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    Structure and formulae of alkenes — AQA GCSE Chemistry

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    Structure and formulae of alkenes explained

    Alkenes are a homologous series of unsaturated hydrocarbons.

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    Their defining feature is a double covalent bond between two carbon atoms, written as C=C. Ethene has the formula C₂H₄, with two carbon atoms joined by a double bond and two hydrogen atoms bonded to each carbon. The double bond means alkenes have two fewer hydrogen atoms than the corresponding alkane, so ethene is C₂H₄ while ethane is C₂H₆. The double bond makes alkenes reactive, so they undergo addition reactions, decolourise bromine water and can join together in addition polymerisation. General formula is CₙH₂ₙ for the chain members studied.

    Your focus

    1. Define an alkene as a hydrocarbon containing a C=C double bond.
    2. Draw and interpret the structure and formula of ethene.
    3. Explain how the double bond makes alkenes unsaturated and reactive.

    Structure and formulae of alkenes exam tips

    Marking Points
    • Alkenes contain only carbon and hydrogen, so they are hydrocarbons.
    • The defining feature is a double covalent bond between two carbon atoms, shown as C=C.
    • Ethene is C₂H₄ and has a C=C double bond with two hydrogen atoms on each carbon.
    • Alkenes are unsaturated because they have fewer hydrogen atoms than the corresponding alkane.
    • The double bond makes alkenes reactive, so they undergo addition reactions and addition polymerisation.
    • The general formula of the alkene homologous series is CₙH₂ₙ.
    Examiner Tips
    • 💡Show the double bond clearly in displayed and structural formulae.
    • 💡Use the word unsaturated and link it to the C=C bond.
    • 💡Check hydrogen counts: ethene C₂H₄, propene C₃H₆, butene C₄H₈.
    Common Mistakes
    • Drawing ethene with a single C-C bond; correction: draw C=C with two shared pairs of electrons.
    • Saying alkenes are saturated; correction: alkenes are unsaturated because of the C=C double bond.
    • Using the alkane general formula CₙH₂ₙ₊₂ for alkenes; correction: use CₙH₂ₙ for alkenes.