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    Reactions of alkenes — AQA GCSE Chemistry

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    Reactions of alkenes explained

    Alkenes are a homologous series of unsaturated hydrocarbons whose molecules contain at least one carbon-carbon double bond, C=C.

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    This double bond is the functional group: the reactive part that gives the series its characteristic chemistry. Because of the C=C double bond, alkene molecules contain fewer hydrogen atoms than the maximum possible, meaning they are not saturated with hydrogen. Ethene, C₂H₄, is the simplest alkene; propene, C₃H₆, and butene, C₄H₈, follow. The general formula CₙH₂ₙ applies to non-cyclic alkenes with one double bond. Students should draw the displayed formula of ethene, recognise the C=C in a larger molecule, and distinguish alkenes from the saturated alkanes, which contain only single C–C bonds.

    Your focus

    1. Define an alkene as a hydrocarbon containing the C=C functional group.
    2. Draw and interpret the displayed formula of ethene and other simple alkenes.
    3. Use the general formula CₙH₂ₙ to deduce the molecular formula of a non-cyclic alkene.

    Reactions of alkenes exam tips

    Marking Points
    • Alkenes are hydrocarbons: their molecules contain carbon and hydrogen only.
    • The functional group of an alkene is the carbon-carbon double bond, C=C.
    • The C=C makes an alkene unsaturated, because the carbons are bonded to fewer hydrogen atoms than the maximum possible.
    • Ethene, C₂H₄, is the simplest alkene and its displayed formula shows a double line between the two carbon atoms.
    • The general formula of a non-cyclic alkene with one C=C is CₙH₂ₙ, so ethene is C₂H₄ and propene is C₃H₆.
    • Alkanes are saturated and contain only single carbon-carbon bonds, so they are a different homologous series from alkenes.
    Examiner Tips
    • 💡When asked to identify an alkene, locate the C=C and state that the compound is unsaturated.
    • 💡Use the general formula CₙH₂ₙ to deduce a molecular formula, then check that the structure contains one C=C.
    • 💡In displayed formulae, draw the double bond as two parallel lines between the carbon atoms and complete the outer shells with hydrogen atoms.
    Common Mistakes
    • Calling any hydrocarbon with a double bond an alkane; the correct term is alkene, and the C=C must be identified.
    • Writing the general formula as CₙH₂ₙ₊₂, which describes alkanes; the correct alkene formula is CₙH₂ₙ.
    • Drawing ethene with a single C–C bond; the corrected displayed formula must show C=C.