass numbers' leads to 'Physical properties may differ slightly'.
    Shows that isotopes are atoms of the same element with the same number of protons but different numbers of neutrons, giving the same chemical properties but slightly different physical properties.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node reads 'Atoms of the same element' and branches to three nodes: 'Same number of protons', 'Different numbers of neutrons' and 'Called isotopes'. 'Same number of protons' leads to 'Same atomic number'. 'Different numbers of neutrons' leads to 'Different mass numbers'. 'Called isotopes' leads to 'Same electron configuration', which leads to 'Identical chemical properties'. 'Different mass numbers' leads to 'Physical properties may differ slightly'.
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