Chemistry GCSE
Chemistry GCSE glossary
1283 key terms for Chemistry GCSE, A to Z, each linked to the topic pages that use it.
1283 terms found. Open a term to try a short memory check.
A
- Abbreviated LCA
- A shortened assessment that studies only chosen stages or impacts rather than the full life cycle.AQA
- Absence of oxygen
- There was little or no oxygen gas in the early atmosphere, and the atmospheres of Mars and Venus today contain almost no oxygen.AQA
- Absorption and re-emission of radiation
- Greenhouse gas molecules absorb infrared radiation because their bonds can vibrate at frequencies matching that energy, and the absorbed energy is re-emitted…AQA
- Absorption of infrared radiation
- Greenhouse gases take in some of the outgoing longer wavelength infrared radiation that Earth re-emits after its surface warms.AQA
- Abundance
- How much of each isotope of an element is present, which the weighted average reflects.AQA
- Acceptance of scientific models
- A scientific model becomes accepted when its predictions match what experiments show, and agreement makes the model more widely accepted at the time.AQA
- Accuracy
- How close a measurement is to the true or accepted value.OCR
- Accurate
- Describes a method that measures a physical property precisely and compares it with reference data.AQA
- Accurate measurement of volume
- Using accurate procedural techniques, such as rinsing the burette with the acid and reading the bottom of the meniscus at eye level, to ensure precise volume…AQA
- Acid rain formation
- Sulfur dioxide dissolves in atmospheric water to form acid rain, which corrodes limestone buildings and acidifies lakes, damaging aquatic life.AQA
- Acid reactions
- Reactions in which acids react with some metals to produce salts and hydrogen.AQA
- Acid reactions with carbonates
- Carboxylic acids fizz with carbonates, producing a salt, water and carbon dioxide, for example sodium ethanoate from ethanoic acid and sodium carbonate.AQA
- Acid reactions with insoluble bases
- The solid may be a metal, a metal oxide, a metal hydroxide or a metal carbonate, and the acid dissolves the solid so a salt forms in solution.AQA
- Acid-base reactions
- Acids are neutralised by alkalis, which are soluble bases, and by bases, which include insoluble metal hydroxides and metal oxides, to produce salts and water.AQA
- Acid–carbonate reactions
- Reactions in which a carbonate reacts with a dilute acid to produce a salt, water and carbon dioxide.AQA
- Acidic gas pollution
- Sulfur dioxide and oxides of nitrogen are acidic gases released when fuels burn, and they cause respiratory problems and acid rain.AQA
- Acidic solution
- An aqueous solution of an acid has a pH value of less than 7, and the lower the number, the more acidic the solution.AQA
- Acids
- In aqueous solution, these produce hydrogen ions, H⁺.AQA
- Activation
- Removing a seal, pulling a tab or pressing a button so that reactants mix or air enters.AQA
- Activation energy
- The minimum amount of energy that particles must have to react, shown on a reaction profile as the vertical gap from the reactant energy level up to the peak…AQA
- Activation energy as an energy barrier
- The energy needed for a reaction to occur, labelled as the vertical gap from the reactant level to the peak.AQA
- Actual yield
- The amount of product that is obtained in practice, which is often lower than the theoretical yield.AQA
- addition polymer
- A long-chain saturated molecule made of repeating units, recognised from diagrams showing a saturated carbon chain.AQA
- Addition polymerisation
- A reaction in which no other molecule is formed, so the repeating unit of the polymer has the same atoms as the monomer.AQA
- Addition reaction
- A reaction in which bromine adds across the carbon–carbon double bond of an alkene, so the orange colour is decolourised and the mixture turns colourless.AQA
- Addition reactions
- Reactions in which the C=C double bond opens and two new single bonds form, so each of the two carbons forms a new single bond.AQA
- Addition reactions of alkenes
- The alkene adds bromine across its double bond in an addition reaction, decolourising the bromine water.AQA
- Aerobic biological treatment
- Treatment of effluent where microorganisms with oxygen break down remaining organic matter.AQA
- Age of the Earth
- The Earth is about 4.6 billion years old, an approximate value supported by evidence from meteorites and rocks.AQA
- Agricultural production
- Products that are grown or farmed, such as crops and livestock.AQA
- Agricultural productivity
- Chemistry improves agricultural processes by producing fertilisers that replace nutrients removed from soil by crops, so more food can be grown on the same…AQA
- Agriculture
- A human-managed supplement to naturally occurring resources, providing food, timber, clothing and fuels.AQA
- Alcohols
- A homologous series of organic compounds containing the –OH functional group, whose names end in -ol.AQA
- Algebraic rearrangement and unit consistency
- Changing the subject of a mathematical equation using inverse operations and keeping units consistent, converting between dm³ and cm³ where needed.AQA
- alkali metals
- The elements in Group 1 of the periodic table, which have characteristic properties because of the single electron in their outer shell.AQA
- Alkaline batteries
- A common example of non-rechargeable batteries, which are discarded once flat.AQA
- Alkaline properties and pH
- The presence of OH⁻ ions is linked to alkaline properties such as high pH, and the concentration of OH⁻ ions determines the pH value, with more OH⁻ giving a…AQA
- Alkaline solution
- An aqueous solution of an alkali has a pH value greater than 7, and the higher the number, the more alkaline the solution.AQA
- Alkalis
- In aqueous solution, these produce hydroxide ions, OH⁻.AQA
- Alkane
- A compound such as ethane that has no double bond, so no addition occurs and the orange colour remains, distinguishing it from an alkene.AQA
- Alkanes
- Hydrocarbons that have only single carbon–carbon bonds and are saturated, and are useful as fuels.AQA
- Alkenes
- Hydrocarbons that contain at least one carbon–carbon double bond and are unsaturated, and are reactive starting materials for making polymers.AQA
- Allotrope
- Different structural forms of the same element in the same physical state.OCR
- Allotropes of carbon
- Forms such as diamond and graphite that contain only carbon atoms but have different structural arrangements.AQA
- Alloy
- A mixture of a metal with other elements, such as iron with chromium, nickel and carbon.AQA
- Alloy as a mixture containing different-sized atoms
- A mixture of a metal with other elements, often other metals, whose atoms are a different size from the atoms of the main metal.AQA
- Alloys
- Mixtures of metals with small amounts of other elements added to improve strength or resistance to corrosion.AQA
- Alloys in everyday use
- Gold used as jewellery is usually an alloy with silver, copper and zinc, an everyday example of how alloying changes the properties of a metal.AQA
- Alloys of copper
- Bronze and brass are both alloys based on copper, but they contain different second metals.AQA
- Alpha particle scattering
- Alpha particles were fired at thin gold foil; most passed straight through, some were deflected through small angles, and a very small number bounced back.AQA
- Alpha-particle scattering evidence
- Most alpha particles passed straight through thin gold foil, but a few were deflected strongly, and some bounced back.AQA
- Alternative metal extraction
- Methods that can obtain metals from low-grade ores or waste, but which may be slower or need different conditions.AQA
- Alternative pathway
- A different route for the reaction that a catalyst provides, having a lower activation energy.AQA
- Aluminium alloy
- A mixture of aluminium with other elements such as magnesium, manganese, silicon or copper.AQA
- Amide links
- The link formed when the amine group of one amino acid reacts with the carboxylic acid group of another, releasing water.AQA
- Amine groups
- A functional group, –NH₂, contained in an amino acid molecule.AQA
- Ammonia
- The product of the Haber process, which can be used to produce nitrogen-based fertilisers.AQA
- Ammonia as a feedstock
- A versatile starting material because it is a base and a source of nitrogen, used to manufacture ammonium salts and nitric acid.AQA
- Amounts of substance
- The amount in moles, from which the number of particles is found by multiplying by 6.02 × 10²³.AQA
- Anaerobic conditions
- Conditions without oxygen, which favour fermentation rather than aerobic respiration.AQA
- Anaerobic digestion
- Treatment of sewage sludge in which microorganisms break it down without oxygen, reducing its volume and producing biogas that can be used as fuel.AQA
- Anions
- Negatively charged ions, which move to the positive electrode, the anode.AQA
- Anode
- The positive electrode, towards which negatively charged ions move because opposite charges attract.AQA
- Applications of endothermic reactions
- Sports injury packs use an endothermic reaction to cool an injury and reduce swelling and pain.AQA
- Applications of nanoparticles
- The effect depends on the application, such as catalysis, sun cream or medicine, where a smaller quantity may be effective.AQA
- Applying knowledge to unfamiliar products
- Suggesting why a component is included or how changing its amount would alter the product, using the evidence given rather than assumptions.AQA
- Appropriate technology and sustainability
- A suitable treatment is chosen based on the source, such as filtration and chlorination for fresh water or desalination for sea water or water with high salt…AQA
- Aqueous
- Dissolved in water, shown by (aq), used for acids and solutions of ionic compounds rather than (l).AQA
- Atmospheric carbon dioxide decrease
- The reduction in the percentage of carbon dioxide in the atmosphere caused by algae and plants carrying out photosynthesis.AQA
- Atmospheric evolution
- The change in the composition of the atmosphere over billions of years as photosynthesis removed carbon dioxide and added oxygen.AQA
- Atmospheric pollution
- Released substances such as carbon monoxide, sulfur dioxide and oxides of nitrogen enter the atmosphere and cause problems such as acid rain, respiratory harm…AQA
- Atom
- The smallest part of an element that can exist.AQA
- Atom economy
- A measure of the amount of starting materials that end up as useful products, also called atom utilisation.AQA, OCR
- Atom utilisation
- Another name for atom economy, the measure of the amount of starting materials that end up as useful products.AQA
- Atomic (proton) number
- The number of protons in the nucleus, which equals the number of electrons in a neutral atom.AQA
- Atomic dimensions in metres
- The typical radius of an atom is about 0.1 nm, which is 1 × 10⁻¹⁰ m.AQA
- Atomic emission
- When a sample is vaporised in a flame, excited electrons fall back to lower energy levels and emit light of characteristic wavelengths.AQA
- Atomic neutrality
- Atoms are neutral overall when proton and electron numbers are equal, and ions form when electrons are gained or lost.AQA
- Atomic number
- The number of protons in an atom of an element, which identifies the element and fixes its position in the periodic table.AQA, OCR
- Atomic number ordering
- Elements are arranged in order of atomic number, and after a set number of elements a new period begins.AQA
- Atomic structure and electron shells
- Atoms lower in Group 1 have more electron shells and a larger atomic radius.AQA
- Atomic structure and periodic table position
- An element's position in the periodic table reflects its atomic structure, because elements are arranged in order of atomic number, so proton number…AQA
- Atoms and molecules
- Typical atoms are about 0.1 to 0.5 nm across and small molecules are often about 0.5 to 2 nm across.AQA
- Attraction between shared electrons and nuclei
- Covalent bonds are strong because the shared pair is attracted to both nuclei.AQA
- Avogadro constant
- The number of atoms, molecules or ions in a mole of a given substance, with a value of 6.02 × 10²³ per mole.AQA
B
- Balanced chemical equation
- A symbol equation in which coefficients are adjusted so that the number of atoms of each element is the same on both sides.AQA
- Balanced chemical equations
- A balanced symbol equation for a named carbonate and dilute acid, including state symbols where required.AQA
- Balanced equation
- A symbol equation in which the number of atoms of each element is equal on both sides, achieved by placing whole-number coefficients in front of formulae.AQA
- Balanced equations
- Used to identify the mole ratio between the two reactants, which is applied to find moles of the second solution.AQA
- Balanced equations and coefficients
- Each species' Mᵣ must be multiplied by its coefficient in the balanced equation, and the equation must be balanced before totals can be compared.AQA
- Balanced equations and mole ratios
- A balanced equation gives the mole ratio of gaseous reactants and products, and its coefficients can be used to set the volume ratio.AQA
- Balanced equations as mole ratios
- A balanced symbol equation shows the ratio in which particles react, and that same ratio applies to amounts in moles.AQA
- Balanced half equation
- An equation showing the ion, product and electrons with correct formulae and state symbols, balanced so atoms and total charge are equal on both sides.AQA
- Balanced symbol equations
- Symbol equations which are balanced in terms of the numbers of atoms of each element involved on both sides of the equation.AQA
- Balancing chemical equations
- Checking that each element has the same number of atoms on both sides, for example counting atoms of each element on both sides of the equation.AQA
- Balancing equations
- A balanced symbol equation can show the oxidation, checking that every element is balanced on each side.AQA
- Balancing symbol equations
- Writing the balanced symbol equation using those whole numbers as balancing numbers.AQA
- Barium chloride solution
- The reagent added dropwise that supplies barium ions, which combine with sulfate ions.AQA
- Barium chloride with dilute hydrochloric acid
- A test used for sulfate ions, giving a white precipitate.AQA
- Barrier protection
- A coating that stops oxygen and water reaching the metal surface, so corrosion cannot start.AQA
- Barriers to change
- Reasons why actions may be limited, such as renewable sources being unreliable or costly to install, or governments and individuals lacking money or motivation.AQA
- Battery
- Consists of two or more cells connected together in series to provide a greater voltage.AQA
- Benefits and risks
- New applications can bring benefits such as greater efficiency, lower material use or new functions, but possible risks to health and the environment must…AQA
- Benefits and risks of nanotechnology
- The useful properties of nanoparticulate materials must be weighed against drawbacks such as possible toxicity, unknown long-term effects and the difficulty…AQA
- Benefits versus drawbacks
- Comparing benefits such as low mass or targeted delivery with drawbacks such as possible toxicity, uncertain long-term effects and environmental impact, then…AQA
- Bias
- Selecting or emphasising only part of the evidence, or presenting one side more strongly.AQA
- Bioleaching
- Bacteria obtain energy by breaking down metal sulfide ores, producing a solution containing metal ions that can be processed to obtain the metal.AQA
- Biological importance of DNA
- DNA carries coded information needed by living organisms, which is passed from parents to offspring.AQA
- Blast furnace
- Where iron is extracted from iron ore by reduction with carbon.AQA
- Blast furnace chemistry
- In the industrial extraction of iron, carbon is added but first reacts to form carbon monoxide, which acts as the main reducing agent.AQA
- Bleaching
- The removal of colour from damp litmus paper by chlorine, so that the paper turns white because the dye is destroyed.AQA
- Blue glass
- Placed between the eye and the flame to absorb yellow light so that a lilac colour becomes visible.AQA
- Boiling
- Heating a liquid so particles gain enough energy to overcome the forces between them and escape as a gas throughout the liquid.AQA
- Boiling point
- Increases as molecular size increases because stronger intermolecular forces require more energy to overcome.AQA
- Boiling point and molecular size
- Hydrocarbons with low boiling points are typically small molecules and travel further up the column before condensing, while those with high boiling points…AQA
- Boiling point elevation
- An impure substance boils above the known boiling point, and the change happens over a range of temperatures.AQA
- Bond breaking
- Energy must be supplied to break bonds in the reactants, because the atoms are pulled apart against the attraction holding them together.AQA
- Bond breaking and bond forming energy balance
- Overall energy is absorbed because bond breaking takes in more energy than bond forming releases.AQA
- Bond breaking and bond making
- Energy is absorbed when bonds break in the reactants, and energy is released when new bonds form in the products.AQA
- Bond energies
- Supplied values in kJ mol⁻¹ used to total the energy absorbed for bonds broken and the energy released for bonds made.AQA
- Bond energy
- The amount of energy required to break one mole of a particular covalent bond.AQA
- Bond formation
- Exothermic, because energy is released as new bonds form and the system becomes more stable.AQA
- Bond making
- Energy is released when bonds in the products are formed, as the atoms come together into a lower-energy arrangement.AQA
- Bond strength and energy transfer
- A large amount of energy is needed to break covalent bonds, so they remain intact during physical changes such as melting and boiling.AQA
- Bonding and forces between particles
- The temperature of a change of state is linked to the type and strength of bonding or forces between particles.AQA
- Brackets
- A grouping in a formula where a subscript after the bracket multiplies every element inside the bracket.AQA
- Brittle
- Describes a material that cannot absorb much energy by bending, so it tends to crack or shatter rather than deform when struck or overloaded.AQA
- Bromine water
- An orange solution used to test for a carbon–carbon double bond, added to the sample and shaken, with the colour recorded before and after.AQA
- Bromine water test
- Shaking a substance with bromine water, which changes from orange to colourless, to identify ethene.AQA
- Buckminsterfullerene
- A spherical fullerene, C₆₀, whose surface is made from hexagons and pentagons.AQA
- Build-up of nitrogen in the atmosphere
- Nitrogen gradually built up in the atmosphere because it is relatively unreactive and was not removed by reactions or dissolving in the oceans.AQA
- Bulk properties
- The familiar properties of the material that coarse particles usually show because most of their atoms are inside the particle rather than at its surface.AQA
- Burette
- A piece of apparatus filled with the acid, from which the acid is added gradually while the flask is swirled.AQA
C
- Calibration
- Comparing the sample spectrum with spectra from solutions of known concentration.AQA
- Carbon cycle and carbon stores
- Carbon dioxide is removed from the atmosphere when carbon becomes locked into solid or buried stores rather than remaining as a gas.AQA
- Carbon dioxide
- A greenhouse gas released by burning fossil fuels such as coal, oil and natural gas.AQA
- Carbon dioxide and methane reduction
- Cutting emissions by using renewable sources, improving energy efficiency, using public transport or electric vehicles, and capturing landfill gas or reducing…AQA
- Carbon dioxide sources
- Burning fossil fuels such as coal, oil and natural gas, and deforestation, which reduces photosynthesis so less carbon dioxide is removed from the atmosphere.AQA
- Carbon footprint
- The total amount of carbon dioxide and other greenhouse gases emitted over the full life cycle of a product, service or event.AQA
- Carbon monoxide
- Produced by partial oxidation of carbon in the fuel when oxygen is limited.AQA
- Carbon nanotubes
- Cylindrical fullerenes with variable lengths, forming extended structures rather than simple molecules.AQA
- Carbonate reactions
- Metal carbonates neutralise acids but produce carbon dioxide as well as salt and water.AQA
- Carboxylic acid
- A compound containing the –COOH functional group, which can be identified from a displayed, structural or molecular formula.AQA
- Carboxylic acid groups
- A functional group, –COOH, contained in an amino acid molecule.AQA
- Carboxylic acids
- Compounds that contain the –COOH group, from which alcohols are distinguished.AQA
- Catalysis
- Transition metals act as catalysts, for example manganese(IV) oxide catalyses the decomposition of hydrogen peroxide.AQA
- Catalysis in industrial and laboratory reactions
- Transition elements and their compounds are useful catalysts, for example iron catalyses the Haber process and nickel catalyses hydrogenation.AQA
- Catalyst
- A substance that increases the rate of reaction by providing an alternative pathway with a lower activation energy, and is regenerated at the end of it.AQA, OCR
- Catalysts
- Nanoparticles provide a large surface area for reactions, so a smaller quantity may be effective.AQA
- Catalytic cracking
- Hydrocarbon vapour is passed over a hot catalyst, commonly a zeolite, at a high temperature, and the catalyst allows reaction at a lower temperature than…AQA
- Catalytic oxidation
- Ammonia is oxidised industrially, typically over a heated catalyst, to nitrogen monoxide, which is further oxidised to nitrogen dioxide and dissolved in water…AQA
- Catenation and structural variety in carbon compounds
- Carbon atoms bond to one another, forming chains, branched chains and rings of varying length, which generates structural variety.AQA
- Cathode
- The negative electrode, towards which positively charged ions move because opposite charges attract.AQA
- Cations
- Positively charged ions, which move to the negative electrode, the cathode.AQA
- Causal mechanisms
- Warmer air holds more water vapour, ice melts and ocean water expands, altering weather patterns, sea level and habitats.AQA
- Cell
- A device that converts chemical energy into electrical energy, containing chemicals which react to produce electricity.AQA
- Ceramics
- Glass is a ceramic material made mainly from sand, which is silicon dioxide.AQA
- Chain growth
- Two functional groups per monomer allow chain growth in two directions, while a monomer with only one functional group would terminate chain growth.AQA
- Changes of state
- Energy is transferred during a change of state, but the temperature stays constant until the change is complete.AQA
- Char or decompose
- What a thermosetting polymer may do at very high temperatures instead of melting, because the covalent bonds of the network are too strong to be overcome.AQA
- Characteristic colours of metal hydroxides
- Copper(II) forms a blue precipitate, iron(II) a green precipitate and iron(III) a brown precipitate.AQA
- Characteristic flame colours of metal cations
- Lithium, sodium, potassium, calcium and copper compounds produce distinctive colours in flame tests, and the colour is characteristic of the metal cation…AQA
- Characteristic line spectra
- The instrument separates the emitted light into a line spectrum, and the pattern of lines identifies the metal.AQA
- characteristic properties
- Features explained by the single outer electron: soft, low density, shiny when freshly cut but tarnishing quickly, and reacting vigorously with water, oxygen…AQA
- Charge and relative numbers of protons and electrons
- Loss of electrons produces a positive ion because the number of protons now exceeds the number of electrons, and the size of the charge matches the number of…AQA
- Charge balance
- The overall compound is neutral because the total positive charge equals the total negative charge, which helps work out formulas.AQA
- Charge balance in atoms
- The positive and negative charges balance, so the atom has no overall charge.AQA
- Charge carriers
- Charged particles, such as ions or delocalised electrons, that are free to move and are required for conduction.AQA
- Charge flow in circuits
- The movement of ions through the electrolyte allows charge to flow and completes the circuit.AQA
- Charge notation for ions
- The ion symbol carries a superscript charge whose sign shows the direction of electron transfer, as in Mg²⁺ and O²⁻.AQA
- Chemical amount
- A quantity measured in moles, where the symbol for the unit mole is mol.AQA
- Chemical behaviour and ion formation
- Metals generally form positive ions when they react, and this behaviour applies to the majority of elements.AQA
- Chemical bonding
- There are three types of strong chemical bonds: ionic, covalent and metallic, which hold atoms or ions together in compounds and elements.AQA
- Chemical bonding and bond breaking
- The elements in a compound are held together by chemical bonds, so separating them requires breaking those bonds.AQA
- Chemical change
- A change in which one or more new substances form, with different properties from the reactants, because atoms are rearranged into different combinations.AQA
- Chemical combination of elements
- A compound contains two or more different elements joined by chemical bonds, not just mixed together.AQA
- Chemical formula
- Shows the number and type of atoms in a substance.AQA
- Chemical formulae
- A way of representing compounds, such as NaCl or H₂O.AQA
- Chemical reactions
- The process by which compounds are formed from elements, involving the formation of chemical bonds between atoms.AQA
- Chemical stability
- A stable arrangement of electrons, which a full outer shell provides.AQA
- Chemical symbol
- A representation of an atom of each element, usually one or two letters, where the first letter is always a capital and the second letter, if present, is…AQA
- Chemical treatment of pollutants
- Chemical methods such as neutralisation, precipitation or adsorption onto activated carbon, used with physical separation to remove substances from waste water.AQA
- Chemical versus physical properties
- Chemical properties are unchanged in a mixture, while physical properties such as melting point and boiling point may change because the components affect…AQA
- Chemical versus physical separation
- Because the metal is chemically bonded in the compound, chemical reactions are needed to extract it, as physical separation alone cannot break the…AQA
- Chlorination
- Sterilisation of water, often used to kill microbes.AQA
- Chlorine
- Added as a gas or in a solution, it kills microbes by disrupting their cell processes and provides some residual protection as water travels through pipes.AQA
- Choosing fuels for particular uses
- The choice of fuel depends on matching these properties to the intended use, for example a gas for a quick hot flame and a liquid for storage and transport.AQA
- Chromatography
- A separation technique in which a mixture is carried by a mobile phase through a stationary phase, and substances separate because they move at different rates.AQA
- Classification of elements
- Elements can be distinguished as metal or non-metal by their location in the periodic table rather than by memorising every element.AQA
- Climate modelling
- Computer models that predict climate change have limitations because they may simplify processes, rely on incomplete data, or struggle to represent clouds and…AQA
- Climate versus weather
- Weather is short term and local, whereas climate is long term and average.AQA
- Closed System
- A system in which no substances can enter or leave during a reaction.OCR
- Closed systems
- Apparatus which prevents the escape of reactants and products, so no reactants or products can escape.AQA
- Closed systems and gas exchange
- In a closed system the total mass before and after a reaction is unchanged, but an apparent mass change is usually because a gas has escaped or a gas from the…AQA
- Cloudiness
- Caused by calcium carbonate forming as a precipitate when carbon dioxide reacts with calcium hydroxide.AQA
- Coarse particles
- Larger particles, typically with diameters from about 1 × 10⁻⁵ m to 2.5 × 10⁻⁶ m, commonly called dust.AQA
- Coefficient
- A number in normal script before a formula that multiplies the whole formula unit, so every atom in that formula unit is multiplied.AQA
- Coefficients
- Whole-number multipliers placed in front of chemical formulae to balance an equation, never changing the formulae themselves.AQA
- Collision frequency
- The number of collisions per second between reactant particles, which rises when concentration, pressure or surface area is increased.AQA
- Collision theory
- For a reaction to happen, particles must collide with at least the activation energy, and the rate depends on the frequency and energy of collisions between…AQA
- Collisions
- Particles collide constantly, but most do nothing because the particles simply bounce apart; only those with energy at or above the activation energy can react.AQA
- Colour changes
- The change observed as the halogen formed appears, for example orange for bromine and brown for iodine.AQA
- Coloured compounds
- Transition metals form coloured compounds, for example hydrated copper(II) sulfate is blue and cobalt(II) chloride is pink in aqueous solution.AQA
- Coloured transition element compounds
- Compounds of transition elements are often coloured, such as blue copper(II) sulfate, yellow-brown iron(III) chloride and purple potassium manganate(VII).AQA
- Colourless
- Carbon monoxide has no colour, so it cannot be seen.AQA
- Combustion
- Burning a fuel in oxygen, releasing energy as bonds form in the products.AQA
- Combustion and oxidation
- Oxygen supports combustion more effectively than air, so the glowing tip bursts back into flame.AQA
- Combustion products
- The products of complete combustion are carbon dioxide and water, with carbon oxidised to carbon dioxide and hydrogen oxidised to water.AQA
- Combustion reactions
- Burning a fuel in oxygen, releasing energy, and in a hydrocarbon producing carbon dioxide and water vapour when complete.AQA
- Comparative LCA
- A simple comparison that sets the same stages side by side for two products, such as shopping bags made from plastic and paper.AQA
- Comparing measured and known values
- A measured melting point or boiling point is set against the known value for the pure substance at the same pressure.AQA
- Comparing melting and boiling points
- Comparing the type and strength of forces between the particles of substances and linking this to the energy needed for the change of state.AQA
- Comparison of analytical methods
- Stating advantages such as speed, sensitivity, accuracy and precision, and use with very small samples, with reference to the chemical tests in this…AQA
- Comparison with known values
- Checking a measured melting or boiling point against the known value for the expected pure substance, where a close match to the sharp known value indicates…AQA
- Comparison with Mars and Venus
- The Earth's early atmosphere may have been like the atmospheres of Mars and Venus today, which provide a useful model for the early Earth.AQA
- Complementary base pairing
- The two chains are held together by bonds between the bases of the nucleotides, and the pairing of bases means the chains are complementary.AQA
- Complete and incomplete combustion
- Complete combustion of a hydrocarbon gives carbon dioxide and water vapour, while a limited supply of oxygen causes incomplete combustion, which also produces…AQA
- Complete ionisation in aqueous solution
- A strong acid is completely ionised in aqueous solution, so essentially every acid molecule releases a hydrogen ion, H⁺, to a water molecule.AQA
- Complex systems
- Global climate is one of these, with many interacting parts including the atmosphere, oceans, ice, land and living things.AQA
- composite
- A material that combines two or more materials so that the useful properties of each are retained in the finished article.AQA
- Composite materials
- Materials made from two or more materials combined so that the product has properties better than either material alone.AQA
- Composition
- The specific amounts of carbon and other metals in a steel, which are adjusted for a purpose.AQA
- Composition and carat
- The proportion of gold in the alloy is measured in carats, with 24-carat gold being pure gold and 18-carat gold containing 18 parts gold out of 24 by mass.AQA
- Composition and function
- Identifying the function of each listed component and explaining how the combination of components gives the product its required properties.AQA
- Composition and properties
- Because alloys are mixtures, their composition can be varied to adjust properties.AQA
- Composition of the early atmosphere
- The Earth's atmosphere at the start of this period may have consisted of mainly carbon dioxide with little or no oxygen gas.AQA
- Compound
- A substance made of two or more different elements chemically combined in fixed proportions.AQA
- Concentrated
- Describes a solution with a large amount of substance in a given volume.AQA
- Concentration
- The number of moles of solute dissolved per cubic decimetre of solution, found by dividing the moles by the volume in dm³.AQA
- Concentration and pH
- The concentration of H⁺ ions determines the pH, so a higher concentration of H⁺ gives a lower pH value.AQA
- Concentration and pressure effects
- More reactant particles in the same volume of solution, or the same number of gas particles squeezed into a smaller volume, makes collisions more frequent.AQA
- Concentration and volume
- Moles of the known solution are calculated using amount = concentration × volume in dm³, and the unknown concentration is found by dividing its moles by its…AQA
- Concentration calculations
- The mass of solute is found from concentration multiplied by volume, and the relationship can be rearranged to find concentration or volume.AQA
- Concentration changes
- When the concentration of one reactant or product is changed, the concentrations of all the substances will change until equilibrium is reached again.AQA
- Concentration versus strength
- Strength is about degree of ionisation, whereas concentration is about the amount of substance per unit volume.AQA
- Concordant Results
- In a titration, results (titres) that are within 0.10 cm³ of each other.OCR
- Concordant results and reliability
- Repeating the titration until concordant titres agree, which improves reliability, and using a mean of concordant values.AQA
- Condensation and the formation of oceans
- As the planet cooled, water vapour condensed into liquid water, which fell as rain and collected in hollows to form the oceans.AQA
- Condensation polymerisation
- A type of polymerisation in which monomers with two functional groups react together, and a small molecule is eliminated for each new bond formed.AQA
- Condensation reactions
- Reactions in which monomers join together, usually losing small molecules such as water.AQA
- Condensing
- Cooling a gas so particles lose energy and move closer together, forming a liquid.AQA
- Conditions for life
- The natural greenhouse effect maintains temperatures on Earth high enough to support life.AQA
- Conduction by free-moving ions
- When an ionic compound melts or dissolves, the lattice breaks down and the ions become free to move, which allows the molten or dissolved compound to conduct…AQA
- Conflict between ordering principle and chemical properties
- Strict atomic-weight ordering sometimes placed elements in groups that did not match their chemical properties, as with tellurium and iodine.AQA
- Consequences for people and ecosystems
- Four potential effects are rising sea levels, more frequent and severe extreme weather, changes to ecosystems and habitats, and impacts on agriculture and…AQA
- Conservation of chemical identity
- The substances keep their original chemical identities because no chemical reactions occur during the separation.AQA
- Conservation of chemical identity in mixtures
- Each substance in a mixture keeps its own chemical properties because no chemical bonds form between the components, so the particles remain the same.AQA
- Conservation of energy
- The total energy of a closed system stays constant during any chemical change, so energy cannot be created or destroyed in a chemical reaction.AQA
- Conservation of mass
- The total mass of reactants equals the total mass of products for a fully balanced equation, as when 4 g plus 32 g gives 36 g.AQA
- Conservation of mass in equations
- Every element must have the same number of atoms on each side of the equation.AQA
- Conservation of matter
- Atoms are conserved, so fuel and oxygen atoms rearrange into the product gases and particles rather than being destroyed.AQA
- Conservation of particles during changes of state
- Ice, water and steam all contain H₂O particles, but the spacing and motion of the spheres differ.AQA
- Conservation of protons in chemical change
- The proton number does not change in chemical reactions; atoms gain, lose or share electrons instead.AQA
- Contamination
- A dirty wire gives a misleading colour, so the wire is cleaned with concentrated hydrochloric acid and heated until no colour is seen before each test.AQA
- Context in scientific language
- When a question uses the word pure, the context determines which meaning applies, such as a food label or a melting point investigation.AQA
- Continuous electricity generation
- The cell produces a potential difference while the fuel and oxygen supplies continue, unlike a battery that stores a fixed amount of chemical energy.AQA
- Contrast between mixtures and compounds
- In a compound the elements have reacted and the compound has different chemical properties from its constituent elements, whereas in a mixture each substance…AQA
- Contrasting gas tests
- A burning splint popping would indicate hydrogen instead, rather than a glowing splint relighting.AQA
- Controlled release of heat
- Design features control the rate of reaction so heat is released gradually and safely rather than all at once.AQA
- Converting between mass and amount
- Moles are found from mass using n = m ÷ Mr, and mass is found from moles using m = n × Mr.AQA
- Corrosion
- The destruction of materials by chemical reactions with substances in the environment.AQA
- Corrosion resistance
- Aluminium resists corrosion despite being more reactive than iron because the oxide layer stays intact and stops further corrosion.AQA
- Cosmetics and sun creams
- Nano-sized titanium dioxide or zinc oxide gives transparent protection by absorbing or scattering ultraviolet radiation.AQA
- Cost and energy in water production
- Desalination by distillation or reverse osmosis is expensive and energy-intensive, which explains why it is used in some locations but not others.AQA
- Counting atoms
- Applying subscripts within the formula first and then coefficients, so each element's atoms in the formula unit are multiplied correctly.AQA
- Counting atoms and relative formula mass
- The formula lets you count atoms, calculate relative formula mass and balance equations.AQA
- Covalent Bond
- A shared pair of electrons between two non-metal atoms.AQA
- Covalent bonding
- Bonds that hold atoms together within molecules, with shared electrons held between the atoms and not free to move through the substance.AQA
- Covalent bonding and shared electron pairs
- Two halogen atoms can each contribute one electron to a shared pair, forming a single covalent bond.AQA
- Covalent bonds
- Bonds inside each molecule that are strong compared with intermolecular forces and remain intact when a molecular substance changes state.AQA
- Covalent bonds in the network
- These must be overcome to melt or boil a giant covalent substance, and the energy needed depends on their number and strength per atom.AQA
- Covalent bonds remain intact
- The strong covalent bonds within each molecule are not broken during melting or boiling, so the molecules themselves stay intact.AQA
- Covalent cross-links
- Strong bonds that join polymer chains to one another, holding them firmly in place so they cannot slide past each other.AQA
- Cracking
- Breaking large hydrocarbon molecules down into smaller molecules that are more useful as fuels and as starting materials for making polymers and other…AQA
- Cradle-to-grave environmental assessment
- An assessment carried out to assess the environmental impact of products in each stage, from extracting and processing raw materials to disposal at the end of…AQA
- Crude oil as the feedstock for most plastics
- Most plastics are produced from crude oil, a fossil fuel, through fractional distillation and cracking to give monomers that are then polymerised.AQA
- Crystallisation
- The process in which a salt solution is warmed to evaporate some water, raising the concentration until saturated, then cooled so that crystals of the salt…AQA
- crystallise
- After evaporating some water, cooling allows the salt to crystallise before it is filtered, washed and dried gently.AQA
- Cullet
- Small pieces of crushed glass, produced when glass bottles are crushed before being melted in a furnace.AQA
D
- Damp litmus paper
- Litmus paper moistened with distilled water, which is essential because dry litmus does not respond to chlorine gas.AQA
- Data evaluation
- Analysing provided data, such as energy costs, environmental impacts and the chemical reactions involved, to weigh the pros and cons of a metal extraction…AQA
- Data interpretation
- Using given data, such as equilibrium concentrations or amounts, to predict how a change in concentration of a reactant or product affects a reversible…AQA
- Decolourised
- Describes the change in which an alkene turns bromine water from orange to colourless, because bromine adds across the C=C double bond.AQA
- Decomposition reactions
- Chemical reactions that break a compound into its elements or simpler compounds, for example passing electricity through molten sodium chloride or heating…AQA
- Deducing order from evidence
- Ranking metals by comparing the vigour of reactions or the outcomes of displacement experiments.AQA
- degree of ionisation
- The extent to which an acid ionises, which is complete for strong acids and partial for weak acids.AQA
- Degree of ionisation and acid strength
- Acid strength depends on how completely an acid ionises, not on how much acid is dissolved.AQA
- Delocalised Electron
- An electron that is not associated with a single atom or a covalent bond, and is free to move through a structure.OCR
- Delocalised electrons
- Electrons in a metal that are not attached to any particular ion and are free to move throughout the structure.AQA
- Demand for small-molecule fuels
- High demand for fuels with small molecules for heating, cooking and transport, which drives cracking.AQA
- Density
- Mass per unit volume, so a low-density alloy gives a strong but light component.AQA
- Desalination
- A treatment used when supplies of fresh water are limited, removing dissolved salts from salty water or sea water to produce potable water.AQA
- Desalination by distillation
- A desalination method that requires much more energy because water must be heated to boiling and condensed.AQA
- Desalination by reverse osmosis
- A desalination method that requires energy to force water at high pressure through a membrane.AQA
- Designed mixtures
- A formulation is a mixture designed to have specific useful properties, not a random combination of substances.AQA
- Detection
- Because carbon monoxide has no colour or smell, it is not easily detected without a detector such as a carbon monoxide alarm.AQA
- Detergents
- Help water to remove grease and dirt and are used in cleaning products.AQA
- Development of scientific theories
- Theories about what was in the Earth's early atmosphere and how the atmosphere was formed have changed and developed over time.AQA
- Development of the atomic model
- The atomic model changed over time as new experimental evidence emerged, moving from Dalton's solid spheres through Thomson's plum pudding model and…AQA
- Development of the periodic table
- Mendeleev's table was not merely a convenient list but a model with genuine predictive power, and its predictive success increased confidence in it.AQA
- Diamond
- A giant covalent structure of carbon atoms, each bonded to four others in a tetrahedral network, so it is very hard and has a very high melting point.AQA
- Diatomic molecules
- Group 7 halogens exist as diatomic molecules, so relative molecular mass is twice the relative atomic mass for each element.AQA
- Dihaloalkane
- The product formed when a halogen adds to an alkene, with two halogen atoms added, one to each carbon of the former double bond.AQA
- dilute
- Having a small amount of acid per unit volume, which is not the same as being weak.AQA
- Dilute hydrochloric acid
- Added to acidify the sample before the barium chloride solution, removing carbonate ions by reacting them to form carbon dioxide.AQA
- Dilution
- Adding more solvent increases the total volume, which decreases the concentration.AQA
- Discharge
- The process during which the reactants inside the cell are used up.AQA
- Discharge at electrodes
- The ions gain or lose electrons at the electrodes, producing new substances.AQA
- Discovery of new elements
- Chemists found new elements whose measured properties closely resembled the values Mendeleev had forecast from the surrounding groups.AQA
- Discovery of the electron
- Experiments on cathode rays showed that atoms contain small, negatively charged particles called electrons.AQA
- Discovery of the neutron
- James Chadwick conducted experiments that yielded evidence for a previously undiscovered subatomic particle, which had a relative mass of 1 but carried no…AQA
- Displacement
- Iron is more reactive than copper, so iron displaces copper from a solution of a copper compound.AQA
- Displacement of hydrogen
- Metals above hydrogen displace it from dilute acids, while metals below hydrogen, such as copper, do not.AQA
- Displacement Reaction
- A reaction where a more reactive element takes the place of a less reactive element in a compound.OCR
- Displacement reactions
- Displacement occurs when a more reactive metal, which forms positive ions more readily, takes the place of a less reactive metal in a compound.AQA
- Dissolved salts
- Impurities in water that can affect taste and, in extreme cases, health, and may be reduced by desalination.AQA
- Dissolved salts and water purity
- Both methods produce water with low levels of dissolved salts.AQA
- Distribution between phases
- Each substance spends a different proportion of time in each phase, and this difference is what causes separation.AQA
- Distribution of results
- The pattern formed when repeated measurements are plotted, for example as a dot plot or a small bar chart, showing how they cluster around the mean.AQA
- Disturbance and re-equilibration
- Changing the concentration of a reactant or product means the system is no longer at equilibrium, and concentrations of all substances change until…AQA
- Dominant emission
- The brightest colour that the eye sees, so that the weaker emission from another cation is not visible against it.AQA
- dot and cross diagram
- A diagram that represents the electron transfer during the formation of an ionic compound, using dots for one atom and crosses for the other.AQA
- Dot and cross diagrams
- A representation that shows the outer-shell electrons of each atom, with shared pairs in the overlap between atoms.AQA
- Double helix
- The two chains are arranged in the form of a double helix, like a twisted ladder.AQA
- Dynamic equilibrium
- Equilibrium is reached when the forward and reverse reactions occur at exactly the same rate, so both reactions continue but the amounts of reactants and…AQA, OCR
E
- Earth's early atmosphere
- One theory suggests it was mainly carbon dioxide with little or no oxygen, formed by volcanic activity, while another emphasises water vapour and nitrogen.AQA
- Earth's energy balance
- A continuous balance between incoming short wavelength radiation, outgoing long wavelength radiation, and absorption and re-emission by greenhouse gases.AQA
- Earth's finite raw materials
- Metals, glass, building materials, clay ceramics and most plastics are produced from limited raw materials, so continued production at current rates will…AQA
- Earth’s first billion years
- During the first billion years of the Earth’s existence there was intense volcanic activity that released gases and water vapour.AQA
- Economic and environmental choices in metal extraction
- Scrap iron is cheap and often waste material, which makes this an economical method, while electrolysis needs electrical energy.AQA
- Economic factors in industrial chemistry
- Raw materials cost money, and separating, purifying and disposing of unwanted by-products adds further cost and energy use, so a process that converts most…AQA
- Economic, social and technological factors
- Reasons affecting the take-up of actions, such as countries relying on fossil fuels for jobs and income, or lacking the grid connections and storage to use…AQA
- Ecosystem damage
- Habitats such as coral reefs and polar ecosystems may be damaged, so species may migrate, decline or become extinct.AQA
- Effect of changing conditions
- Changing the solvent can change the separation because the distribution of the substances changes.AQA
- Effect of concentration on equilibrium
- If the concentration of a reactant is increased, more products will be formed until equilibrium is reached again.AQA
- Effect of concentration, pressure and temperature
- The principle applies to changes in concentration, pressure and temperature, and predictions must state both the direction of shift and the resulting effect…AQA
- Effect of impurities on physical properties
- An impurity lowers the melting point and raises the boiling point, and it spreads melting and boiling over a range of temperatures rather than at one value.AQA
- Effect of temperature on collision energy
- Raising temperature increases the proportion of particles with energy greater than or equal to the activation energy, so more collisions are successful.AQA
- Efficiency of materials
- A larger exposed surface area allows the effect to be achieved with a smaller quantity, which can reduce cost, waste and the mass of material needed.AQA
- Electric current
- The movement of charge that occurs when delocalised electrons drift towards the positive terminal after a potential difference is applied.AQA
- Electrical conductivity
- Graphite conducts electricity because of delocalised electrons, whereas diamond does not because all outer electrons are localised in bonds.AQA
- Electrical conductivity and mobile charge carriers
- All outer electrons are used in covalent bonding, so there are no delocalised electrons or free ions, and diamond does not conduct electricity.AQA
- Electrical conductivity in carbon nanotubes
- The ability of carbon nanotubes to conduct electricity because of their delocalised electrons and extended structure, allowing them to act as tiny wires or…AQA
- Electrical neutrality of atoms
- The atom is neutral overall because the positive and negative charges balance.AQA
- Electrochemical cells
- A simple cell's voltage is not fixed but depends on the chemicals chosen, including the metals used as electrodes and the electrolyte.AQA
- Electrochemical oxidation
- The fuel is oxidised at an electrode surface, transferring electrons through the circuit rather than releasing energy only as heat.AQA
- Electrode processes
- At the negative cathode positive ions gain electrons, and at the positive anode negative ions lose electrons, forming neutral atoms.AQA
- Electrode products
- The metal is produced at the cathode and the non-metal is produced at the anode.AQA
- Electrode reactions in molten electrolysis
- At the positive electrode, oxide ions are oxidised to oxygen: 2O²⁻ → O₂ + 4e⁻.AQA
- Electrodes
- The places where oxidation and reduction happen, with hydrogen oxidised at the negative electrode and oxygen reduced at the positive electrode.AQA
- Electrodes and ion movement
- Positive metal ions are attracted to the cathode and gain electrons, while negative non-metal ions are attracted to the anode and lose electrons.AQA
- Electrolysis
- A process in which ions in an electrolyte move to the electrode of opposite charge and are discharged, requiring a direct current supply.AQA, OCR
- Electrolysis and direct current
- Passing a direct current through an electrolyte causes the mobile ions to move towards the electrodes, and this process is electrolysis.AQA
- Electrolysis of aqueous solutions
- Process in which an aqueous solution is electrolysed using inert electrodes, with the ions discharged depending on the relative reactivity of the elements…AQA
- Electrolysis of molten compounds
- Aluminium is manufactured by the electrolysis of a molten mixture of aluminium oxide and cryolite using carbon as the positive electrode.AQA
- Electrolysis of solutions
- A direct current is used to reduce copper ions at the negative electrode, producing copper metal.AQA
- Electrolyte
- A liquid or solution that contains mobile ions and can conduct electricity.AQA, OCR
- Electron arrangement and reactivity
- Chemical reactions depend on the arrangement of electrons, especially the outer shell, and hence on atomic number.AQA
- Electron configuration
- The arrangement of electrons in an atom, such as helium having two electrons in its only shell and neon having eight in its outer shell.AQA
- Electron counting
- The mole can also count electrons, such as in electrolysis or redox reactions, where one mole of electrons is 6.02 × 10²³ electrons.AQA
- Electron gain
- Halogens react by gaining one electron to form a 1⁻ ion in reactions with metals and in displacement reactions.AQA
- Electron gain and loss to form ions
- A Group 1 metal loses one electron, a Group 2 metal loses two electrons, a Group 6 non-metal gains two electrons and a Group 7 non-metal gains one electron.AQA
- Electron loss and positive charge
- Metal atoms lose one or more outer-shell electrons and become positively charged ions, because the loss of negatively charged electrons leaves more protons…AQA
- Electron loss as the basis of reactivity
- Metals that lose electrons readily form positive ions easily and are more reactive, while metals that form positive ions only with difficulty are less reactive.AQA
- Electron sharing
- The process in which non-metal atoms share pairs of electrons to achieve a full outer electron shell.AQA
- electron shells
- Fixed shells or energy levels around the nucleus that electrons occupy.AQA
- Electron transfer
- In ionic bonding, electrons are transferred from a metal atom to a non-metal atom, producing positively charged cations and negatively charged anions.AQA
- Electronic structure and stability
- Each Group 0 atom has a full outer electron shell, which is a stable arrangement, so its atoms neither gain nor lose electrons easily.AQA
- Electronic structure and the outer shell
- Group 1 atoms each have one electron in their outer shell, and that single outer electron is lost relatively easily when the metal reacts, forming a 1⁺ ion.AQA
- Electronic structure and the periodic table
- The electronic structure of the ion formed is that of the nearest noble gas, for example Cl⁻ is 2,8,8 like argon.AQA
- Electronic structure of atoms and ions
- The arrangement of electrons in an atom changes by the number lost or gained when it forms an ion, so the ion's structure differs from the atom's.AQA
- Electronic structure of sodium
- Written as 2,8,1, meaning two electrons in the lowest energy level, eight in the second energy level and one in the third energy level.AQA
- Electronics
- Nanoparticles are used in components such as conductive films, displays and high-surface-area electrodes where a high surface area or small size is useful.AQA
- Electroplating
- A method that coats a metal with another metal using electrolysis, also improving appearance and conductivity.AQA
- Electrostatic attraction
- The strength of the bond comes from the attraction between oppositely charged ions, which attract each other electrostatically.AQA
- Electrostatic attraction between oppositely charged ions
- Ionic compounds are held together by strong electrostatic forces of attraction between oppositely charged ions, which attract each other because opposite…AQA
- Electrostatic forces
- The attractions between positive and negative charges, which fundamentally drive all chemical bonding.AQA
- Electrostatic forces of attraction
- Strong forces that act in all directions between oppositely charged ions in a giant ionic lattice.AQA
- Element
- A substance that contains only one type of atom.AQA
- Element identity
- What makes an atom a particular element, determined by its proton number.AQA
- elements
- There are about 100 different elements, and they are shown in the periodic table.AQA
- Elimination of small molecules
- A small molecule, commonly water, is lost at each link formed as a new covalent bond forms between monomer units.AQA
- Embedded electrons
- Negative electrons are embedded in a ball of positive charge.AQA
- Emission control
- Reducing these emissions involves using low-sulfur fuels, removing sulfur from flue gases, and using catalytic converters.AQA
- Emission of light
- What happens when the sample is introduced into a flame, where the metal ions emit light of characteristic wavelengths.AQA
- Emission of light by excited ions
- The colour comes from light emitted by excited metal ions as they return to lower energy levels.AQA
- Empirical formula
- The simplest whole-number ratio of cations to anions in the diagram, found by counting the ions.AQA
- Empirical ratios from moles
- Dividing all mole values by the smallest mole value to start simplifying the ratio.AQA
- Empty space in atoms
- Most alpha particles passed straight through the gold foil, showing that most of the atom is empty space.AQA
- End point
- The point at which a suitable indicator changes colour, showing that the acid and alkali have reacted completely.AQA
- End users
- The people and organisations who consume products, and whose choices drive demand for raw materials.AQA
- Endothermic
- A reaction that takes in energy and lowers the temperature, such as thermal decomposition of calcium carbonate.AQA
- Endothermic and exothermic reactions
- When temperature is increased, the system absorbs the extra heat by favouring the endothermic direction, while for an exothermic reaction the relative amount…AQA
- Endothermic reaction
- A reaction that takes in energy from the surroundings so the temperature of the surroundings decreases.AQA
- Endothermic reactions
- Reactions that take in energy from their surroundings, so the surroundings cool.AQA
- Energy and cost of water treatment
- Desalination is expensive and uses a lot of energy, so it is not the first choice where fresh water is available.AQA
- Energy and modern lifestyle
- Many of the fuels on which we depend for our modern lifestyle are produced from crude oil.AQA
- Energy barriers in reactions
- The energy barrier to starting a reaction, represented in a model by the height of a hill a ball must be pushed over.AQA
- Energy changes and bonding
- A large amount of energy is needed to break the many strong bonds, which is why these compounds have high melting points and high boiling points.AQA
- Energy changes during state changes
- Only a small amount of energy is needed to separate the molecules from one another when a substance melts or boils.AQA
- Energy demand in water treatment
- The processes that make water potable can demand significant energy, especially when water is scarce or salty.AQA
- Energy demands of desalination
- Both methods require significant energy, which affects their cost and practicality.AQA
- Energy input required for decomposition
- Energy must be taken in continuously, so thermal decomposition is endothermic.AQA
- Energy level diagrams
- Simple reaction profiles showing the relative energies of reactants and products, the activation energy and the overall energy change, with a curved line to…AQA
- Energy levels and shells
- The regions around the nucleus that electrons occupy, with the lowest available energy level being the innermost shell, closest to the nucleus.AQA
- Energy transfer
- The difference between the energy absorbed in bond breaking and the energy released in bond making appears as energy transferred to or from the surroundings,…AQA
- Energy transfer during state changes
- Energy transferred during melting or boiling is used to overcome weak intermolecular forces rather than to break strong covalent bonds.AQA
- Energy transfer from fuels
- Burning hydrocarbon fuels transfers energy to the surroundings, which is why they are useful as fuels.AQA
- Energy transfer from the surroundings
- Energy is transferred from the surroundings to the reacting system during an endothermic change.AQA
- Energy transfer in reactions
- Drawing conclusions about energy transfer from recorded results, using them to identify patterns or explain how a chosen variable affected the temperature…AQA
- Energy transfer to the surroundings
- The excess energy is transferred to the surroundings, usually shown by a temperature rise.AQA
- Energy transfers
- Energy transferred by heating is used to overcome forces between particles during melting and boiling.AQA
- Energy transfers during changes of state
- Energy transferred by heating overcomes the forces holding particles together, and stronger forces need more energy to weaken or break.AQA
- Environmental and economic trade-offs in extraction
- Weighing advantages such as working on low-grade ores and less landscape disruption against disadvantages such as slow rates and the need for large areas of…AQA
- Environmental cost of extracting raw materials
- Obtaining raw materials from the Earth by quarrying and mining causes environmental impacts.AQA
- Environmental damage
- Acid rain can damage trees, acidify lakes and soils, and corrode buildings and statues made from limestone or marble.AQA
- Environmental impact
- Acid rain acidifies lakes and damages aquatic life, and carbon particulates can cause global dimming by reflecting sunlight.AQA
- Environmental impact and future generations
- A process is not sustainable if it uses finite resources faster than they can be replaced or causes lasting environmental harm for later users.AQA
- Environmental impact of extraction
- Digging, moving and disposing of large amounts of rock damages habitats and creates spoil heaps, while these methods reduce landscape disturbance and waste.AQA
- Environmental standards
- Requirements that treated water must meet before being released into rivers or the sea.AQA
- Enzymes
- Provided by yeast, these catalyse the reaction that converts glucose into ethanol and carbon dioxide.AQA
- Equilibrium
- In reversible reactions, changing temperature, pressure, or concentration can shift its position and alter yield.AQA
- Equilibrium position
- Changing temperature affects the position of equilibrium because it changes the rates of the forward and reverse reactions differently, depending on whether…AQA
- Equilibrium shift
- The direction in which an equilibrium moves, determined by using the balanced equation to oppose the change described.AQA
- Equilibrium shifts
- The movement of equilibrium to the right if a reactant is added or a product removed, or to the left if a product is added or a reactant removed.AQA
- Error and uncertainty
- Repeating each concentration and calculating a mean reduces the effect of random errors and improves the reliability of the conclusion.AQA
- Ester links
- The link formed when an alcohol group reacts with a carboxylic acid group, with water eliminated at each link formed.AQA
- Esterification with alcohols
- At higher tier, carboxylic acids react with alcohols to form esters, usually with an acid catalyst.AQA
- Estimating uncertainty
- A simple estimate given by half the range, often written as ± half the range about the mean.AQA
- Evaluate
- Weigh advantages such as strength, density, corrosion resistance and cost against disadvantages.AQA
- Evaluating applications
- Weighing benefits such as portability against risks such as burns, cost, reversibility and environmental impact using the information given.AQA
- Evaluating applications against a specified purpose
- Use the information given in a question to judge whether a use is worthwhile, reaching a justified judgement about whether a particular use is suitable for…AQA
- Evaluating competing reaction pathways
- Atom economy is only one factor; a company must also consider yield, rate, equilibrium position, energy demands, safety and the usefulness of any by-products…AQA
- Evaluating evidence and reaching justified conclusions
- Weighing advantages against disadvantages using the information given, with a judgement based on the evidence provided, not on a general preference.AQA
- Evaluating evidence for a purpose
- Using the information supplied in a question to judge how well nanoparticles suit the stated purpose, reaching a clear judgement supported by reasons.AQA
- Evaluating hydrogen fuel cells
- Weighing advantages, such as continuous electricity while hydrogen and oxygen are supplied and water as the only chemical product, against drawbacks, such as…AQA
- Evaporation and condensation
- Crude oil is heated so that hydrocarbons evaporate and rise as vapours, and a vapour condenses when it reaches a level where the temperature is below its…AQA
- Everyday materials
- Low density poly(ethene) is used for bags and film, and high density poly(ethene) is used for bottles and pipes.AQA
- Everyday meaning of pure
- Often means clean or natural, which differs from the chemical definition of pure.AQA
- Everyday products
- Formulations are common in everyday products including medicines, paints, cleaning agents, fuels, alloys, fertilisers and foods.AQA
- Everyday versus chemical meaning
- In everyday language pure means a substance has had nothing added to it, while in chemistry it means a substance contains only one substance.AQA
- Evidence and conclusion
- Using collected data to state whether the hypothesis is supported, identifying anomalies and basing the conclusion on the overall pattern.AQA
- Evidence and regulation
- Research informs regulation, and conclusions may change as new evidence is collected, so the field is developing rather than a fixed set of facts.AQA
- Evidence and revision
- As evidence accumulates, theories are modified or replaced, and new evidence leads to theories being modified or replaced.AQA
- Evidence and scientific explanation
- New experimental evidence can show that an existing model cannot explain observations, so the model is changed or replaced.AQA
- Evidence for no new substance
- No new substances are made during filtration, crystallisation, simple distillation, fractional distillation or chromatography.AQA
- Evidence from characteristic reactions and tests
- The particles of each substance remain unchanged, so their reactions and characteristic tests are the same as when the substance is pure, such as oxygen in…AQA
- Evidence interpretation
- Identifying patterns, trends, or relationships in the given data or information.AQA
- Evidence-based acceptance of models
- The periodic table became widely accepted because the agreement between prediction and discovery provided strong evidence that the underlying pattern was real.AQA
- Evidence-based conclusions
- The measured value and the known value are quoted, the direction of any difference is stated, and the sample is concluded to be pure or impure.AQA
- Evidence-based decision making
- The correct approach is to weigh evidence for the specific use rather than assume a general danger, using information supplied in the question to reach a…AQA
- Evidence-based identification
- Using the information supplied, such as an ingredient list or composition table, to decide whether the product is a formulation.AQA
- Evidence-based model change
- Science is a sequence of models revised when new evidence appears, such as cathode rays showing smaller, negatively charged particles inside atoms.AQA
- Evolution of the atmosphere
- The change from an early mixture rich in carbon dioxide with little or no oxygen to today's nitrogen-rich, oxygen-containing air.AQA
- Examples of strong acids
- Hydrochloric, nitric and sulfuric acids are examples of strong acids.AQA
- excess
- Adding the insoluble solid until it is in excess means the acid is fully neutralised and no unreacted acid remains.AQA
- Excess reactant
- The reactant that is not fully used up and some of which remains unreacted after the reaction.AQA
- Excess reactant after reaction
- The reactant in excess remains after the reaction and may need to be separated or recovered.AQA
- Excess solid method
- Because the solid is insoluble, it can be added in excess and then removed by filtration, and the reaction stops when no more solid dissolves.AQA
- Excitation and emission
- The heat energy from the flame excites the metal ions, which then emit light of characteristic wavelengths as they return to their lower energy states.AQA
- Exothermic
- A reaction that transfers energy to the surroundings and raises the temperature, such as combustion.AQA
- Exothermic and endothermic changes
- An exothermic change releases energy to the surroundings, while an endothermic change absorbs energy from the surroundings.AQA
- Exothermic and endothermic classification
- Using the sign or direction of the temperature change to show whether the reaction is exothermic or endothermic.AQA
- Exothermic and endothermic processes
- These are underpinned by the principle of conservation of energy, with energy transferred between the chemical store of reactants or products and the thermal…AQA
- Exothermic and endothermic reactions
- Reactions identified from reaction profiles by comparing the two levels: lower products mean energy is released, so the reaction is exothermic; higher…AQA
- Exothermic reaction
- A reaction in which the energy released from forming new bonds is greater than the energy needed to break existing bonds.AQA
- Exothermic reactions
- A reaction that transfers energy to the surroundings so the temperature of the surroundings increases.AQA
- Experimental control of variables
- A valid comparison requires the same mass or amount of reactant when surface area is changed, so that the effect is due to surface area alone.AQA
- Experimental evidence
- Observations such as colour change, solid deposit or temperature change that provide evidence of displacement.AQA
- Experimental evidence for reactivity
- Reactions with water or dilute acid, and displacement reactions, show which metals are more reactive.AQA
- Experimental sequence
- The sample must be put into the flame, the emitted light must be collected and passed through the spectroscope, and the resulting spectrum is then analysed.AQA
- Experimental technique
- A splint is lit, then blown out so that it still glows at the tip, and lowered into the tube so the gas surrounds the tip.AQA
- Experimental testing of models
- The model was later tested by the alpha particle scattering experiment, in which most alpha particles passed straight through gold foil but a few were…AQA
- Explaining physical properties of simple molecules
- Strong covalent bonds explain why molecules stay together, while weak intermolecular forces explain low melting and boiling points.AQA
- Explaining reaction rate in particle terms
- A reaction occurs only when reacting particles collide with each other and with sufficient energy; collisions with less energy do not lead to reaction.AQA
- External current
- A current supplied in the opposite direction, for example from a charger, which reverses the reactions so the products are converted back into the original…AQA
- External reactants
- The fuel and oxygen or air are fed into the cell from outside rather than being stored as the cell's only energy source.AQA
- Extraction of metals from ores
- Metals are extracted from ores, which are rocks containing enough of a metal compound to be worth mining.AQA
- Extraction of metals with carbon
- Metals below carbon can be extracted from their oxides by heating with carbon, whereas metals above carbon cannot be extracted this way.AQA
- Extraction of reactive metals
- Aluminium is extracted from its ore by electrolysis because it is more reactive than carbon, so carbon reduction is ineffective.AQA
- Extreme weather
- Warmer oceans and air can make some storms and rainfall events more intense, while other regions become drier and face drought.AQA
F
- Factors affecting reaction rate
- Increasing temperature, concentration, pressure or surface area, or adding a catalyst, increases the frequency or success of collisions and so increases the…AQA
- Fair testing
- Only the concentration of the chosen reactant is changed while temperature, volumes and other reactant amounts are kept constant for a fair comparison.AQA
- Feedback mechanisms
- These are loops through which the parts of the climate system affect one another, such as melting ice reducing reflectivity and causing more warming.AQA
- Feedstock
- A starting material for the petrochemical industry, rather than something necessarily burned for energy.AQA
- Fermentation
- The breakdown of sugar by yeast to produce ethanol and carbon dioxide.AQA
- Fertiliser specification and quality control
- Industry monitors product purity and nutrient content, while laboratory preparation is mainly for identification or testing rather than bulk supply.AQA
- Fertilisers
- Supply nitrogen compounds that plants need for making proteins and DNA, so crops grow larger and yields increase.AQA
- fibreglass
- A composite of glass fibres set in a polymer resin, where the fibres give tensile strength while the resin binds them and resists impact.AQA
- Filling of energy levels
- Electrons fill the lowest available energy levels first, with the first energy level holding a maximum of two electrons.AQA
- Filter beds
- Passing the water through these removes insoluble solids such as grit, soil and small particles, but not dissolved substances.AQA
- Filtration
- Separates an insoluble solid from a liquid using filter paper and a funnel, because the solid particles are too large to pass through the filter paper pores.AQA
- Filtration and crystallisation
- Filtering the mixture to remove the excess solid and keep the filtrate, then evaporating the filtrate until crystals begin to appear, before cooling,…AQA
- Finite and renewable resources
- Finite resources cannot be replaced as they are used, whereas renewable resources are replenished naturally at a rate that can match use.AQA
- Finite resources
- Resources that will eventually run out if extraction continues at current rates, because they form over geological timescales but are extracted and used much…AQA
- Five-membered rings
- Rings containing five carbon atoms that pull the sheet into a dome and help close the cage.AQA
- Fixed composition and atom ratios
- The proportions of the elements in a given compound are fixed, so the ratio of atoms is always the same for that compound.AQA
- Fixed proportions
- Formulations are made in fixed proportions so that every batch has the same properties.AQA
- Flame test
- A test that can be used to identify some metal ions (cations) from the colour they give to a flame.AQA
- Flame tests
- Tests used for metal cations such as lithium, sodium, potassium, calcium and copper, in which the flame colour is observed.AQA
- Flammability
- Decreases as molecular size increases because larger molecules are less volatile and harder to vaporise.AQA
- Food and clothing
- Categories supplied by natural resources and supplemented by agriculture, with food from fishing and farming and clothing using cotton, wool and synthetic…AQA
- Forces between particles
- The strength of these determines the amount of energy needed to change state from solid to liquid and from liquid to gas.AQA
- Formation of fossil fuels
- Buried carbon-rich remains subjected to heat and pressure over millions of years form deposits such as coal, crude oil and natural gas.AQA
- Formation of halide ions and hydrogen halides
- The halogen achieves a full outer shell either by gaining an electron to form a 1⁻ ion or by sharing an electron pair.AQA
- Formation of positive ions
- The more readily a metal loses electrons to form a positive ion, the more reactive it is.AQA
- Formation of sedimentary rocks
- Shells and skeletons of marine organisms contain calcium carbonate; when these settle and are compacted, sedimentary rock such as limestone forms and stores…AQA
- Formation of sediments and sedimentary rocks
- The precipitates settled on the ocean floor and became sediments, such as limestone.AQA
- Formation of the early atmosphere
- The first atmosphere is thought to have formed from volcanic gases released early in Earth's history, after the Earth formed.AQA
- Formula
- A way of showing which elements are present and, through subscripts, how many atoms of each are present.AQA
- Formulae as symbolic representations
- A chemical formula uses the chemical symbols of the elements and subscript numbers to show how many atoms of each element are in one unit.AQA
- Formulation
- A mixture that has been designed as a useful product, made to a chosen recipe so that it works well.AQA, OCR
- Formulations
- These include fuels, cleaning agents, paints, medicines, alloys, fertilisers and foods, appearing across many areas of chemistry and everyday life.AQA
- Forward and reverse reaction rates
- Increasing the concentration of a reactant makes the forward reaction faster than the reverse reaction, and the shift continues until the two rates become…AQA
- Fossil fuels
- Coal, oil and natural gas, which are limited resources that will eventually run out and whose burning releases carbon dioxide, a greenhouse gas.AQA
- Fraction
- A mixture of hydrocarbons with a similar number of carbon atoms and therefore a similar boiling point range, not a single pure compound.AQA
- Fractional distillation
- The process by which the many hydrocarbons in crude oil are separated into fractions, each containing molecules with a similar number of carbon atoms.AQA
- Fractional distillation products
- These fuels are fractions obtained by fractional distillation of crude oil.AQA
- Fractions as mixtures with boiling-point ranges
- Each collected fraction is a mixture of hydrocarbons with a similar boiling-point range rather than a pure substance.AQA
- Freezing
- Cooling a liquid so particles lose energy and move less, so forces pull them into a regular solid arrangement.AQA
- Frequency of collisions
- How often particles collide, increased by raising concentration or pressure because there are more particles in a given volume, and by increasing surface area…AQA
- Fresh and clear
- The state limewater must be in before use, because stale limewater may already be cloudy and give a false positive.AQA
- Fuel cell
- An electrical cell that is supplied with a fuel and oxygen, and uses energy from the reaction between them to produce electrical energy efficiently.AQA
- Fuel cells
- Devices supplied by an external source of fuel and oxygen or air, generating a potential difference continuously as long as they are supplied.AQA
- Fuels
- Fractions from crude oil provide these for cars, lorries, ships and aircraft, and for heating and electricity generation.AQA
- Fuels and energy resources
- The energy released makes hydrocarbons valuable as fuels for heating, cooking, electricity generation and transport.AQA
- Fuels from crude oil
- Petrol, diesel oil, kerosene, heavy fuel oil and liquefied petroleum gases are all produced from crude oil.AQA
- Full outer electron shells
- A stable electron configuration that means atoms do not easily gain, lose or share electrons.AQA
- full outer shell
- Each ion has eight electrons in its outer shell, except for small ions such as Li⁺ which have two.AQA
- Full outer shells
- Electron transfer allows both atoms to achieve a full outer electron shell.AQA
- Fullerenes
- Molecular forms of carbon in which every carbon atom bonds to three others, producing curved cage-like or tubular molecules.AQA
- Fully displayed formulae
- Structural formulae in which every atom is shown and every bond is drawn as a line, including all C–H bonds and the new C–H or C–X bonds.AQA
- Function of components
- Each component in a formulation has a defined function, such as solvent, detergent, colourant, fragrance, preservative, fuel additive or active ingredient.AQA
- Functional group
- The group present that tells you which reactions to expect, such as the complete –COOH group that distinguishes carboxylic acids from alcohols and esters.AQA
- Functional groups
- The groups in the monomers, such as the alcohol groups and carboxylic acid groups, whose reaction allows the chain to continue growing.AQA
- Functional unit
- The same basis used to make a comparison fair, such as carrying the same shopping for one year.AQA
G
- Galvanising
- A zinc coating on iron, which still protects the exposed iron when scratched because the two metals are in contact.AQA
- Gas identification
- Oxygen is identified by its ability to relight a glowing splint inserted into a test tube of the gas.AQA
- Gas identification tests
- Hydrogen can be identified by a lighted splint giving a squeaky pop.AQA
- Gas production and observation
- Carbon dioxide is seen as effervescence, and it turns limewater milky.AQA
- Genetic information storage
- DNA is essential for life because it stores and transmits genetic information needed by living organisms.AQA
- Geological timescales and atmospheric change
- Both processes are slow and geological, so they reduced carbon dioxide gradually over long time periods.AQA
- Giant covalent structure
- A structure with no separate molecules, so the strong covalent bonds themselves must be overcome throughout the lattice to melt or boil it.AQA
- Giant covalent structures
- Graphite is one of these, in which each carbon atom forms three covalent bonds to three other carbon atoms, producing layers of hexagonal rings.AQA
- Giant ionic lattice
- A regular structure in which oppositely charged ions pack together in a three-dimensional arrangement that extends throughout the crystal.AQA
- Giant ionic lattice structure
- A structure in which huge numbers of positive and negative ions are packed together in a regular repeating pattern.AQA
- Giant lattice
- A structure in which the bonds act throughout, so a large amount of energy is needed to break them.AQA
- Giant metallic lattice structure
- A regular arrangement in pure metals in which identical atoms are arranged in layers.AQA
- Giant structure
- A metal is a giant structure of atoms rather than a simple molecule, with no fixed small number of atoms.AQA
- Giant structures
- Very large numbers of atoms are joined together in one continuous lattice rather than in small molecules.AQA
- Global climate change
- A change expected to result from the rise in the temperature of the Earth's atmosphere at the surface.AQA
- Global dimming
- The effect where particulates in the atmosphere reflect sunlight back into space, reducing the amount of light reaching the Earth's surface.AQA
- Global temperature
- A long-term average calculated from many land and sea measurements around the world.AQA
- Graph interpretation
- Plotting a graph such as volume of gas against time allows the gradient or the time taken to be interpreted as a measure of rate.AQA
- Graphene
- A single flat layer of hexagonal carbon rings one atom thick, with each carbon bonded to three others.AQA
- Greenhouse effect
- Greenhouse gases absorb infrared radiation emitted by the Earth, so increasing their concentration strengthens this effect.AQA
- Greenhouse effect and global warming
- Greenhouse gases such as carbon dioxide and methane absorb infrared radiation re-emitted by Earth, warming the atmosphere and oceans.AQA
- Greenhouse effect mechanism
- Short wavelength radiation from the Sun passes through the atmosphere and is absorbed by Earth's surface, which then emits longer wavelength infrared…AQA
- Greenhouse gas emissions
- Gases released across the life cycle, with carbon dioxide and methane the main gases counted and others included by converting them to a carbon dioxide…AQA
- Greenhouse gases
- Water vapour, carbon dioxide and methane are gases in the atmosphere that absorb and re-emit infrared radiation emitted by Earth's surface.AQA
- Ground water
- Water such as water from aquifers, which is often naturally filtered through rock and may need only screening, aeration and chlorination.AQA
- Group
- Determined by the number of outer-shell electrons in an atom.AQA
- Group 0
- The final column on the right of the periodic table, containing the noble gases.AQA
- Group 0 noble gases
- These sit on the far right of the periodic table and include helium, neon and argon.AQA
- Group 1 and Group 2 metals
- Group 1 metals such as lithium, sodium and potassium sit on the far left, and Group 2 metals such as magnesium and calcium sit next to them.AQA
- Group 1 elements
- Soft, low density and highly reactive metals that form 1⁺ ions.AQA
- Group 1 metals
- Lose one electron, giving ions with a 1⁺ charge, such as Na⁺.AQA
- Group 1, Group 7 and Group 0 trends
- Group 1 metals lose one electron readily, Group 7 non-metals gain one electron, and Group 0 elements have full outer shells and are unreactive.AQA
- Group 2 metals
- Lose two electrons, giving ions with a 2⁺ charge, such as Mg²⁺.AQA
- Group 6 non-metals
- Gain two electrons, giving ions with a 2⁻ charge, such as O²⁻.AQA
- Group 7 halogens
- These sit just to the left of Group 0 and include fluorine, chlorine and bromine.AQA
- Group 7 non-metals
- Gain one electron, giving ions with a 1⁻ charge, such as Cl⁻.AQA
- Group 7 reactivity
- The reactivity trend shown by this reaction, which can be used to place halogens in order of reactivity.AQA
- Group 7 trends
- Down the group, atomic radius and shielding increase, so the attraction for an incoming electron decreases and reactivity decreases.AQA
- Group number
- The number used to work out how many bonds an atom forms, for example carbon in group 4 forms four bonds.AQA
- Group number and ion charge
- For metals the group number tells you how many electrons are lost, and for non-metals the number gained is 8 minus the group number.AQA
- Group properties
- Elements in the same group have the same number of outer electrons, which gives them similar chemical properties.AQA
- groups
- Vertical columns in the periodic table that contain elements with similar properties.AQA
H
- Haber process
- Used to manufacture ammonia, reacting nitrogen from air with hydrogen.AQA
- Habitat and landscape destruction
- Large areas of land are cleared, destroying habitats and landscapes, and the pits and spoil heaps remain after extraction ends.AQA
- Half equation
- Shows electrons gained or lost by one species, for example Mg → Mg²⁺ + 2e⁻ for oxidation or Cl₂ + 2e⁻ → 2Cl⁻ for reduction.AQA
- Half equations
- Balanced equations that demonstrate the transfer of electrons, with electrons on the right side for oxidation and on the left side for reduction.AQA
- Half-equations for hydrogen and oxygen
- At the cathode 2H⁺ + 2e⁻ → H₂, and at the anode 4OH⁻ → O₂ + 2H₂O + 4e⁻.AQA
- Half-equations for reduction
- The cathode half-equation for hydrogen production is 2H⁺ + 2e⁻ → H₂, and for a metal less reactive than hydrogen such as copper it is Cu²⁺ + 2e⁻ → Cu.AQA
- Halide identification
- Halide ions in aqueous solution can be identified by adding dilute nitric acid followed by silver nitrate solution, and the precipitate colour identifies the…AQA
- halide ions
- Ions such as Cl⁻, Br⁻ or I⁻, which are discharged in preference to hydroxide ions, so the halogen forms instead.AQA
- Halide preference at the anode
- Halide ions are discharged at the anode in preference to hydroxide ions, giving a halogen; otherwise oxygen is produced.AQA
- Halide salts
- Salts whose aqueous solutions are used in displacement reactions, where the less reactive halide ion is oxidised to form a halogen molecule.AQA
- Halogens
- The elements in Group 7 of the periodic table, which have similar reactions because they all have seven electrons in their outer shell.AQA
- Hand warmers
- Devices that commonly use the exothermic oxidation of iron by oxygen from the air to release heat.AQA
- Hardness and melting point
- The rigid network makes diamond very hard, and many strong covalent bonds must be broken to melt it, so it has a very high melting point.AQA
- Harmful chemicals
- Toxic dissolved substances including heavy metal ions, acids, alkalis or toxic compounds that must be removed or reduced to safe levels.AQA
- Harmful microbes
- Bacteria and viruses that can cause disease, can contaminate drinking water and cause illness, and must be reduced before water is released.AQA
- Hazard control and apparatus choice
- Evaporating the filtrate using a water bath or electric heater rather than a direct flame, because gentle heating avoids spitting and decomposition.AQA
- Heating and cooling in material manufacture
- The three materials are heated together to a high temperature and then cooled quickly so the mixture solidifies without forming an ordered crystal lattice.AQA
- Hexagonal rings
- Six-membered rings of carbon atoms, exactly like those in graphite, that form the main framework of fullerenes.AQA
- High carbon steel
- An iron alloy containing a relatively large proportion of carbon, which makes it strong and hard but brittle.AQA
- Historical development of atomic theory
- The nucleus was an established scientific idea well before the neutron was identified.AQA
- Homologous series
- A family of compounds with the same general formula and similar chemical properties, in which each member differs from the next by a CH₂ unit.AQA, OCR
- Homologous series and general formulae
- Families with the same general formula and functional group, whose members differ by one CH₂ unit, such as alkanes and alkenes.AQA
- Human activities
- Activities such as burning fossil fuels, deforestation, livestock farming and landfill increase the amounts of carbon dioxide and methane.AQA
- Human health
- Both gases irritate the airways and can worsen respiratory problems such as asthma and bronchitis.AQA
- Human health effects
- Carbon monoxide binds to haemoglobin and reduces oxygen transport, causing dizziness and death, while carbon particulates cause respiratory irritation.AQA
- Human impact on climate
- Some human activities increase the amounts of greenhouse gases in the atmosphere, and these gases trap heat.AQA
- Human impacts
- Agriculture may suffer where rainfall changes or pests spread, affecting food supply, and human health may be affected by heatwaves and changing disease…AQA
- Human needs
- Warmth, shelter, food and transport are provided by using the Earth's resources.AQA
- Hydrocarbons
- Molecules that contain only carbon and hydrogen, as in petrol, diesel and natural gas.AQA
- Hydrogen
- A non-metal even though it appears at the top left, which is a useful exception to remember.AQA
- Hydrogen as a fuel
- A common fuel used in fuel cells, supplied from a cylinder or store, and oxidised at one electrode.AQA
- Hydrogen fuel cell
- Produces a voltage continuously while hydrogen and oxygen are supplied, because the reaction between them releases energy that is transferred electrically.AQA
- Hydrogen ion concentration and pH
- pH is a measure of hydrogen ion concentration, so a higher concentration of H⁺ ions gives a lower pH value.AQA
- Hydrogen oxidation
- In a hydrogen fuel cell, hydrogen is oxidised at one electrode while oxygen is reduced at the other.AQA
- Hydrogen production
- Hydrogen gas is produced when hydrogen ions in the acid gain electrons, seen as effervescence as bubbles form.AQA
- Hydrogen source
- Hydrogen is commonly obtained from natural gas, which is mainly methane, by reacting methane with steam.AQA
- hydroxide ions
- Ions, OH⁻, present from water, which are discharged to produce oxygen gas.AQA
- Hypothesis
- A testable prediction linked to scientific reasoning that identifies the independent variable, the dependent variable and the expected direction of change.AQA
- Hypothesis development and testing
- Developing a testable hypothesis linking the ions in solution to the products at each electrode, then testing it by electrolysing solutions and recording…AQA
I
- Identification by comparison with reference data
- The sample's chart or table is compared with a reference set in the same form, matching line positions or wavelengths rather than brightness alone.AQA
- Identification of electrode products
- The products can be identified by testing gases, for example a lighted splint for hydrogen and damp litmus for chlorine.AQA
- Identification of elements
- Using the line spectrum produced through a spectroscope, since each metal ion gives its own pattern of lines, to identify which metal ions are present.AQA
- Identification of metal ions
- Using the positions of the lines in the spectrum to identify which metal ions are present in the solution.AQA
- Identification of substances
- Comparing Rf values with known values to help identify substances, where a pure substance usually gives a single spot.AQA
- Identifying transition metal ions
- These colours are distinctive and allow the ions to be identified in a simple test.AQA
- Impurities
- Unwanted substances in a material that can change its properties, such as copper in steel making it crack during rolling.AQA
- Incomplete combustion
- Combustion in which some carbon in a fuel is not fully burned, increasing the release of solid particles and unburned hydrocarbons.AQA
- Incompleteness of scientific evidence
- Early tables contained gaps because many elements had not yet been discovered, so they were incomplete in the sense of missing elements.AQA
- Indivisible particles
- Tiny spheres that could not be divided, which is how atoms were thought of before the discovery of the electron.AQA
- Industrial conditions
- The conditions used during polymerisation, such as temperature, pressure and the presence of a catalyst, which affect how the chains form and pack together.AQA
- Industrial costs and maintenance
- The anode must be continually replaced because it is consumed by reaction with oxygen, adding to the cost of the process.AQA
- Industrial efficiency
- Chemistry improves industrial processes by developing catalysts and new materials that increase efficiency and reduce waste.AQA
- Industrial energy and cost considerations
- Cryolite dissolves the oxide and lowers the melting point, reducing energy cost, while the carbon anode is gradually used up and must be replaced.AQA
- Industrial feedstocks
- Alkenes act as starting materials for making many other chemicals, including ethanol and ethanoic acid.AQA
- Industrial processes such as the Haber process
- In the Haber process, increasing pressure shifts equilibrium to the right because there are fewer gas molecules on the product side, partially reducing the…AQA
- Industrial processing of minerals
- Phosphate rock must be treated with an acid to convert the insoluble calcium phosphate into soluble phosphate salts.AQA
- Industrial versus laboratory processes
- Both routes rely on the same reaction between an acid and the basic phosphate rock, but scale, equipment, safety controls and product specification differ.AQA
- Inert electrodes
- Electrodes such as graphite are used so they do not react with the products or electrolyte.AQA
- Inert electrodes and control variables
- Choosing inert graphite electrodes and controlling variables such as solution concentration, voltage and electrode material.AQA
- Instrument resolution
- Instruments have limited resolution, and the resolution of an instrument can be used to estimate the uncertainty in a single reading.AQA
- Instrumental analysis
- A method in which an instrument is used to produce a result, here limited to flame emission spectroscopy, that is interpreted using appropriate data in chart…AQA, OCR
- Instrumental methods
- Methods that use machines to detect and identify elements and compounds from a measured signal.AQA
- Integrated industrial chemistry
- The nitric acid produced can then be reacted with more ammonia to make ammonium nitrate, so the two products are linked within an integrated fertiliser process.AQA
- Interference between overlapping test results
- Sodium yellow is intense and easily masks other colours, so careful cleaning and viewing through a blue glass can help when potassium is suspected.AQA
- Intermolecular forces
- Forces acting between one polymer molecule and its neighbours, which are relatively strong compared with those between small molecules but weaker than the…AQA
- Intermolecular forces and physical properties
- Very weak forces between the atoms give very low melting and boiling points, which rise slowly down the group as atoms get larger and forces between them…AQA
- Intermolecular forces and physical states
- Weak intermolecular forces hold the small molecules together in the element, which explains why fluorine and chlorine are gases, bromine is a liquid and…AQA
- Interpret
- Read the composition and identify the elements and their relative proportions.AQA
- Interpreting graphical models of reactions
- Using reaction profiles to identify reactions as exothermic or endothermic and to explain that the activation energy is the energy needed for a reaction to…AQA
- Inverse proportionality
- The ratio is inversely proportional to side length, so dividing the side length by 10 multiplies the ratio by 10.AQA
- Ion
- An atom or group of atoms that has an electrical charge, either positive or negative, due to the loss or gain of electrons.OCR
- Ion competition in aqueous solution
- The compound supplies a positive ion and a negative ion, while water supplies H⁺ and OH⁻, and the appropriate ions are discharged at each electrode.AQA
- ion discharge
- The process linked to the relative ease of oxidation of the ions present, giving oxygen or a halogen at the anode.AQA
- Ion formation
- Metal atoms lose electrons to form positive ions, and non-metal atoms gain electrons to form negative ions.AQA
- Ion formation and equations
- Hydrochloric acid gives HCl(aq) → H⁺(aq) + Cl⁻(aq), nitric acid ionises to H⁺ and NO₃⁻, and sulfuric acid releases two H⁺ ions per molecule, forming SO₄²⁻.AQA
- Ion formation by electron gain
- Non-metal atoms gain electrons into their outermost shell until that shell is full, producing a negative ion.AQA
- Ion formation by electron loss
- Metal atoms lose electrons to become positively charged ions, losing the electrons in their outermost shell first because these are the least strongly…AQA
- Ion formation by metals
- When metals react with other substances the metal atoms form positive ions.AQA
- Ion migration in electrolytes
- Positively charged ions are attracted to the negative electrode and negatively charged ions are attracted to the positive electrode.AQA
- Ionic Bond
- The strong electrostatic attraction between oppositely charged ions.AQA
- Ionic bonding
- Occurs in compounds formed from metals combined with non-metals, where oppositely charged ions are held together by strong electrostatic attraction in a giant…AQA
- Ionic conduction
- The movement of mobile ions, either molten or in aqueous solution, towards the electrode of opposite charge.AQA
- Ionic equation
- Shows only the ions that change, omitting spectator ions, for example Ag⁺(aq) + Cl⁻(aq) → AgCl(s) for a precipitation reaction.AQA
- Ionic equations
- The ionic equation for chloride is Ag⁺(aq) + Cl⁻(aq) → AgCl(s), and equivalent equations are written for bromide and iodide.AQA
- Ionic equations and state symbols
- Balanced ionic equations show H⁺(aq) as a reactant where appropriate, balancing both atoms and charge and including state symbols where they are given or…AQA
- Ionic formulae and charge balance
- The correct positive and negative ions are combined in the correct ratio so that the charges balance, with subscripts showing the ratio needed for electrical…AQA
- Ionic lattice
- Represented by NaCl because it contains a metal and a non-metal.AQA
- Ionic lattice recognition
- Deducing that a compound is ionic from a diagram by identifying a giant lattice of oppositely charged ions.AQA
- Ionic lattices
- The oppositely charged ions attract each other electrostatically in a giant ionic lattice, arranging in a regular lattice of alternating charges rather than…AQA
- Ionic mobility
- When the compound is melted it dissociates into ions, which are free to move and carry charge.AQA
- Ionic species and charges
- Naming the species with its charge, such as Cu²⁺ or SO₄²⁻, rather than giving just the element name.AQA
- Ionic versus covalent bonding
- The nature of the compound depends on whether the other element is a metal or a non-metal, giving electron transfer or electron sharing.AQA
- Ions in aqueous solution
- When an acid dissolves in water, it ionises to release hydrogen ions, H⁺, and the subscript (aq) shows that the ions are dissolved in water.AQA
- Ions with different charges
- Transition metals form ions with different charges, such as iron in FeSO₄ being 2⁺ and iron in FeCl₃ being 3⁺.AQA
- Isotope
- Atoms of the same element with the same number of protons but a different number of neutrons (and therefore a different mass number).OCR
- Isotope notation
- The mass number is written as a superscript before the element symbol, such as ²³Na.AQA
- Isotopes
- Atoms of the same element with different numbers of neutrons and therefore different mass numbers.AQA
J
- Justification using equations
- Explaining a prediction by referring to Le Chatelier's Principle and the relevant feature of the equation, such as gas molecule numbers or…AQA
- Justified judgement
- A clear judgement that states whether the alloy is suitable and why, supported by at least one property.AQA
K
- Key experiments in atomic history
- Thomson's discovery of the electron and Rutherford's alpha-particle scattering experiment provided evidence that changed the atomic model.AQA
L
- Landfill
- The place glass would otherwise be sent, and the amount sent there is reduced by recycling.AQA
- Large hydrocarbon molecules
- Molecules in crude oil fractions that are less useful as fuels because they are viscous, hard to ignite and burn less cleanly.AQA
- Lattice
- A repeating three-dimensional arrangement of atoms that extends throughout the whole piece of metal.AQA
- Law of Conservation of Mass
- The principle that no atoms are lost or made during a chemical reaction, so the mass of the products equals the mass of the reactants.OCR
- Layered lattice arrangement in pure metals
- In pure metals, the positive ions are arranged in regular layers, like sheets stacked on top of one another.AQA
- Layered structures
- The bonded atoms arrange into flat layers of hexagonal rings, like a honeycomb, with no covalent bonds between the layers.AQA
- Layers of atoms and sliding
- Because the atoms are all the same size, the layers can slide over one another when a force is applied, so the metal is soft.AQA
- Layers of iron atoms
- The layers in the structure that can slide over one another more readily when a force is applied, because fewer carbon atoms disrupt them.AQA
- Le Chatelier's principle
- When a system at equilibrium is subjected to a change in conditions, the position of equilibrium shifts in the direction that opposes the change.AQA
- Leachate
- The solution produced by bacteria, containing copper compounds and other dissolved substances, not pure copper metal.AQA
- Life cycle assessment
- Tracks a product through raw material extraction, manufacture, use and disposal.AQA
- Life Cycle Assessment (LCA)
- An evaluation of the environmental impact of a product throughout its entire life, from extraction of raw materials to disposal.OCR
- Life-cycle thinking
- Considering every stage from raw material extraction through manufacture, packaging, transport, use and repair to disposal, recycling or reuse.AQA
- Limewater
- An aqueous solution of calcium hydroxide used to test for carbon dioxide.AQA
- Limitations of early classification systems
- Early periodic tables were incomplete and some elements were placed in inappropriate groups if the strict order of atomic weights was followed.AQA
- Limitations of early models
- The model does not include a nucleus, protons or neutrons, and was inconsistent with large-angle alpha particle deflections.AQA
- Limitations of flame tests
- The method only works for some cations and cannot detect non-metal ions.AQA
- Limitations of models
- Solid inelastic spheres with no forces between them cannot explain energy changes during melting and boiling.AQA
- Limited resources
- Resources that will eventually run out, such as the fossil fuels supplying much of the energy for extracting raw materials and manufacturing products.AQA
- Limiting reactant
- The reactant that runs out first when reactants are not in the exact ratio of the balanced equation, fixing the maximum amount of product.AQA
- Limiting rules to specified groups
- The method applies only to the metals in Groups 1 and 2 and the non-metals in Groups 6 and 7.AQA
- Line spectra
- The output of flame emission spectroscopy, in which each metal ion produces a characteristic pattern of lines at particular wavelengths.AQA
- Line-bond representations
- Representations that use one line per single bond, for small molecules, polymer repeating units and parts of giant covalent structures.AQA
- Link between ion formation and reactivity
- The more readily a metal loses electrons, the more reactive it is, and this ion formation underlies the reactivity series.AQA
- Link between ionisation and pH
- Because ionisation is complete, the concentration of H⁺ ions equals the concentration of the acid for monoprotic acids, giving a low pH.AQA
- Local and global water availability
- The choice of treatment depends on the water source and local conditions, so treatment is not the same everywhere.AQA
- Long-term changes in atmospheric composition
- Volcanic gases shaped the atmosphere's long-term composition, and nitrogen is now the most abundant gas in it.AQA
- Low carbon steel
- An iron alloy containing only a small proportion of carbon, which is softer and more easily shaped.AQA
- Low density
- A small mass for a given volume, which makes aluminium alloys suitable for aircraft, bicycles, vehicle parts and drink cans.AQA
- Low-grade ores
- Ores that contain only small percentages of copper compounds, so large masses of rock must be processed to obtain useful copper.AQA
- Lubricants
- Reduce friction between moving surfaces, for example in engines and machinery.AQA
M
- Macromolecules
- DNA is a very large molecule, often described as a macromolecule, made of many repeating units.AQA
- Malleability
- The regular packing allows layers of atoms to slide over one another when a force is applied, so metals can be bent and shaped.AQA
- Malleability and ductility
- Malleable means the metal can be bent or hammered into shape, while ductile means it can be drawn into wires.AQA
- Malleable
- Able to be bent, pressed or rolled into shape without cracking, as low carbon steel is.AQA
- Manufacture of glass, building materials and clay ceramics
- Glass is made by melting sand with sodium carbonate and limestone, building materials are quarried directly, and clay ceramics are made by shaping and firing…AQA
- Masked
- Describes a flame colour that is hidden when a sample containing a mixture of ions is used, because one colour can hide another.AQA
- Mass and volume relationships
- For a fixed mass of solute, increasing the volume of the solution decreases the concentration, while for a fixed volume, increasing the mass of the solute…AQA
- Mass number
- A count of protons plus neutrons, which is not the same as the atomic number.AQA, OCR
- Mass number calculation
- The sum of the protons and neutrons in an atom is its mass number.AQA
- Mass relationships in equations
- Calculating the mass of each substance by multiplying its balancing number by its Mr, or by converting a given mass to moles and back to mass.AQA
- Mass–amount relationship
- For a pure substance, amount in moles n = mass m ÷ Mr, and rearranging the same relationship gives mass m = n × Mr.AQA
- Mass–mole calculations
- Converting between mass and chemical amount using the relationship amount in moles equals mass divided by molar mass.AQA
- Mass–mole conversions
- The numerical bridge that lets you convert between mass in grams and amount in moles using n = m ÷ Mr, rearranging to m = n × Mr when mass is required.AQA
- Mass–volume relationships
- For a fixed mass of solute, increasing the volume decreases the concentration, and the mass of solute and volume of solution are related to the concentration.AQA
- Matching supply of fractions to demand
- Cracking helps match the supply of hydrocarbon fractions to demand, since longer-chain fractions are less useful as fuels.AQA
- Materials and their uses
- Knowing the exact metals in each alloy allows you to compare their properties and suggest suitable uses.AQA
- Materials from crude oil and plants
- Plastic comes from crude oil, while paper comes from trees.AQA
- Materials selection for function
- Because the alloy is a mixture, its composition can be adjusted to produce the desired hardness, colour and cost.AQA
- Materials selection for uses
- Matching the demands of the job to the data rather than choosing the cheapest or most familiar option.AQA
- matrix
- The material, also called the binder, that surrounds and binds together the other material and helps transfer forces through the composite.AQA
- Mean and range
- The mean is the sum of the measurements divided by the number of measurements, and the range is the difference between the highest and lowest values.AQA
- Measurement and uncertainty
- Whenever a measurement is made there is always some uncertainty about the result obtained, which is the range of values within which the true value is likely…AQA
- Measurement of concentration
- Using the intensity of the lines, often by comparing the sample spectrum with spectra from solutions of known concentration.AQA
- Medicine
- Nanoparticles can carry drugs to specific cells or be used in imaging and sensors because of their small size and high surface area.AQA
- Medicines
- Combinations of an active ingredient with other components that affect dose, stability or delivery.AQA
- Melting
- Heating a solid so particles vibrate more until the forces holding the regular arrangement are overcome and the solid becomes a liquid.AQA
- Melting and boiling
- Changes that require energy to overcome the forces holding particles together.AQA
- Melting and boiling as physical changes
- Melting or boiling requires breaking the strong electrostatic forces of attraction between ions throughout the giant lattice, not breaking individual covalent…AQA
- Melting and boiling of simple molecular substances
- The molecules separate and move further apart or past one another, but each molecule keeps its covalent bonds.AQA
- Melting and boiling point data
- Measurements of the temperatures at which a substance melts and boils, which for a pure substance are single sharp temperatures at a stated pressure.AQA
- Melting and boiling points
- These are relatively low for small-molecule substances because the weak forces between molecules are overcome, not the covalent bonds within molecules.AQA
- Melting point depression
- An impure substance melts below the known melting point, and the change happens over a range of temperatures.AQA
- Melting points
- Very high for giant covalent substances because melting requires breaking many strong covalent bonds.AQA
- Membrane separation and reverse osmosis
- Salty water is forced at high pressure through a partially permeable membrane that allows water molecules through but retains most dissolved ions.AQA
- Metal and acid reactions
- Magnesium reacts rapidly with dilute acid, zinc and iron react with dilute acid with zinc faster, and copper reacts with neither water nor dilute acid.AQA
- Metal and non-metal compounds
- Compounds in which the metal atoms lose electrons to form positive ions and the non-metal atoms gain electrons to form negative ions.AQA
- Metal and water reactions
- Potassium, sodium and lithium react with cold water to form the metal hydroxide and hydrogen, while calcium reacts steadily and magnesium very slowly.AQA
- Metal extraction
- A process in which the metal oxide loses oxygen and is therefore reduced.AQA
- Metal ions in solution
- The type of sample the method requires, so the metal ions must be in solution for it to be applied.AQA
- Metal reactions with water and acids
- The reactions, if any, of the named metals with water or dilute acids, including the products and observations.AQA
- Metallic Bond
- The electrostatic attraction between positive metal ions and a sea of delocalised electrons.AQA
- Metallic bonding
- The electrostatic attraction between the positive ions and the shared delocalised electrons, acting throughout the structure so it is strong.AQA
- Metallic bonding and physical properties
- Melting points and boiling points decrease down the group because metallic bonding weakens as ions become larger and charge density falls.AQA
- Metallic bonding and structure
- Transition metals have stronger metallic bonding and more delocalised electrons than Group 1 metals, which is why the differences between the groups arise.AQA
- Metallic bonds
- Strong bonds that hold positive ions to a sea of delocalised electrons in a metal.AQA
- Methane sources
- Livestock farming, especially cattle and sheep, releases methane through digestion and waste, and landfill sites release methane as organic waste decomposes…AQA
- Microbes
- Impurities such as bacteria that can cause disease and are reduced by chlorination to kill them.AQA
- Mining of raw materials
- Potassium chloride, potassium sulfate and phosphate rock are obtained by mining.AQA
- Misleading
- Presenting a limited LCA as a complete comparison, when the LCA itself may be valid for its limited scope.AQA
- Mitigation actions
- Actions to reduce emissions of carbon dioxide and methane, such as generating electricity from renewable sources or capturing gas from landfill sites.AQA
- Mixture
- Two or more elements or compounds that are not chemically combined together, so the substances keep their own identities.AQA
- Mixtures
- Components that are not chemically combined and can be separated by physical means.AQA
- Mixtures and compounds
- Separation only divides a mixture, whereas a reaction forms new products.AQA
- Mixtures in natural products
- Pure milk is a mixture of water, fats, proteins, sugars and minerals, so it is not pure in the chemical sense.AQA
- Mixtures versus compounds
- Physical methods separate mixtures, not compounds, because the elements in a compound are chemically combined.AQA
- Mixtures versus pure substances
- A mixture usually melts or boils over a range of temperatures because its different components change state at different temperatures, while a pure substance…AQA
- Mobile and stationary phases
- Components partition between these two phases as the solvent rises, which separates them.AQA
- Mobile charge carriers
- The delocalised electrons in a metal, which are free to move through the giant metallic lattice.AQA
- Mobile ions
- Ions that are free to move within the liquid or solution and carry charge through it, so a current flows.AQA
- Mobile phase
- The phase that moves, a solvent or gas that carries the substances through or over the stationary phase.AQA
- Model limitations
- Each model has limits: dot and cross diagrams show electrons but not shape, ball and stick models show three-dimensional shape but not electron pairs, and…AQA
- Molar gas volume at room temperature and pressure
- The value of 24 dm³ that applies at room temperature and pressure and is used to find gas volume from moles.AQA
- Molar mass
- The mass of one mole of a substance, found by adding the relative atomic masses in the formula and expressed in g/mol.AQA
- Mole
- The amount of a substance obtained by dividing its mass by its molar mass, giving moles of atoms or molecules.AQA, OCR
- Mole as the amount unit
- The amount unit linking mass to particles, where one mole of a substance has a mass in grams equal to its relative formula mass, Mr.AQA
- Mole calculations
- Multiplying the amount in moles by 6.02 × 10²³ gives the number of particles, and dividing the number of particles by 6.02 × 10²³ gives the amount in moles.AQA
- Mole calculations from mass and relative formula mass
- Finding moles by dividing mass by relative formula mass, then multiplying by 24 dm³ to find gas volume at room temperature and pressure.AQA
- Mole calculations from masses
- Converting the masses in grams to amounts in moles, using the correct Mr for each substance.AQA
- Mole concept
- The mole is the chemist's counting unit for particles, and one mole of a substance has a mass in grams numerically equal to its relative formula mass.AQA
- Mole ratio
- The ratio required by the balanced equation, used to convert the amount of limiting reactant into the amount of product in moles.AQA
- Mole ratios
- The balancing-number ratio from the equation, applied after converting a given mass to moles, to find the moles of the required substance.AQA
- Molecular formulae
- The formulae C₂H₄, C₃H₆, C₄H₈ and C₅H₁₀ for the first four alkenes, all fitting the general formula CₙH₂ₙ.AQA
- Moles and concentration
- When concentration is in mol dm⁻³, moles are first calculated using n = c × V, then converted to mass using m = n × Mᵣ.AQA
- Molten compounds
- Compounds that are molten so that their ions are free to move and conduct electricity.AQA
- Molten state
- State in which the ions of the compound are free to move, unlike in the solid state.AQA
- monomer
- The molecule whose atoms all become part of the polymer chain, with its double bond becoming a single bond in the repeating unit.AQA
- Monomer structure
- Each monomer has two of the same functional group, such as a diol with two alcohol groups or a dicarboxylic acid with two carboxylic acid groups.AQA
- Monomer to polymer
- Many small monomer molecules join together to form polymer molecules.AQA
- Monomers
- Small repeating units that covalently bond to form a polymer.AQA
- Monomers and polymerisation
- Ethene is the monomer used to make poly(ethene), and the same monomer can produce two different polymers depending on the conditions used.AQA
- Movement of delocalised electrons
- The delocalised electrons move with the ions and continue to hold the structure together, so the metallic bonding is not broken.AQA
N
- n = m ÷ Mᵣ
- The relationship used to convert between mass and moles when the question gives masses in grams.AQA
- N:P:K ratio
- Numbers where each represents the percentage by mass of that element in the fertiliser.AQA
- Naming compounds from ions
- The salt is named by giving the positive ion name first and the acid-derived anion name second.AQA
- Nanometre range
- One nanometre is 1 × 10⁻⁹ m, so nano dimensions are much smaller than everyday objects.AQA
- Nanometres as a unit of length
- A unit of length in which 1 nm = 1 × 10⁻⁹ m, used when discussing atomic dimensions.AQA
- Nanoparticle
- A particle with dimensions between 1 and 100 nanometres, possessing a very high surface area to volume ratio.AQA
- Nanoparticle properties
- Controlling particle size, shape and surface at the nanoscale can produce new or improved properties.AQA
- Nanoparticles
- Particles with at least one dimension in the range 1 to 100 nanometres, sitting between individual atoms or molecules and bulk material.AQA
- Nanoscience
- Refers to structures that are 1–100 nm in size, of the order of a few hundred atoms.AQA
- Native metals
- Unreactive metals such as gold are found in the Earth as the metal itself, described as native.AQA
- Natural greenhouse effect
- Trapped energy keeps the average surface temperature higher than it would otherwise be, warm enough for liquid water and life.AQA
- Natural resources
- Resources that occur naturally and, supplemented by agriculture, provide food, timber, clothing and fuels.AQA
- Natural versus synthetic carbon compounds
- Many compounds such as carbohydrates and proteins occur naturally, while others such as plastics and medicines are synthetic.AQA
- Natural versus synthetic materials
- Natural products are obtained from plants, animals or the Earth without chemical synthesis, while synthetic products are made by chemical processes.AQA
- Naturally occurring polymers
- DNA is a naturally occurring polymer rather than a synthetic one, found in living organisms.AQA
- Neutral atom
- An atom in which the number of electrons equals the atomic number.AQA
- Neutral atoms
- In an atom the number of electrons is equal to the number of protons in the nucleus, so the positive and negative charges balance exactly.AQA
- Neutral molecules
- Molecules that have no overall electric charge, even though individual atoms in a bond may carry small partial charges.AQA
- Neutralisation
- The process in which acids are neutralised by alkalis and bases to produce salts and water, and by metal carbonates to produce salts, water and carbon dioxide.AQA
- Neutralisation and ionic equations
- In neutralisation, H⁺(aq) from the acid reacts with OH⁻(aq) from the alkali to form water, H₂O(l), and this ionic equation applies to any acid reacting with…AQA
- Neutralisation and salt formation
- Adding the insoluble oxide or carbonate a little at a time until it is in excess and no more dissolves, so the acid is used up and a soluble salt forms.AQA
- Neutralisation endpoint
- The point at which no more solid reacts or dissolves, showing that all the acid has been used up and excess solid remains.AQA
- Neutrality
- Means hydrogen ion concentration equals hydroxide ion concentration, giving pH 7 for aqueous solutions at the usual laboratory temperature.AQA
- neutron
- A neutral particle in the nucleus, supported by Chadwick's evidence.AQA
- Nitrogen source
- Nitrogen is obtained from air, which is approximately 78% nitrogen by volume, and can be separated from air by fractional distillation of liquid air.AQA
- Noble gases
- The elements in Group 0 of the periodic table, which are unreactive non-metals.AQA
- Nomenclature
- The names use the stem for the number of carbon atoms, eth-, prop-, but- and pent-, with the ending -ene showing the C=C double bond.AQA
- Non-electrolyte
- A substance such as pure water or a solid ionic compound that lacks mobile ions and so is not an electrolyte in this sense.AQA
- Non-enclosed systems
- In these, matter can leave or enter as a gas, so the mass reading may change even though atoms are conserved.AQA
- Non-metal character of the halogens
- The halogens are non-metals, so they lack the typical properties of metals such as conduction of electricity and malleability.AQA
- Non-metals
- Found towards the right and top of the periodic table, they are poor conductors of electricity, often brittle as solids, and tend to form negative ions or…AQA
- Non-metals in the series
- Hydrogen and carbon are included among the metals in the series for prediction.AQA
- Non-rechargeable cell
- A cell that produces electricity from chemical reactions and cannot be recharged by passing current through it.AQA
- NPK fertilisers
- Fertilisers that supply nitrogen, phosphorus and potassium, with the potassium coming from mined soluble potassium salts.AQA
- Nuclear charge
- The charge of the nucleus, which changes when the proton number changes.AQA
- nuclear model
- Describes an atom as a tiny, dense, positively charged nucleus surrounded by electrons in shells, with most of the atom being empty space.AQA
- Nuclear model of the atom
- The model in which the mass and positive charge are concentrated in a tiny central nucleus, replacing the plum pudding model.AQA
- Nucleotide monomers
- The monomers of DNA are called nucleotides, and there are four different nucleotides in DNA.AQA
- Nucleus as the mass centre
- Almost all of the mass of an atom is in the nucleus, which contains protons and neutrons.AQA
O
- Observation and description of chemical change
- Describing observations such as fizzing, movement on the water surface and the metal becoming smaller.AQA
- Observation and product identification
- Recording observations at both electrodes, such as bubbles, colour or gas test results, and identifying products using suitable tests.AQA
- Odourless
- Carbon monoxide has no smell, so it cannot be smelled.AQA
- Opinion
- A personal or group viewpoint rather than a conclusion drawn from the full evidence base.AQA
- Oppositely charged ions
- The particles between which ionic bonding is the electrostatic attraction.AQA
- Ordering by experimental observation
- Metals are placed in order by comparing the vigour of their reactions rather than their physical appearance or density.AQA
- Orders of magnitude
- How many powers of ten separate two values, where an order of magnitude is a factor of 10.AQA
- Ores and metal compounds
- Most metals are found as compounds in ores, which are rocks containing a metal compound in sufficient amount to be extracted economically.AQA
- Organic matter
- Material in sewage and agricultural waste water that includes food waste, faeces and plant material, and is broken down by microorganisms in rivers, using up…AQA
- Origin of crude oil
- The remains of an ancient biomass consisting mainly of plankton that was buried in mud.AQA
- Outer electrons
- The electrons in the outer shell of an element, which are the electrons involved in bonding and reactions.AQA
- Outer shell electrons
- Group 7 atoms have seven electrons in their outer shell, so each needs to gain one electron to achieve a stable noble gas configuration.AQA
- Overall cell reaction
- The overall chemical change is hydrogen plus oxygen forming water, with the balanced equation 2H₂ + O₂ → 2H₂O.AQA
- Overall energy change
- Energy absorbed for bonds broken minus energy released for bonds made; a negative result means the reaction is exothermic overall and a positive result means…AQA
- Overcoming intermolecular forces
- When a substance melts or boils, energy is transferred and used to overcome the weak intermolecular forces between the molecules.AQA
- Oxidation
- The gain of oxygen in a chemical reaction, for example when carbon gains oxygen and is oxidised to carbon dioxide.AQA
- Oxidation and reduction
- Oxidation is loss of electrons and reduction is gain of electrons.AQA
- Oxidation and reduction at electrodes
- Hydrogen is oxidised at the anode and oxygen is reduced at the cathode, so the overall reaction produces water as the only chemical product.AQA
- Oxidation at the anode
- At the positive electrode, oxide ions are oxidised to oxygen: 2O²⁻ → O₂ + 4e⁻.AQA
- Oxidation State
- A number assigned to an element in chemical combination that represents the number of electrons lost or gained.OCR
- Oxidation states of iron
- Iron(II) and iron(III) give different colours, so a green precipitate shows the original solution contained iron(II) ions, not iron(III) ions.AQA
- Oxide layers
- Aluminium reacts quickly with oxygen in air to form a thin, tough layer of aluminium oxide, Al₂O₃, on its surface.AQA
- Oxides of nitrogen
- At the high temperatures inside engines and furnaces, nitrogen and oxygen from the air react to form these.AQA
- Ozone
- A reactive gas that destroys microbes by oxidation.AQA
P
- Paints
- Formulations of pigment, binder, solvent and additives that together give colour, adhesion and durability.AQA
- Particle diagram
- A representation showing different types of particles mixed but not bonded together.AQA
- Particle Model
- A scientific model used to explain the properties of solids, liquids, and gases by describing the arrangement and movement of the particles they are made of.OCR
- Particle model of matter
- A model linking the arrangement, spacing and movement of particles, and the forces between them, to properties such as shape, volume or compressibility.AQA
- Particle size and atomic dimensions
- A typical atom is roughly 0.1–0.3 nm across, so a 1–100 nm structure contains of the order of a few hundred atoms.AQA
- Particle size and properties
- Reducing particle size increases surface area for the same mass, which can make the material more effective per gram.AQA
- Particle types
- The mole can be applied to any stated particle, including atoms, molecules, ions and electrons.AQA
- Particulate pollution
- Tiny solid particles, mainly soot and unburnt carbon, released by incomplete combustion of fuels and able to remain suspended in the air.AQA
- Particulates
- Tiny solid or liquid particles suspended in the air, which solid particles and unburned hydrocarbons can join together to form in the atmosphere.AQA
- Patterns in organic chemistry
- The generality that compounds sharing a functional group undergo the same type of reaction, even when their carbon chains differ in length.AQA
- Patterns in properties
- Chemical and physical properties repeat as you move through the elements in order of atomic number.AQA
- Peer review
- Other experts examine methods and conclusions before publication, which improves quality but does not prove a claim.AQA
- Peer-reviewed evidence
- Research that has been checked by other experts before publication.AQA
- Percentage by mass
- The contribution of one element to the total mass of a compound, found by dividing the element's total mass by Mᵣ and multiplying by 100.AQA
- Percentage composition
- The percentages of all elements in a compound, which should sum to 100% as a useful check.AQA
- Percentage yield
- A value that depends on how much product is actually collected, unlike atom economy which depends only on the reaction pathway chosen.AQA
- Period
- Determined by the number of occupied electron shells in an atom.AQA
- periodic table
- A table in which elements are arranged in order of increasing atomic number, grouping together elements with similar properties.AQA
- Periodic table group patterns
- The number of electrons gained or lost equals the distance from the nearest noble gas group, and the sign shows whether electrons are lost or gained.AQA
- Periodic table layout
- Metals are found to the left and towards the bottom of the periodic table, while elements towards the top right are not metallic.AQA
- Periodic table ordering
- The arrangement of the modern periodic table by increasing atomic number rather than by atomic mass.AQA
- Periodic table structure
- Metals occupy the large block on the left, centre and lower part of the table, while non-metals form a much smaller region towards the top right.AQA
- Periodic trends
- Going down Group 0, relative atomic mass, atomic radius and boiling point increase, while reactivity stays very low.AQA
- Periodic trends and group properties
- Transition metals have high melting points, high densities and are strong and hard, whereas Group 1 metals have low melting points, low densities and are soft…AQA
- Periodic trends in reactivity
- Going down Group 1, the reactivity of the elements increases, so rubidium and caesium would react even more vigorously than potassium.AQA
- Periodicity
- Similar properties occur at regular intervals, which is why the table is called a periodic table.AQA
- Periods
- Horizontal rows in the periodic table, across which the outer-shell electron count increases by one per element.AQA
- Petrochemical industry
- Produces many useful materials on which modern life depends, such as solvents, lubricants, polymers and detergents.AQA
- Petrochemicals
- Products of the petrochemical industry made from hydrocarbon feedstocks, including plastics, synthetic fibres, detergents, medicines, lubricants and solvents.AQA
- pH probe
- An electronic sensor connected to a meter that gives a numerical reading and is more precise and objective.AQA
- pH scale
- A continuous scale running from 0 to 14 that tells you how acidic or alkaline an aqueous solution is.AQA
- Phosphate rock
- A substance containing insoluble calcium phosphate, meaning plants cannot absorb it.AQA
- Photosynthesis
- A process in which carbon dioxide is taken in from the atmosphere and used to produce glucose, while oxygen is released.AQA
- Photosynthesis and oxygen accumulation
- Photosynthesis by algae and plants removed carbon dioxide and added oxygen, allowing oxygen levels to rise.AQA
- Physical and chemical properties of metals and non-metals
- Metals and non-metals differ in physical properties such as conductivity, malleability and melting point, and in chemical behaviour such as forming positive…AQA
- Physical change
- A change such as melting ice in which the same substance remains, so no new substance forms.AQA, OCR
- Physical properties of fractions
- Boiling point increases, viscosity increases and flammability decreases as molecular size increases.AQA
- Physical properties of metals
- Characteristic properties such as electrical conductivity, malleability and shiny appearance apply to the majority of elements.AQA
- Physical state
- The state of a substance under the stated conditions, such as metals usually solid, water liquid, and gases including H₂, O₂ and CO₂.AQA
- Physical versus chemical change
- Physical separation processes do not involve chemical reactions, whereas a chemical reaction does make a new substance.AQA
- Physical versus chemical separation methods
- Physical methods such as filtration, distillation, crystallisation and chromatography separate mixtures by differences in physical properties and do not break…AQA
- Phytoextraction
- The use of plants to absorb metal compounds from the soil.OCR
- Phytomining
- Plants absorb metal ions from the soil through their roots, are harvested and burned, and the ash contains the metal compound, which is then processed.AQA
- plum pudding model
- A model picturing the atom as a ball of positive charge with negative electrons embedded in it, so charge was spread evenly throughout.AQA
- Pollution of water, air and soil
- Water running through spoil heaps can become acidic or carry dissolved metals, polluting rivers and groundwater, and fossil fuels burned by machinery and…AQA
- Poly(ethene)
- The polymer of ethene, named by adding 'poly' before the monomer name, whose repeating unit is –CH₂–CH₂–.AQA
- Polyester
- The polymer formed when a dicarboxylic acid and a diol react, with water eliminated.AQA
- Polymer architecture
- Using two different monomers with matching pairs of groups gives a regular alternating pattern in the polymer chain.AQA
- Polymer notation
- A representation in which the repeating unit is placed in brackets with n outside, where n is a large number.AQA
- Polymer structure
- Polymer molecules are long chains, so many intermolecular forces act along each chain, and heating weakens the forces between chains so the chains can slide…AQA
- Polymers
- Materials such as poly(ethene) and poly(propene) made by polymerising alkenes from cracking, used for bags and bottles.AQA
- Positive charge of the nucleus
- Alpha particles, which are positive, were repelled, showing that the nucleus is positively charged.AQA
- Positive metal ions
- Ions that sit in a regular lattice and are held to the electron sea by strong electrostatic attraction.AQA
- Positive result
- The limewater turning milky or cloudy when carbon dioxide is present.AQA
- Potability
- Being about safety rather than purity, depending on safety standards rather than absence of all impurities.AQA
- Potable
- A term used to distinguish drinking water from other water, such as sea water or waste water, which may be unsafe.AQA
- Potable water
- Water that is safe to drink, containing dissolved substances but with sufficiently low levels of microbes and contaminants.AQA
- Potential difference
- Produced by the flow of electrons through an external circuit, it can drive a current that can do useful work.AQA
- Potential energy and temperature
- Energy supplied during melting or boiling increases the potential energy of the particles rather than their average kinetic energy, so the temperature stays…AQA
- Practical data handling
- Recording initial and final temperatures with the same thermometer and the same units, and stating the temperature change clearly, including whether it is a…AQA
- Practical measurement and accuracy
- Measure the distance travelled by each spot from the baseline to the centre of the spot, and measure the solvent front distance from the same baseline.AQA
- Pre-determined conclusions
- Results that a selective LCA can be misused to reach, for example in support of claims for advertising purposes.AQA
- Precipitate
- An insoluble solid that emerges from a liquid solution during a chemical reaction.OCR
- Precipitate colours
- The characteristic colours are white for silver chloride, cream for silver bromide and yellow for silver iodide, and these colours allow the halide ion…AQA
- Precipitation of carbonates
- Some dissolved carbon dioxide reacted to form carbonate compounds, which precipitated as insoluble solids.AQA
- Precipitation reactions
- Silver ions combine with halide ions to form insoluble silver halides, which form a solid suspension.AQA
- Precipitation tests
- The colour is an observation of the solid formed when sodium hydroxide solution is added, not of the solution before reaction.AQA
- Precision
- How close repeated measurements are to each other, regardless of whether they are accurate.OCR
- Precision of measurements
- A smaller range usually indicates more precise measurements, so the spread of results can be compared to comment on precision.AQA
- Predicting electrolysis products
- Identifying the ions present, including H⁺ and OH⁻ from water, then applying the cathode and anode rules to name the product at each electrode.AQA
- Predicting properties
- Predictions should be based on trends in the group, such as a halogen lower down being less reactive and having a higher melting point.AQA
- Predicting trends from the reactivity series
- The tendency to form positive ions explains observed reactions with water, acid and oxygen, and can be used to predict and explain trends in reactivity.AQA
- Prediction and confirmation in science
- Mendeleev forecast the properties of missing elements, and later discoveries matched his predictions, showing a model tested and strengthened by new evidence.AQA
- Prediction from patterns
- The trend can be used to predict that rubidium and caesium react more vigorously than potassium, sometimes explosively.AQA
- Prediction from structure
- Identifying the functional group of an unfamiliar compound and applying the known reactions of that group to predict its behaviour.AQA
- Predictive power of scientific models
- The approach turned the periodic table into a predictive model that not only organised known elements but also made testable forecasts.AQA
- Prefixes meth-, eth-, prop- and but-
- Stems used in the names to show one, two, three or four carbon atoms, counting the carbon of the –COOH group.AQA
- Preparing soluble salts
- A soluble salt can be prepared by reacting an acid with an insoluble solid, which dissolves the solid and forms a salt in solution.AQA
- Prioritising chemical properties over atomic weight
- Where the next atomic weight would have placed an element in a group that did not match its chemistry, he swapped the order.AQA
- Procedural techniques for precision
- Accurate procedural techniques, such as rinsing the burette with the acid and reading the bottom of the meniscus at eye level, to ensure precise measurements.AQA
- Processing resources
- Crude oil must be fractionally distilled before petrol can be used for transport.AQA
- Product yield
- The final yield of product is greater than before the change, although some of the added reactant remains.AQA
- Product, service and event impacts
- Emissions added at each stage, since transport, manufacture, use and waste disposal can each add emissions.AQA
- Products of combustion
- The gases released into the atmosphere when a fuel is burned may include carbon dioxide, water vapour, carbon monoxide, sulfur dioxide and oxides of nitrogen.AQA
- Progression from nuclear model to modern atom
- The atomic model develops as a sequence of evidence-led changes rather than a single event.AQA
- Properties linked to uses
- Soda-lime glass is used for windows, bottles and drinking glasses because it is transparent, rigid and relatively cheap.AQA
- Properties of gold and its alloys
- Pure gold is a soft, dense metal that is too soft to wear well in jewellery, so added metals make the gold harder and more durable while keeping its…AQA
- Properties of solids, liquids and gases
- A solid has a fixed shape and volume, a liquid has a fixed volume but a shape that flows to fit the container, and a gas changes both shape and volume to fill…AQA
- Properties required of the final product
- The qualities the final product must have, such as strength, flexibility, appearance or electrical conductivity, which set how pure the recycled material must…AQA
- Proportions and properties
- The properties of the formulation depend on which components are present and on their proportions.AQA
- Proportions of gases
- The fractions of different gases in the atmosphere, which have been much the same as they are today for 200 million years.AQA
- Protective oxide layer
- A thin, adherent oxide layer formed on the surface by chromium that seals the metal beneath from water and oxygen.AQA
- proton
- The name given to the positive particles found in the nucleus of an atom, carrying a relative charge of 1⁺ and a relative mass of 1.AQA
- Proton number
- The number of protons in an atom, which defines which element the atom is.AQA
- Provisional nature of science
- Scientific explanations are provisional and develop over time, so theories are not fixed and may be revised with new evidence.AQA
- Provisional nature of scientific models
- Such mismatches showed that atomic weight was not the fundamental property controlling chemical behaviour, so early tables were provisional and required…AQA
- Pure substance
- A single element or compound, not mixed with any other substance.AQA, OCR
- Pure water
- In a chemistry context, water that contains only H₂O molecules and no dissolved substances.AQA
- purity
- The excess solid guarantees the acid is used up and filtration removes the excess solid, giving a pure salt.AQA
- Purity and impurities
- A pure substance contains only one substance, while an impurity is something else present that lowers the melting point and raises the boiling point.AQA
- Purity testing
- Melting point and boiling point data can be used to test purity, as a substance that melts sharply at the expected temperature is likely to be pure.AQA
- Purpose of excess
- To ensure that all of the other reactant is used and the reaction is driven to completion.AQA
Q
- Qualitative
- Describes a test that shows the presence or absence of sulfate ions rather than their concentration.AQA
- Qualitative chemical tests
- Bromine water, an orange-brown solution, is used as a test for alkenes and turns colourless when shaken with one.AQA
- Qualitative identification
- A positive result is a distinctive flame colour that matches a known cation, so the test identifies rather than measures the amount.AQA
- Qualitative identification by comparison with standards
- The observed colour is used to identify an unknown cation by comparison with the known colours, and the test is qualitative and does not measure the amount of…AQA
- Qualitative prediction
- A description of the direction in which an equilibrium shifts and whether the yield of a product increases or decreases, without calculating numerical…AQA
- Quantitative comparison of acids
- For a given concentration, the stronger acid ionises more completely and so produces a higher concentration of H⁺ ions, giving a lower pH.AQA
- Quantitative comparison of properties
- Comparing materials numerically rather than by impression, reading the table, identifying the property being compared and quoting the figures.AQA
- Quantitative measurement
- Quantities that are objective because instruments give numbers in defined units.AQA
- Quantitative reasoning
- Multiplying each species' Mᵣ by its coefficient and summing for reactants and products supports reacting mass calculations and shows why coefficients matter…AQA
R
- Rapid
- Describes a method that produces a result in seconds or minutes, quickly compared with many chemical tests.AQA
- Rate
- The change in amount of reactant or product per unit time, meaning how quickly reactants are used or products formed.AQA
- Rate measurement
- In the gas-volume method, the initial gradient of a volume-time graph gives a measure of rate, while in the turbidity method a shorter time means a faster rate.AQA
- Rate of movement
- A substance spending more time in the mobile phase moves more and travels further, while one held back by the stationary phase travels less far.AQA
- Rate of reaction
- How fast the reaction happens, rather than how much product is formed.AQA
- Rates of forward and reverse reactions
- Immediately after a concentration change the rates of the forward and reverse reactions become unequal, until a new equilibrium is established.AQA
- Rates of reaction
- The rate is the change in the number of moles divided by the time taken, giving units of moles per second (mol/s).AQA
- Ratio of ions
- The proportion of cations to anions in a model, which gives the empirical formula of an ionic compound.AQA
- Raw material extraction and processing
- The first stage of an LCA, in which the raw materials needed to make the product are extracted and processed.AQA
- Raw materials
- Soda-lime glass is made from sand with sodium carbonate and calcium carbonate, while borosilicate glass is made from sand with boron trioxide.AQA
- Raw materials and their functions
- Sand supplies silicon dioxide, sodium carbonate lowers the melting point, and limestone stabilises the glass and helps it resist water.AQA
- Raw materials and their sources
- Nitrogen and hydrogen are the raw materials, with nitrogen obtained from air and hydrogen commonly obtained from natural gas or by electrolysis of water.AQA
- Reactants
- The substances sealed inside the cell that are used up as the cell discharges.AQA
- Reaction profile
- A curve on which activation energy is shown as the vertical gap from the reactant energy level up to the peak.AQA
- Reaction profiles
- These show the energy of reactants and products and the activation energy as the height from the reactants' energy level to the peak of the curve.AQA
- Reactions in solution
- Dissolved particles mix freely and can collide, so reactions can happen quickly.AQA
- Reactions of alkali metals
- The first three alkali metals react with oxygen to form metal oxides, with chlorine to form white metal chlorides, and with water to form a metal hydroxide…AQA
- Reactions of halogens with metals
- The halogen gains one electron from the metal atom, which loses electrons to form a positive ion, so the compound is an ionic halide.AQA
- Reactions of halogens with non-metals
- Electrons are shared rather than transferred, so the compound formed is covalent, as when hydrogen and chlorine form hydrogen chloride.AQA
- Reactions of hydrocarbons
- During combustion, the carbon and hydrogen in the fuels are oxidised, which is why complete combustion needs plenty of oxygen.AQA
- reactivity
- Being highly reactive because only one electron must be lost, with vigorous reactions with water, oxygen and chlorine.AQA
- Reactivity and electron gain
- The ease of gaining an electron depends on the attraction between the nucleus and the incoming electron, which is affected by atomic radius and shielding.AQA
- Reactivity and ion formation
- The reactivity of a metal is related to its tendency to form positive ions.AQA
- Reactivity of metals
- Aluminium is more reactive than iron yet corrodes less because of its protective oxide layer.AQA
- Reactivity of the C=C double bond
- The carbon–carbon double bond makes alkenes reactive and allows addition reactions that convert them into a wide range of products.AQA
- Reactivity of transition metals
- These metals react slowly with oxygen and water compared with Group 1 metals, for example iron rusts slowly.AQA
- Reactivity series
- A greater difference in reactivity between the two electrode metals gives a larger voltage, because the more reactive metal has a stronger tendency to lose…AQA
- Reactivity series and cathode discharge
- The less reactive positive ion is usually discharged at the cathode; if the metal is more reactive than hydrogen, hydrogen is produced instead.AQA
- Reactivity series and extraction
- Metals more reactive than carbon cannot be extracted with carbon because carbon is not reactive enough to displace them, so they require electrolysis instead.AQA
- Reactivity series and extraction methods
- The method chosen depends on the metal's position in the reactivity series, with carbon reduction for metals less reactive than carbon and electrolysis for…AQA
- Reactivity series and reduction
- If the metal is more reactive than hydrogen, its ions are less easily reduced, so H⁺ ions are reduced instead and hydrogen gas is produced.AQA
- Reactivity series and selective discharge
- Relative reactivity of the elements involved decides which ions are discharged, since at the cathode the more easily reduced positive ion is discharged.AQA
- Reactivity trends
- Elements in a group show similar properties but trends in reactivity, such as Group 1 becoming more reactive down the group.AQA
- Reactivity with oxygen, water and halogens
- Group 1 metals react vigorously with oxygen, water and halogens, while transition metals react slowly or require heating.AQA
- Reagent order and control
- Dilute nitric acid is added before silver nitrate solution, because the nitric acid removes carbonate ions that would otherwise form a white precipitate and…AQA
- Rearrangement of atoms
- During a chemical reaction, bonds break and new bonds form, but the atoms themselves are rearranged rather than created or destroyed.AQA
- Rearranging equations and unit consistency
- Rearranging the same relationship gives both directions, and units must always be included: g for mass and mol for amount, with Mr dimensionless whereas molar…AQA
- Recall a use
- Name one clear use for each alloy specified in the course.AQA
- Recall of examples
- You need to recall two human activities for carbon dioxide and two for methane, naming the activity and the gas it increases.AQA
- Rechargeable cells
- Cells that can be recharged because the chemical reactions are reversed when an external electrical current is supplied.AQA
- Rechargeable cells and batteries
- These store reactants internally and must be recharged, but they are familiar and widely available.AQA
- Recharging
- Storing electrical energy as chemical energy, which is later converted back to electrical energy, rather than creating energy.AQA
- Recognising molecules from formulas
- Recognising a small molecule from its formula is a key skill, using formulas such as H₂, Cl₂, O₂, N₂, HCl, H₂O, NH₃, CH₄ and CO₂.AQA
- Recovery from leachate
- Copper can be recovered from leachate by displacement using scrap iron or by electrolysis.AQA
- Recycling
- Collecting, sorting and reprocessing waste materials into new products, for example melting used aluminium cans to make new ones.AQA
- Recycling and resource conservation
- Recycling metals conserves ore resources, reduces the need for mining and lowers the energy demand and environmental impact of extraction.AQA
- Recycling of reactants
- The remaining hydrogen and nitrogen are recycled back into the reactor, giving unreacted gases further chances to react.AQA
- Recycling, reusing and reducing
- Ways of reducing the use of limited resources, including recycling materials such as metals, glass, paper and plastics, reusing items, and reducing consumption.AQA
- Redox and electron transfer
- Iron atoms lose electrons and dissolve as iron ions, while copper ions gain electrons and form copper metal.AQA
- Redox at electrodes
- At the cathode hydrogen ions gain electrons to form hydrogen gas, and at the anode hydroxide ions lose electrons to form oxygen gas.AQA
- Redox reaction
- A reaction in which one substance is oxidised and another is reduced, the two processes happening together.AQA
- Reducing the use of resources
- Manufacturing fewer new products, which avoids the energy and raw materials needed to make them.AQA
- Reducing use
- Designing and buying less, such as lighter packaging, longer-lasting goods and products that need fewer materials.AQA
- Reduction
- The loss of oxygen in a chemical reaction, for example when iron(III) oxide loses oxygen and is reduced to iron.AQA
- Reduction with carbon
- Metals less reactive than carbon can be extracted from their oxides by heating them with carbon, which removes the oxygen.AQA
- Regular arrangement of ions
- Each ion is surrounded by ions of opposite charge, and the structure extends in three dimensions.AQA
- Regular pattern
- The atoms in a metal are arranged in a regular, repeating pattern, not a random arrangement.AQA
- reinforcement
- The material being bound by the matrix, which may be in the form of fibres or fragments and usually provides strength and stiffness.AQA
- Relationship between bonding and physical properties
- Strong electrostatic forces explain the high melting points and high boiling points of ionic compounds.AQA
- Relationship between structure and physical properties
- The regular layered arrangement is the key reason pure metals are malleable and ductile, as layers can slide over each other when a force is applied.AQA
- Relationship between structure and properties
- The giant arrangement explains the high melting points because many strong attractions must be overcome.AQA
- Relative atomic mass
- A weighted average that reflects the abundance of each isotope, relative to 1/12 of the mass of a carbon-12 atom.AQA
- Relative charge and mass
- Protons have relative charge 1⁺, neutrons have no charge and electrons carry relative charge 1⁻, with protons and neutrons together giving the nucleus almost…AQA
- Relative formula mass
- The sum of the relative atomic masses of all atoms in a substance's formula, found by multiplying each element's relative atomic mass by its subscript before…AQA
- Relative formula mass from relative atomic masses
- Found by adding relative atomic masses for every atom in the formula; for a monatomic element Ar is used, and for a compound or molecular element the Ar…AQA
- Relative mass of subatomic particles
- Protons and neutrons each have a relative mass of 1, while electrons have a relative mass of about 1/1836, which is negligible.AQA
- Removal of carbon dioxide from the atmosphere
- Carbon dioxide dissolved in the water when the oceans formed and carbonates were precipitated, reducing the amount of carbon dioxide in the atmosphere.AQA
- Renewable resources
- Resources such as timber and fresh water, which are not being depleted faster than they are naturally replaced.AQA
- Repeat measurements
- Repeating measurements can reduce uncertainty, and the mean of repeated readings is usually more reliable.AQA
- Repeatability
- The precision obtained when the same person repeats the experiment using the same equipment and method.OCR
- Repeating unit
- The part of the polymer shown with bonds extending from the carbon atoms to indicate continuation of the chain, containing the same atoms as the monomer.AQA
- Repeating units
- The unit placed in brackets with n outside, showing the correct atoms and bonds, with bonds extending beyond the brackets to show the chain continues.AQA
- Representation of ions using symbols and superscripts
- The charge on the ion is written as a superscript after the symbol, and the superscript charge must match the number of electrons removed, with a positive sign.AQA
- Representing combustion symbolically
- Complete combustion is written as hydrocarbon plus oxygen gives carbon dioxide plus water.AQA
- Representing ions with symbols and charges
- The charge on the ion equals the number of electrons lost by the atom, written as a superscript after the symbol, such as Na⁺, Mg²⁺ and Al³⁺.AQA
- Representing organic structures
- Carboxylic acids can be shown as displayed formulae, structural formulae or molecular formulae such as CH₃COOH.AQA
- Reproducibility
- The precision obtained when a different person performs the experiment, or when a different method or equipment is used.OCR
- Required practical investigation
- An investigation of what happens when aqueous solutions are electrolysed using inert electrodes, involving developing a hypothesis.AQA
- Required practical skills
- Skills in measuring temperature, controlling variables, recording data and drawing conclusions about energy transfer, developed by investigating variables…AQA
- Resolution
- The smallest change in the quantity being measured of a measuring instrument that gives a perceptible change in the reading.OCR
- Resource management
- Renewable resources can be used repeatedly if managed carefully, with use not exceeding the rate of replacement.AQA
- Resource reduction as a mitigation strategy
- These impacts are reduced when less raw material is needed, which is why reducing, reusing and recycling matter.AQA
- Reuse
- Using an item again for the same or a new purpose, such as refilling a glass bottle or passing on clothing, so no new material is extracted.AQA
- reversible arrow
- The double arrow used to show that the ionisation of a weak acid is reversible and incomplete, unlike the single arrow used for a strong acid.AQA
- Reversible reaction
- A reaction that may not go to completion because it can reach equilibrium before all reactants convert, so some remain unreacted.AQA
- Reversible reactions
- Reactions that continue in both directions, so the forward and reverse reactions occur at exactly the same rate at equilibrium.AQA
- Rf values
- The distance moved by a substance compared with the distance moved by the solvent front, which can be compared with known values to help identify substances.AQA
- Rf values and identification
- The distance each spot travels relative to the solvent front gives its Rf value, and matching both spot colour and Rf value with known reference spots…AQA
- Risk and uncertainty in nanotechnology
- A risk is a possible harm, so uncertainty about long-term effects is itself a valid reason for caution, because behaviour in the body or environment is not…AQA
- Risk, vulnerability and adaptation
- Risk is the likelihood and seriousness of harm, which is greater where populations are exposed and less able to adapt.AQA
- Role of algae and plants
- These organisms decreased the percentage of carbon dioxide in the atmosphere by photosynthesis.AQA
- Role of carbon dioxide
- Carbon dioxide was the main gas in the Earth's early atmosphere, and the atmospheres of Mars and Venus today are dominated by carbon dioxide.AQA
- Role of evidence in accepting models
- Scientific models are accepted only when evidence supports them, and acceptance can take time.AQA
- Role of gaps in classification
- He left deliberate gaps rather than forcing every known element into a continuous sequence, and for each gap predicted the properties of the missing element…AQA
- Role of volcanic activity
- Intense volcanic activity released large volumes of gases, including water vapour, carbon dioxide and nitrogen.AQA
- Rusting
- An example of corrosion, being the corrosion of iron and steel that requires both oxygen and water.AQA
S
- Sacrificial protection
- A more reactive metal is used so it corrodes in place of iron, losing electrons which flow to the iron.AQA
- Safety and purity
- Potable water is not pure water in the chemical sense, because it still contains dissolved substances.AQA
- Safety in gas tests
- The splint is held at the open end so the gas ignites safely at the mouth.AQA
- Salt formation
- The salt produced when an acid reacts with a base, alkali or carbonate depends on the acid used and the positive ions in the base, alkali or carbonate.AQA
- Salt formation from acids
- Treating phosphate rock with nitric acid, sulfuric acid or phosphoric acid gives different soluble salts that supply phosphate and sometimes nitrate or…AQA
- Same conditions of temperature and pressure
- Equal moles of gases occupy the same volume under the same conditions, so gas volumes are compared only at the same temperature and pressure.AQA
- Saturated
- Describes alkanes, which have only single carbon–carbon bonds.AQA
- Saturated and unsaturated hydrocarbons
- The bromine water test distinguishes unsaturated hydrocarbons, which decolourise it, from saturated hydrocarbons, which do not.AQA
- Saturated Hydrocarbon
- A compound containing only carbon and hydrogen atoms, with only single bonds between the carbon atoms (e.g., alkanes).OCR
- Scale and apparatus in chemistry
- Industry uses large-scale continuous plants with concentrated acids and controlled temperatures, whereas laboratory preparation uses small quantities and…AQA
- Scale and measurement
- A nanometre is 1 × 10⁻⁹ m, so nanoscale objects are far smaller than everyday particles but larger than single atoms.AQA
- Scale and size of atoms
- Atoms are extremely small, with a radius of about 0.1 nm and diameters around 0.2 nm.AQA
- Scale and timescale of environmental change
- The effects are global and long-lasting, spanning decades and continents rather than one local area.AQA
- Scarce
- Describes copper ores as rich, high-grade ores are being used up, while low-grade ores remain.AQA
- scattering experiment
- An experiment in which positively charged alpha particles were fired at thin gold foil, with most passing straight through but some deflected through large…AQA
- Science communication
- Communicating results to the public, policymakers and other scientists allows scrutiny and informed decisions.AQA
- Scientific reasoning
- Reasoning with the provided information to draw justified conclusions about which theory is best supported.AQA
- Scientific research and development
- New applications for nanoparticulate materials are an important area of research, developed alongside testing, regulation and life-cycle assessment.AQA
- Scrap steel
- Steel that has already been used and collected, for example from old cars, buildings or machinery.AQA
- Screening
- A treatment stage that removes large objects from waste water.AQA
- Screening and grit removal
- The first stage, which takes out large objects, rags, plastics and dense grit that would damage pumps or block pipes.AQA
- Sea-level rise
- Melting ice sheets and glaciers, plus thermal expansion of seawater, raise sea level and increase flooding of low-lying land.AQA
- Secondary cells
- Another name for rechargeable cells, which can discharge and then be recharged.AQA
- Sedimentation
- A stage that lets finer suspended solids settle, producing sewage sludge at the bottom and effluent above.AQA
- Selective discharge at the cathode
- At the negative electrode, the ion that gains electrons more readily is discharged, so either hydrogen or the metal is produced.AQA
- Selective LCA
- An assessment devised to evaluate a product that covers only chosen stages, materials or impacts.AQA
- Self-heating cans
- Cans that contain reactants which react exothermically when activated, transferring energy to the food or drink.AQA
- Sensitive
- Describes a method that can detect very small amounts of a substance, sometimes parts per million or less.AQA
- Sensitivity and accuracy
- Being more sensitive means detecting very low concentrations that chemical tests would miss, and being more accurate and precise gives reliable measurements…AQA
- Separation
- The process of sorting a material from a mixture of different materials before it can be reused.AQA
- Separation by cooling and condensation
- On cooling, the ammonia liquefies and is removed.AQA
- Separation by distillation
- The water is heated to boiling, the vapour is cooled and condensed, leaving dissolved salts behind in the original container.AQA
- Separation of mixtures
- Because different substances have different distributions, they move at different rates and separate into spots or bands.AQA
- Separation of mixtures by physical processes
- The process separates the mixture because evaporation and condensation occur repeatedly at different temperatures.AQA
- Separation techniques
- Paper chromatography separates coloured substances by allowing a solvent to move up paper, carrying dissolved dyes at different rates.AQA
- Series
- The positive terminal of one cell connects to the negative terminal of the next, so the voltages add.AQA
- Shared pair
- Each atom contributes one electron to it, and it is attracted to both nuclei, holding the atoms together.AQA
- Shielding and nuclear attraction
- More inner shells shield the outer electron, and because it is further from the nucleus the attraction is weaker, so it is lost more easily.AQA
- Shielding Effect
- The decrease in electrostatic attraction between the nucleus and outer electrons due to the presence of inner electron shells.OCR
- Significance of evidence
- Judging whether a difference is significant by comparing orders of magnitude to see if it is large enough to matter.AQA
- Silicon dioxide
- The main compound in sand, with a giant covalent structure in which each silicon atom is bonded to four oxygen atoms and each oxygen atom is bonded to two…AQA
- Silver halides
- Silver chloride is white, silver bromide is cream and silver iodide is yellow, and these are the silver halides formed when silver nitrate solution is added…AQA
- Silver nitrate with dilute nitric acid
- A test used for halide ions, acidified first so carbonate ions do not produce a misleading precipitate.AQA
- Simple distillation
- Heating a solution to evaporate the solvent, then condensing the vapour to collect the pure solvent.AQA
- Simple molecular substance
- A substance where intermolecular forces between molecules are overcome and the covalent bonds inside each molecule stay intact, so melting points are low.AQA
- Simple molecular substances
- Substances that contain a limited number of atoms joined by covalent bonds, such as hydrogen, chlorine, oxygen, nitrogen, carbon dioxide and methane.AQA
- Simplest ratio shown by a formula
- The formula shows the simplest ratio of ions, not a molecule.AQA
- Simplest whole-number ratio
- The result of comparing mole values by dividing each by the smallest value, used as the coefficients in the balanced equation.AQA
- Simplified model
- A model that omits some greenhouse gases, feedbacks or natural factors, and can be useful if its limitations are stated and it fits the purpose.AQA
- Single superphosphate
- A mixture of calcium phosphate and calcium sulfate produced by treating phosphate rock with sulfuric acid.AQA
- Single, double and triple covalent bonds
- A single bond is one shared pair, a double bond is two shared pairs, and a triple bond is three shared pairs.AQA
- Size comparisons
- Comparisons should use the same unit, such as nanometres, and may use a simple ratio or scale factor.AQA
- Size-dependent properties
- The ratio explains why smaller particles have a greater proportion of their atoms at the surface, so properties change with particle size.AQA
- Small molecules
- Contain only a few non-metal atoms, for example H₂O, CO₂, NH₃, CH₄, HCl, O₂, N₂, H₂ and Cl₂.AQA
- Small molecules and simple molecular substances
- Covalently bonded substances may consist of small molecules, meaning a modest number of atoms held together by strong covalent bonds.AQA
- Small proportions of other gases
- The remaining part of the atmosphere contains various other gases, including carbon dioxide, water vapour and noble gases.AQA
- Small-molecule alkanes
- Alkanes such as methane, ethane, propane and butane that ignite easily, burn with a clean flame and are in high demand as fuels.AQA
- Soda-lime glass
- The common glass used for windows, bottles and drinking glasses, made by heating a mixture of sand, sodium carbonate and limestone.AQA
- Sodium hydroxide solution
- A test used for metal cations that form coloured or white precipitates.AQA
- Solubility and nutrient availability
- A fertiliser must release its nutrient ions into soil solution so plant roots can absorb them, and insoluble compounds cannot do this quickly enough.AQA
- Solubility of bases and alkalis
- An alkali is a base that is soluble in water and produces OH⁻(aq), and not all bases dissolve.AQA
- Soluble salt solution
- The filtrate that passes through the filter paper, giving a clean salt solution without leftover acid.AQA
- Soluble salts
- Products formed when phosphate rock is treated with acid, allowing phosphate ions to dissolve in soil water and be absorbed by plant roots.AQA
- Solution
- A mixture formed when a solute dissolves in a solvent.AQA
- Solvents
- Substances used to dissolve other substances, for example in paints and cleaning products.AQA
- Spectator ions
- Ions that appear unchanged on both sides of a full equation and are cancelled so that only the reacting species are written.AQA
- Spectroscope
- An instrument that separates the light given out into its component wavelengths.AQA
- Speculation
- A claim that goes beyond the available evidence, such as predicting a specific local effect from global data.AQA
- Speed of analysis
- These methods are faster than the chemical tests in this specification because no lengthy test-tube reactions are needed.AQA
- Spherical fullerenes
- Closed cages built from hexagonal rings together with five-membered rings.AQA
- square brackets
- Drawn around each ion in the final diagram, with the charge written outside the bracket.AQA
- Stability and full outer shells
- When atoms lose or gain electrons so that their outer shell becomes full, the resulting ion is stable.AQA
- Stability of atoms
- An atom is most stable when its electrons occupy the lowest available energy states.AQA
- Stability over geological time
- The atmosphere has had much the same proportions of gases for about 200 million years, meaning they have not changed significantly over that period.AQA
- Stainless steel
- An alloy of iron with chromium and nickel, and also containing carbon, that is hard and resistant to corrosion.AQA
- Standard form and unit conversion
- A way of writing very small numbers and converting between units, used to express atomic dimensions such as 1 × 10⁻¹⁰ m.AQA
- State symbols
- Symbols that show the physical state of each substance in an equation: (s) solid, (l) liquid, (g) gas, (aq) aqueous (dissolved in water).AQA
- States of matter
- The three states are solid, liquid and gas, and the state depends on the arrangement, spacing and movement of the particles and the strength of the forces…AQA
- States of matter and boiling point
- Boiling point increases down the group because more energy is required to overcome stronger intermolecular forces.AQA
- States of matter and changes of state
- A substance is solid below its melting point, liquid between its melting and boiling points, and gas above its boiling point.AQA
- States of matter and the particle model
- Atoms are rearranged, not destroyed, but gas particles can move into or out of the container.AQA
- States of matter at room temperature
- Small-molecule substances usually exist as gases or liquids at room temperature, although some, such as water and ethanol, are liquids.AQA
- Stationary and mobile phases
- In paper chromatography, the solvent is the mobile phase and the water held in the paper is the stationary phase.AQA
- Stationary phase
- The phase that does not move, such as the chromatography paper or a thin layer of solid such as silica on a plate.AQA
- Steam cracking
- The hydrocarbon feedstock is mixed with steam at a very high temperature and no catalyst is used.AQA
- Steel
- An alloy based on iron that always contains iron as the main metal, together with a controlled, specific amount of carbon and often other metals added for…AQA
- Stem
- The part of a name, meth-, eth-, prop- or but-, that gives the number of carbon atoms.AQA
- Sterilising
- The final treatment step described for producing potable water, which kills microbes.AQA
- Sterilising agents
- Chlorine, ozone or ultraviolet light are used for potable water to kill microbes that could cause disease.AQA
- Stoichiometric calculations
- The masses of reactants and products can be calculated from balanced symbol equations, converting the known mass to moles, using the balancing numbers, then…AQA
- Stoichiometry from balanced equations
- Using a balanced equation to set a gas volume ratio and scaling it to a given volume of a gaseous reactant or product.AQA
- Stoichiometry of gaseous reactions
- The volumes of gaseous reactants and products can be calculated from the balanced equation by scaling the volume ratio to the given volume.AQA
- Strength and hardness
- The ability to resist forces without deforming, produced in high carbon steel because carbon atoms disrupt the layers of iron atoms so they cannot slide easily.AQA
- Strength of electrostatic forces
- The strength of the forces increases with the charge on the ions, so compounds such as magnesium oxide have even higher melting points than sodium chloride.AQA
- Strength of ionic bonding
- The attractions are strong, so a large amount of energy is needed to overcome them.AQA
- Strength of metallic bonding
- This varies between metals, so melting points vary, and the more electrons donated per atom, the higher the melting point tends to be.AQA
- Strong Acid
- An acid that is completely ionised in aqueous solution (e.g., hydrochloric, nitric, sulfuric acid).OCR
- Strong covalent bonds within molecules
- The bonds that hold each molecule together internally, which remain strong.AQA
- Structure and properties
- The strong covalent bonds within a polymer molecule make it difficult to break apart, and they are distinct from the weaker intermolecular forces between…AQA
- Structure and properties of monatomic gases
- Because the stable arrangement means they do not need to bond to gain a full outer shell, they exist as single atoms and are chemically unreactive.AQA
- Structure and property relationships
- Longer molecules become tangled and slide over one another less easily, so the liquid flows more slowly.AQA
- Structure and reactivity
- Alkenes contain a carbon–carbon double bond, which makes them more reactive than alkanes, whose molecules have only single bonds.AQA
- Structure of noble gases
- They exist as single atoms, not as diatomic molecules.AQA
- Structure of the atom
- A tiny, dense, positively charged nucleus sits at the centre and most of the atom is empty space, with electrons outside the nucleus.AQA
- Structure of the nucleus
- The modern nuclear model establishes that the nucleus contains both protons and neutrons, accounting for the full atomic mass.AQA
- Structure recognition
- Looking for a long chain rather than a small discrete molecule, and finding the shortest section that repeats along the chain.AQA
- Structure-property relationships
- Chains that are long, straight and closely packed give a denser, stronger, more rigid polymer with a higher softening temperature, while shorter or more…AQA
- Structure-property-application links
- Linking a named property, such as high tensile strength or electrical conductivity, to a specific use rather than listing uses without justification.AQA
- Structure-property-use relationships
- Iron is strong and dense and used in construction, while copper is a good conductor used in electrical wiring.AQA
- Structure–property relationships
- The way the arrangement of atoms in a structure leads to different properties, such as hardness and electrical conductivity.AQA
- Subatomic particles
- Protons, each with relative charge 1⁺, and neutrons, which have no charge, are found in the nucleus, while electrons carry relative charge 1⁻ and occupy shells.AQA
- Subscript
- A small, low number written after a symbol that multiplies only the atom or bracketed group immediately before it within that formula unit.AQA
- Substance
- A material that can be an element, compound or mixture, and all substances are made of atoms.AQA
- Successful collisions
- Collisions in which the particles have energy equal to or greater than the activation energy, so a reaction takes place.AQA
- Sufficiently low
- The phrase showing that water need not be chemically pure, but must meet safety standards for consumption.AQA
- Sulfur dioxide
- Produced when sulfur impurities in a fuel burn and react with oxygen.AQA
- Sulfur impurities
- Sulfur present in many fuels as an impurity rather than as the main fuel component, as in coal and crude-oil fractions.AQA
- Surface area
- Increasing this for a solid reactant, for example by using a powder, increases the rate of reaction.AQA
- Surface area and reaction rate
- Exposing more particles of a solid to the other reactant allows more frequent collisions, so the rate increases.AQA
- Surface area to volume ratio
- Nanoparticles have a very large one of these because a high proportion of their atoms lie at the surface.AQA
- Surface protection
- The strongly bonded, unreactive layer seals the metal underneath from oxygen and water, and if scratched it reforms immediately in air.AQA
- Surface temperature rise
- An increase in the temperature of the Earth's atmosphere at the surface, expected because human activities increase greenhouse gas concentrations.AQA
- Sustainability
- An issue raised by dependence on crude oil, which is a finite resource, so alternatives and recycling are important.AQA
- Sustainable development
- Development that meets the needs of current generations without compromising the ability of future generations to meet their own needs.AQA
- Sustainable use of limited resources
- Reducing the use of limited resources by recycling materials, reusing items, and designing products that last longer or use less material.AQA
- Symbol equation
- A way of representing a reaction that uses chemical formulae instead of names and gives the same reaction information more precisely.AQA
- Systematic balancing strategy
- Balance carbon first using the coefficient of CO₂, then hydrogen using H₂O, and finally oxygen by adjusting the number of O₂ molecules.AQA
T
- Temperature change
- The difference found by subtracting the initial temperature from the final temperature, showing how large the change is.AQA
- Temperature change measurement
- Measuring the initial temperature of the solution before adding the second reactant, then measuring the maximum or final temperature after the reaction and…AQA
- Temperature change of surroundings
- The basis for distinguishing the two types of reaction, where a rise indicates exothermic and a fall indicates endothermic.AQA
- Temperature changes
- If the temperature of a system at equilibrium is increased, the relative amount of products at equilibrium increases for an endothermic reaction and decreases…AQA
- Temperature decrease as evidence
- A temperature drop measured with a thermometer or temperature sensor is evidence that a reaction is endothermic.AQA
- Temperature measurement
- Recording the initial temperature of the surroundings or solution before the reaction and the highest or lowest temperature reached after the reaction.AQA
- Testing predictions against new evidence
- He predicted the existence and properties of an element he called eka-silicon, which was later discovered as germanium.AQA
- The mole and Avogadro number
- The unit used to measure chemical amount, containing the Avogadro number of particles, 6.02 × 10²³, which may be atoms, molecules, ions or electrons.AQA
- Theoretical maximum
- The maximum mass of product that could possibly be created from the given reactants.AQA
- Theoretical yield
- The maximum calculated amount of product, assuming all reactants convert fully into the desired product.AQA
- Theory and evidence
- Agreement between theory and evidence supports a scientific model, because models are judged by how well they explain and predict evidence.AQA
- Theory evaluation
- Comparing how well each theory explains the evidence provided, considering strengths and weaknesses such as how well it explains the data.AQA
- Thermal decomposition
- Breaking a compound down by heating, for example heating calcium carbonate to form calcium oxide and carbon dioxide.AQA
- Thermosetting polymers
- Polymers whose chains are joined by strong covalent cross-links, so they do not melt when heated and may char or decompose at very high temperatures.AQA
- Three-dimensional network
- A rigid structure formed when polymer chains are joined to one another by strong covalent cross-links.AQA
- Timber and fuels
- Categories supplied by natural resources and supplemented by agriculture, with timber from managed forests and fuels including wood, biodiesel and fossil fuels.AQA
- Time scale of scientific discovery
- The neutron was identified roughly two decades after the nucleus became an accepted scientific idea.AQA
- Titration
- A practical method used to measure the volume of one solution that reacts exactly with a known volume of another solution.AQA
- Titration calculations
- Use concentrations in mol/dm³ and balanced equations to link reacting solutions, calculating the concentration of the other solution when the volumes of two…AQA
- Toxic
- Carbon monoxide is a toxic gas, meaning it is poisonous to humans and can cause serious harm or death.AQA
- Toxic gas
- A gas such as chlorine that must never be smelled directly or prepared in open laboratory conditions without suitable ventilation.AQA
- Trace gases methane and ammonia
- There may have been small proportions of methane and ammonia in the atmosphere.AQA
- Trade-off between purity and cost
- A high-purity product usually needs more separation stages, which uses more energy and costs more.AQA
- Trade-offs between environmental benefit and cost
- Weighing benefits against drawbacks, for example energy saved by recycling aluminium against energy and money used in collecting and sorting the cans.AQA
- Transition elements
- Metals located in the central block of the periodic table between Groups 2 and 3, showing similar properties to each other.AQA
- Transition metal chemistry
- Transition metals show general properties such as forming ions with different charges, forming coloured compounds and acting as catalysts, exemplified by…AQA
- Transition metals
- Chromium, manganese, iron, cobalt, nickel and copper are examples, having high melting points and high densities.AQA
- Trend description
- Saying whether values increase, decrease or remain constant and quoting data points to support it.AQA
- Trends in Group 0
- Going down the group, relative atomic mass increases and boiling point increases from helium to radon.AQA
- Trends in metallic character
- Moving down a group, metallic character becomes more pronounced, so elements lower in a group behave more typically as metals.AQA
- Trends in physical properties
- As the chain lengthens, the molecules have greater intermolecular forces, so boiling points rise and solubility in water decreases.AQA
- Trends in properties
- Boiling point and viscosity increase with chain length.AQA
- Trends in reactivity
- Reactivity increases from lithium to sodium to potassium, so potassium reacts most vigorously, often igniting the hydrogen produced.AQA
- Trends in reactivity down a group
- Reactivity increases down Group 1 because the outer electron is further from the nucleus and shielded by more inner shells, so the attraction holding it is…AQA
- Trends in reactivity down Group 7
- Reactivity decreases down Group 7 because atomic radius increases and shielding increases, so the nucleus attracts an incoming electron less strongly.AQA
- Trends with molecular size
- As the molecules in a hydrocarbon fraction get larger, boiling point, viscosity and flammability change in a regular way.AQA
- Triple superphosphate
- Calcium phosphate produced by reacting phosphoric acid with further phosphate rock.AQA
U
- Ultraviolet light
- Used by passing water through a chamber where UV radiation damages the genetic material of microbes so they cannot reproduce.AQA
- Unadulterated substances
- A substance that has had nothing added to it, so it is in its natural state, as with pure milk.AQA
- Unburned hydrocarbons
- Fuel molecules that escape combustion unchanged.AQA
- Uncertainty
- A range or limitation arising from measurement limits, natural variation or model simplification, so scientists give ranges rather than single values.AQA
- Unit conversion
- Volume in cm³ is converted to dm³ by dividing by 1000 before substituting, and consistent units are used throughout.AQA
- Units and dimensional reasoning
- The unit mol/s represents the amount of substance in moles reacting or forming each second.AQA
- Units of concentration
- Common units include g dm⁻³ or mol dm⁻³.AQA
- universal indicator
- A mixture of dyes that gives a colour for each pH, which you compare with a colour chart; it is quick but only gives an approximate value.AQA
- Unsaturated
- Describes alkenes, which contain a carbon–carbon double bond.AQA
- Unsaturation
- The presence of a carbon-carbon double bond, shown by bromine water being decolourised from orange-brown to colourless.AQA
- Use and limitations of scientific models
- The simple model represents particles as small solid spheres, but it ignores forces, particle size and the internal structure of atoms.AQA
- Useful products
- Formulations are designed as useful products, and examples include paints, medicines, alloys, fertilisers and foods.AQA
- Uses of polymers
- Polymers made from alkenes are used for bags, bottles, pipes and fibres.AQA
- Uses of water
- Different uses need different quality, so washing, irrigation and industrial cooling may use lower-quality water.AQA
- Using data to predict properties
- Identify the trend from the data given, then extend it to the next element, justifying the prediction using outer-shell electron loss and increased atomic size.AQA
- Using multiple observations
- Combining evidence from several tests, because one observation alone may fit more than one species.AQA
- Using named examples to support comparisons
- Naming the property, stating the trend for each group and supporting it with a named example makes the comparison precise.AQA
- Using the series to make predictions
- The series can be used to predict whether a displacement reaction occurs.AQA
V
- Value judgements
- Decisions about how harmful each pollutant is, which are choices rather than readings from an instrument.AQA
- Variable composition
- The components of a mixture can be present in any proportion, unlike a compound which has a fixed composition by mass.AQA
- Variable exhaust composition
- The exact mixture depends on the fuel, the oxygen supply and the temperature, which is why the word may is important.AQA
- Variable oxidation states
- Many transition elements form ions with different charges, for example iron forms Fe²⁺ and Fe³⁺ and copper forms Cu⁺ and Cu²⁺.AQA
- Variables affecting cell performance
- The voltage of a cell depends on the type of electrode and electrolyte, and temperature can also affect the voltage in practical cells.AQA
- Variables and control
- Changing only the independent variable and controlling other variables such as temperature, volumes and reactant amounts.AQA
- Variables and fair testing
- Varying one independent variable at a time, such as concentration, volume, particle size or identity of metal, while controlling other variables to ensure a…AQA
- Viscosity
- Increases with molecular size, meaning longer chain hydrocarbons flow less easily.AQA
- Volcanic production of nitrogen
- Volcanoes produced nitrogen, which then gradually built up in the atmosphere.AQA
- Voltage
- The energy transferred per unit charge, which drives a larger current through a circuit when greater.AQA
- Voltage and energy transfer
- Voltage is described as the energy transferred per unit charge, and is not the same as current, which is the rate of flow of charge.AQA
- Volume ratios of gases
- The coefficients in the balanced equation give the volume ratio for gases measured under the same conditions of temperature and pressure.AQA
W
- Waste
- Products that are discarded after one use, some of which is sent to landfill.AQA
- Waste minimisation and resource efficiency
- A process that converts most of its starting materials into the desired product uses resources more efficiently and produces less waste.AQA
- Waste reduction
- Less rock is dug, transported and discarded, so waste is reduced.AQA
- Waste water
- Water including sewage and industrial effluent, which contains organic matter, harmful chemicals and microorganisms and so needs multiple treatment stages.AQA
- Water as a product
- The only chemical product of the overall reaction is water, which is why hydrogen fuel cells are described as producing no carbon dioxide at the point of use.AQA
- Water as a source of ions
- Water molecules break down producing hydrogen ions and hydroxide ions, and water is a weak electrolyte because only a small fraction of its molecules…AQA
- Water quality and health
- Water of appropriate quality is essential for life, as it supports drinking, sanitation, agriculture and industry.AQA
- Water scarcity and supply
- Some regions have limited fresh water because of low rainfall, high demand or both, so an alternative source may be required.AQA
- Water treatment methods
- The methods used to produce potable water depend on available supplies of water and local conditions.AQA
- weak acid
- An acid that is only partially ionised in aqueous solution, so only a small proportion of its molecules release hydrogen ions.AQA
- Weak acids, ionisation and pH
- Carboxylic acids dissolve in water and ionise only slightly, releasing few H⁺ ions, so their pH is higher than that of a strong acid of the same concentration.AQA
- Weak and strong
- Describe the degree of ionisation: a strong acid ionises completely, a weak acid only partially.AQA
- Weak forces between molecules
- The attraction between separate molecules in a simple molecular substance, which is weak.AQA
- Weak intermolecular forces
- The weak forces between separate molecules that must be overcome when the substance changes state, and which are the key factor in low melting and boiling…AQA
- Weighting pollutant effects
- Assigning a number to the harm caused by each pollutant so that effects can be compared.AQA
- White precipitate
- The fine solid of barium sulfate that appears when sulfate ions are present, showing they are present.AQA
- Whole-number coefficients and formula integrity
- Use the lowest whole-number coefficients, doubling the equation if an odd oxygen count appears, while keeping every formula fixed and adjusting coefficients…AQA
- Whole-number ratios
- Multiplying through if necessary to obtain the smallest whole-number ratio, rather than leaving decimals or fractions.AQA
- wide range indicator
- An indicator that can be used to measure the approximate pH of a solution, added as a few drops or as a piece of indicator paper dipped into it.AQA
- Word equation
- A way of representing a reaction that names all reactants and products, for example hydrochloric acid + sodium hydroxide → sodium chloride + water.AQA
- Word equations
- Nitrogen + hydrogen ⇌ ammonia summarises the reaction and shows that the process is reversible.AQA
Y
- Yield
- The amount of a product obtained in a reaction, usually measured in grams.AQA
Other terms
- -anoic acid
- The ending in a name that signals the –COOH group and shows a carboxylic acid.AQA
- -ol ending
- Used in a name as evidence that the compound is an alcohol.AQA
- -ol suffix
- The ending used to name alcohols, with a number added where needed to show the position of the –OH group.AQA
- –COOH
- A carbon atom joined to an oxygen by a double bond and to an –OH group, sitting at the end of a chain.AQA
- –COOH unit
- The group looked for in a formula, which may be written as COOH, CO₂H or drawn with the carbon double-bonded to oxygen and single-bonded to –OH.AQA
- –OH group
- An oxygen atom covalently bonded to a hydrogen atom, with that oxygen also bonded to a carbon atom of the hydrocarbon chain.AQA
- 1⁺ ion
- Formed when a Group 1 atom loses its single outer electron, giving a stable full outer shell.AQA
Where these terms come from
Each definition is one we publish on a Chemistry GCSE topic page or study guide. Open a term to see how each exam board words it and which topic it belongs to. For the full course, go to Chemistry revision or the glossary for every subject.
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