position of equilibrium
What position of equilibrium means in Chemistry A-Level, as defined for AQA, OCR.
Definitions of position of equilibrium
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Reference: AQA
In water, ethylamine sets up an equilibrium with water, and that equilibrium lies well to the left, so only a small fraction of the molecules are protonated at any moment.
Estimated from the magnitude of Kc, it lies to the right when products dominate and to the left when reactants dominate, rather than the reaction going to completion.
It shifts in a direction, to the left or to the right, or towards a named side, and the principle predicts direction only, never how far or how fast.
For a weak acid the equilibrium lies well to the left, as typically fewer than two molecules in a hundred have donated a proton at any moment.
Because these are equilibria, the reaction need not go to completion, and the position tells you about relative strengths.
Shifted towards the product when a volatile product is removed as it forms, as in an esterification.
Topics that use position of equilibrium
- Base properties (A-level only) (AQA A-Level)
- Brønsted–Lowry acid–base equilibria in aqueous solution (A-level only) (AQA A-Level)
- Chemical equilibria and Le Chatelier's principle (AQA A-Level)
- Weak acids and bases, Ka, for weak acids (A-level only) (AQA A-Level)
- Chemical equilibrium (OCR A-Level)
- Nitrogen compounds, polymers and synthesis - 6.2.5 Organic synthesis (OCR A-Level)
Related terms
- closed system
- constant concentrations
- dynamic equilibrium
- equal forward and reverse rates
- homogeneous equilibria
- Le Chatelier's principle
- strength versus concentration
- approximations
Using position of equilibrium in the exam
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