AQA · A-Level · Chemistry

    Course version: 7405 · Version from Sept 2016

    A base is a proton acceptor.

    Full specification wording

    Brønsted–Lowry acid–base equilibria in aqueous solution (A-level only): A base is a proton acceptor.

    A base is a proton acceptor, and to accept a proton it must have a lone pair of electrons available to form the new bond.

    Checked against the AQA 7405 specification (opens in a new tab) on .

    • Point 2 of 3
    • 3 key terms

    Study notes

    From the checked teaching notes for this specification point.

    The idea

    A base is a proton acceptor, and to accept a proton it must have a lone pair of electrons available to form the new bond. Ammonia has a lone pair on nitrogen, so NH₃ + H₂O ⇌ NH₄⁺ + OH⁻: the ammonia takes a proton from water, and NH₄⁺ is its conjugate acid. This definition is wider than 'a substance that produces hydroxide ions', which would exclude ammonia and the carbonate ion altogether. An alkali is the narrower idea: a base that dissolves in water and so releases OH⁻(aq). Water itself is amphoteric, acting as a base towards HCl and as an acid towards NH₃, which is why it turns up on both sides of this topic and why its own slight dissociation matters later.

    What earns the marks

    • Defining a base as a proton acceptor or H⁺ acceptor.
    • Identifying the lone pair that accepts the proton.
    • Naming the conjugate acid formed when the base gains the proton.
    • Distinguishing an alkali as a base that dissolves to give OH⁻(aq).

    Common mistakes and how to put them right

    • Defining a base as a substance that produces hydroxide ions, which excludes ammonia.

    • Using base and alkali as interchangeable words.

    • Giving the conjugate acid of NH₃ as NH₂⁻, which is its conjugate base.

    • Forgetting that water can act as a base towards HCl and as an acid towards NH₃.

    Exam tips

    • If asked why a species can act as a base, point to the lone pair, not to a negative charge alone.
    • To write a conjugate acid, add one H⁺ and increase the charge by one.

    Try the lesson

    The start of the Brønsted–Lowry acid–base equilibria in aqueous solution (A-level only): A base is a proton acceptor. lesson, made from checked teaching notes for this specification point.

    Have a go first

    According to the Brønsted–Lowry definition, what does a base accept?

    Listen

    A base is a proton acceptor, and to accept a proton it must have a lone pair of electrons available to form the new bond. Ammonia has a lone pair on nitrogen, so NH₃ + H₂O ⇌ NH₄⁺ + OH⁻: the ammonia takes a proton from water, and NH₄⁺ is its conjugate acid. This definition is wider than 'a substance that produces hydroxide ions', which would exclude ammonia and the carbonate ion altogether. An alkali is the narrower idea: a base that dissolves in water and so releases OH⁻(aq). Water itself is amphoteric, acting as a base towards HCl and as an acid towards NH₃, which is why it turns up on both sides of this topic and why its own slight dissociation matters later. A strong answer earns marks for these points. defining a base as a proton acceptor or H⁺ acceptor. identifying the lone pair that accepts the proton. naming the conjugate acid formed when the base gains the proton. distinguishing an alkali as a base that dissolves to give OH⁻(aq). Exam tip: If asked why a species can act as a base, point to the lone pair, not to a negative charge alone.

    See it

    A top-down flowchart. The top node reads 'Base: proton acceptor'. An arrow leads down to 'Must have a lone pair to form the new bond', which leads to 'Ammonia has a lone pair on nitrogen', which leads to the equation 'NH₃ + H₂O ⇌ NH₄⁺ + OH⁻'. From the equation, two arrows branch out: one to 'Ammonia takes a proton from water' and one to 'NH₄⁺ is the conjugate acid'. From the top node 'Base: proton acceptor', two further arrows branch out: one to 'Alkali: a base that dissolves in water and releases OH⁻(aq)' and one to 'Water is amphoteric: a base towards HCl, an acid towards NH₃'.
    It shows that a base is a proton acceptor needing a lone pair, illustrated by ammonia accepting a proton from water to form its conjugate acid, with alkali and amphoteric water as related ideas.

    Key words

    Say what each word means before you turn the card.

    Brønsted–Lowry base

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    conjugate acid

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    amphoteric water

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    See every definition
    Brønsted–Lowry base
    A proton acceptor, which must have a lone pair of electrons available to form the new bond.
    conjugate acid
    The species formed when a base gains a proton, such as NH₄⁺ formed when ammonia takes a proton from water.
    amphoteric water
    Water can act as a base towards HCl and as an acid towards NH₃, so it turns up on both sides of this topic.

    Label the diagram

    Some boxes have lost their names. Pick the right name for each number.

    The diagram again, with 3 boxes numbered instead of named. A top-down flowchart. The top node reads 'Base: proton acceptor'. An arrow leads down to 'Must have a lone pair to form the new bond', which leads to 'Ammonia has a lone pair on nitrogen', which leads to the equation 'NH₃ + H₂O ⇌ NH₄⁺ + OH⁻'. From the equation, two arrows branch out: one to 'Ammonia takes a proton from water' and one to 'NH₄⁺ is the conjugate acid'. From the top node 'Base: proton acceptor', two further arrows branch out: one to 'Alkali: a base that dissolves in water and releases OH⁻(aq)' and one to 'Water is amphoteric: a base towards HCl, an acid towards NH₃'.
    • 1Box 1

    • 2Box 2

    • 3Box 3

    0 of 3 labelled

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